Patents by Inventor José-Carlos Araujo-Da-Silva

José-Carlos Araujo-Da-Silva has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20130012652
    Abstract: The invention relates to a tire comprising at least one rubber composition based on at least one diene elastomer, one reinforcing filler, one chemical crosslinking agent and one modifying agent, chosen from the compounds of following formula (I): where R denotes a unit comprising at least one reactive group, R1 denotes hydrogen, R2 denotes an alkylene radical comprising from 2 to 8 carbon atoms and optionally one or more heteroatoms chosen from S, N, O or Si, A denotes an oxygen or sulphur atom or an ?NH group, preferably an oxygen atom.
    Type: Application
    Filed: March 15, 2011
    Publication date: January 10, 2013
    Applicants: Michelin Recherche et Technique S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: José Carlos Araujo Da Silva, Jean-Michel Favrot, Rachid Matmour, Anne Frédérique Salit, Nicolas Seeboth
  • Publication number: 20120283360
    Abstract: A rubber composition which can be used in particular in tires, based on at least one diene elastomer, one reinforcing filler, one crosslinking system, between 1 and 20 phr of an epoxide resin and between 1 and 15 phr of an amine-comprising curing agent. The pair formed of epoxide resin with an amine-comprising curing agent advantageously replaces the pair formed of phenol/formaldehyde resin, which is a methylene acceptor, with the curing agent(s) HMT or H3M, which are conventional methylene donors. The use of this pair of reactants, epoxide resin and amine-comprising curing agent, makes it possible to obtain rubber compositions exhibiting a greater low-strain stiffness in comparison with conventional rubber compositions, without significantly damaging the hysteresis. Moreover, the combination of a phenolic resin, which is a methylene acceptor, with HMT or H3M, which is a methylene donor, produces formaldehyde during the vulcanization of the rubber composition.
    Type: Application
    Filed: October 13, 2010
    Publication date: November 8, 2012
    Inventors: Anne Veyland, Vincent Hunault, Jose Carlos Araujo Da Silva
  • Publication number: 20120196960
    Abstract: Reinforced rubber composition, exhibiting improved hysteresis, based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler and (c) a specific polyimine compound in a small proportion, preferably ranging from 1 to 5 mmol per 100 g of elastomer. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tyres of motor vehicles.
    Type: Application
    Filed: July 8, 2010
    Publication date: August 2, 2012
    Inventors: José Carlos Araujo Da Silva, Justin Belz, Stéphanie De Landtsheer, Natalie Simon, Brigitte Chauvin
  • Publication number: 20120196976
    Abstract: The invention relates to the use of an adhesive composition between a vulcanized rubber part and an uncured or prevulcanized or vulcanized rubber part, based on at least one highly unsaturated elastomer chosen from the group formed by natural rubber, polyisoprene, polybutadiene, styrene-butadiene, styrene-isoprene and butadiene-isoprene copolymers and styrene-butadiene-isoprene terpolymers, an aliphatic solvent and a “curing” system comprising at least one stable aryl dinitrile oxide compound.
    Type: Application
    Filed: March 30, 2010
    Publication date: August 2, 2012
    Applicants: Michelin Rechercheet Technique S.A., Societe De Technologie Michelin
    Inventors: José Carlos Araujo Da Silva, Vincent Hunault, Pierre Robert, Anne Veyland
  • Patent number: 8232338
    Abstract: A rubber composition based on at least one diene elastomer, containing less than 2 phr of zinc, phr meaning parts per hundred parts of rubber (elastomer), and based on at least one reinforcing filler and one sulphur-based crosslinking system, comprising a zinc carboxylate of formula: (RCOO)2Zn, in which R represents a hydrocarbon group chosen from cyclic or non-cyclic, linear or branched alkyl groups having 1 to 16 carbon atoms, aryl groups, aralkyl groups or alkaryl groups having 1 to 16 carbon atoms. Also disclosed is a process for preparing such a rubber composition which is suitable for manufacturing tires or semi-finished products made of rubber intended for these tires.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: July 31, 2012
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: José Carlos Araujo Da Silva, Anne Veyland
  • Publication number: 20120165449
    Abstract: Reinforced rubber composition based on, exhibiting a lesser hysteresis degradation over time, based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler and (c) a specific polyimine compound in a content of between 6 and 20 mmol per 100 g of elastomer. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tyres of motor vehicles.
    Type: Application
    Filed: July 8, 2010
    Publication date: June 28, 2012
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., SOCIETE DE TECHNOLOGIE MