Abstract: Methods for distributing catalyst in a counter-current reactor may include passing the catalyst from a catalyst hopper to a perforated plate distributor; distributing the catalyst into a reaction zone of the counter-current reactor by passing the catalyst from a catalyst discharge zone, through the perforations of the perforated plate distributor, into the reaction zone, wherein the catalyst enters the perforations of the perforated plate distributor at a superficial velocity from 0.01 m/s to 10 m/s, and the superficial velocity is in a substantially downward direction; and passing a hydrocarbon feed stream into the reaction zone, wherein the catalyst moves in a substantially downward direction through the reaction zone, the hydrocarbon feed stream moves in a substantially upward direction through the reaction zone, and wherein contacting the catalyst with the hydrocarbon feed stream cracks one or more components of the hydrocarbon feed stream and forms a hydrocarbon product stream.

Abstract: A composition of an indium oxide catalyst including an alkali dopant and a method for producing an indium oxide catalyst including an alkali dopant. The alkali dopant may include a cation of Li+, Na+, K+, Rb+, Cs+, and Fr+. The method for producing the indium oxide catalyst including an alkali dopant includes mixing a solution of an indium salt with a base to form precipitated indium hydroxide, contacting the precipitated indium hydroxide with a solution including an alkali metal salt to produce an indium hydroxide solution, and calcinating the indium hydroxide solution to form indium oxide; thereby forming the indium oxide catalyst including an alkali dopant.

Abstract: A sand aggregate includes plural aggregate grains, wherein at least one aggregate grain of the plural aggregate grains includes, desert sand grains that are too small to be used in concrete applications, carbonate particles distributed on an external surface of the desert sand grains, and a sand-based glue that aggregates the desert sand grains together. The at least one aggregate grain has a size comparable to river sand grains, while the desert sand grains have a size smaller than the river sand grains so that the at least one aggregate grain is suitable for concrete applications.

Abstract: A method for making a metal carbide based catalyst for crude oil cracking includes mixing a clay with a phosphorous based stabilizer material to obtain a liquid slurry; adding an aluminosilicate zeolite and an ultrastable Y zeolite to the liquid slurry; adding Al2Cl(OH)5 to the liquid slurry; adding metal carbide particles, having a given diameter, to the liquid slurry to obtain a mixture; and spray drying the mixture to obtain the metal carbide based catalyst. The metal carbide particles are coated with the aluminosilicate zeolite and the ultrastable Y zeolite.

Abstract: A sand aggregate includes plural aggregate grains, wherein at least one aggregate grain of the plural aggregate grains includes, desert sand grains that are too small to be used in concrete applications, carbonate particles distributed on an external surface of the desert sand grains, and a sand-based glue that aggregates the desert sand grains together. The at least one aggregate grain has a size comparable to river sand grains, while the desert sand grains have a size smaller than the river sand grains so that the at least one aggregate grain is suitable for concrete applications.

Abstract: Light olefins may be produced from hydrocarbons by a method including passing a hydrocarbon feed stream into one or more feed inlets of a reactor, with one or more co-feeds of steam, a recycle stream or oxygenates. The reactor may include an upper reactor portion defining an upper reaction zone and a lower reactor portion defining a lower reaction zone. The catalyst may move in a generally downward direction through the upper reactor portion and the lower reactor portion, and the hydrocarbon feed stream may move in a generally upward direction through the lower reactor portion and upper reactor portion such that the hydrocarbon feed stream and the catalyst move with a counter-current orientation. Contacting the catalyst with the hydrocarbon feed stream may crack one or more components of the hydrocarbon feed stream and form a hydrocarbon product stream.

Abstract: A hydrocarbon feed stream may be processed by a method that may include catalytically cracking a hydrocarbon feed stream in a counter-current reactor to produce a first effluent stream, and processing a portion or all of the first effluent stream by at least one or more separations. The at least one or more separations may form at least a second effluent stream including at least 95 wt. % C4-C6 hydrocarbons, and a third effluent stream including at least 95 wt. % of ethane, propane, or a combination thereof. In some embodiments, the method may further include catalytically cracking a portion or all of the second effluent stream in a second reactor to form a second reactor effluent stream, combining a portion of all of the second reactor effluent stream with the first effluent stream, steam cracking a portion or all of the third effluent stream to form a steam cracked effluent stream, and combining a portion or all of the steam cracked effluent stream with the first effluent.

Abstract: Light olefins may be produced from hydrocarbons by a method including passing a hydrocarbon feed stream into one or more feed inlets of a reactor, using catalyst formulations or mixtures. Catalyst formulations may include multi-zeolite composite particles, or a mixture that is a physically mixed combination of separate particles of at least first composite particles of a first type of zeolite and second composite particles of a second type of zeolite. The reactor may include an upper reactor portion defining an upper reaction zone and a lower reactor portion defining a lower reaction zone. The catalyst may move in a generally downward direction through the upper reactor portion and the lower reactor portion, and the hydrocarbon feed stream may move in a generally upward direction through the lower reactor portion and upper reactor portion such that the hydrocarbon feed stream and the catalyst move with a counter-current orientation.

Abstract: A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.

Abstract: A multi-zoned fluidized bed reactor system may include a multi-zoned fluidized bed reactor and at least one catalyst regeneration loop. The multi-zoned fluidized bed reactor comprising a housing, a fluid bed distributor plate positioned at the bottom of the housing, a fluidized catalyst bed disposed vertically above the fluid bed distributor plate and a condensation zone disposed vertically above the fluidized catalyst bed. The at least one catalyst regeneration loop may be fluidly coupled to the stripping zone and a reaction zone. The at least one catalyst regeneration loop may be operable to withdraw a portion of spent catalyst from the stripping zone, regenerate the portion of spent catalyst to produce regenerated catalyst, and return the regenerated catalyst to the reaction zone. A method of regenerating catalyst in a multi-zoned fluidized bed reactor may include passing a portion of spent catalyst from a stripping zone to a catalyst regeneration loop.

Abstract: A hydrocarbon feed stream may be processed by a method that may include catalytically cracking a hydrocarbon feed stream in a counter-current reactor to produce a first effluent stream, and processing a portion or all of the first effluent stream by at least one or more separations. The at least one or more separations may form at least a second effluent stream including at least 95 wt. % C4-C6 hydrocarbons, and a third effluent stream including at least 95 wt. % of ethane, propane, or a combination thereof. In some embodiments, the method may further include catalytically cracking a portion or all of the second effluent stream in a second reactor to form a second reactor effluent stream, combining a portion of all of the second reactor effluent stream with the first effluent stream, steam cracking a portion or all of the third effluent stream to form a steam cracked effluent stream, and combining a portion or all of the steam cracked effluent stream with the first effluent.

Abstract: A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.

Abstract: A method for ammonia decomposition to produce hydrogen, the method comprising the steps of introducing an ammonia stream to a reactor, wherein the ammonia stream comprises ammonia, wherein the reactor comprises a cobalt-based catalyst, the cobalt-based catalyst comprising 15 wt % and 70 wt % of cobalt, 5 wt % and 45 wt % of cerium, and 0.4 wt % and 0.5 wt % barium, wherein a remainder of weight of the cobalt-based catalyst is oxygen; contacting the ammonia in the ammonia stream with the cobalt-based catalyst, wherein the cobalt-based catalyst is operable to catalyze an ammonia decomposition reaction; catalyzing the ammonia decomposition reaction to cause the ammonia decomposition in the presence of the cobalt-based catalyst to produce hydrogen; and withdrawing a product stream from the reactor, the product stream comprising hydrogen.

Abstract: A reaction unit for catalytic conversion of a hydrocarbon or hydrocarbon containing feedstock to a petrochemical mixture, includes a housing; a fluid bed distributor plate located at a bottom of the housing; a regeneration zone and a stripping zone located above the fluid bed distributor plate, in which catalytic particles are housed; a reaction zone located above the stripping zone; and a condensation zone located above the reaction zone, in which a petrochemical product fluid is condensed.

Abstract: A method and catalyst for forming higher carbon number products from carbon dioxide is provided. An exemplary catalyst includes red mud including iron and aluminum, and impregnated potassium.

Abstract: A method for making a metal carbide based catalyst for crude oil cracking includes mixing a clay with a phosphorous based stabilizer material to obtain a liquid slurry; adding an aluminosilicate zeolite and an ultrastable Y zeolite to the liquid slurry; adding Al2Cl(OH)5 to the liquid slurry; adding metal carbide particles, having a given diameter, to the liquid slurry to obtain a mixture; and spray drying the mixture to obtain the metal carbide based catalyst. The metal carbide particles are coated with the aluminosilicate zeolite and the ultrastable Y zeolite.

Abstract: A multi-zoned fluidized bed reactor system may include a multi-zoned fluidized bed reactor and at least one catalyst regeneration loop. The multi-zoned fluidized bed reactor comprising a housing, a fluid bed distributor plate positioned at the bottom of the housing, a fluidized catalyst bed disposed vertically above the fluid bed distributor plate and a condensation zone disposed vertically above the fluidized catalyst bed. The at least one catalyst regeneration loop may be fluidly coupled to the stripping zone and a reaction zone. The at least one catalyst regeneration loop may be operable to withdraw a portion of spent catalyst from the stripping zone, regenerate the portion of spent catalyst to produce regenerated catalyst, and return the regenerated catalyst to the reaction zone. A method of regenerating catalyst in a multi-zoned fluidized bed reactor may include passing a portion of spent catalyst from a stripping zone to a catalyst regeneration loop.

Abstract: Embodiments of the present disclosure describe pre-catalysts comprising including one or more of indium oxide, indium hydroxide, indium oxyhydroxide, an active oxide, and a refractory oxide. Embodiments of the present disclosure also describe method of making pre-catalysts based on one or more of impregnation, precipitation or co-precipitation, ball milling, and metal-organic framework (MOF)-mediated synthesis. Embodiments of the present disclosure further describe methods of activating pre-catalysts and synthesizing one or more of methanol and olefins using catalysts obtained from the pre-catalysts.

Abstract: A reaction unit for catalytic conversion of a hydrocarbon or hydrocarbon containing feedstock to a petrochemical mixture, includes a housing; a fluid bed distributor plate located at a bottom of the housing; a regeneration zone and a stripping zone located above the fluid bed distributor plate, in which catalytic particles are housed; a reaction zone located above the stripping zone; and a condensation zone located above the reaction zone, in which a petrochemical product fluid is condensed.

Abstract: A method and catalyst for forming higher carbon number products from carbon dioxide is provided. An exemplary catalyst includes red mud including iron and aluminum, and impregnated potassium.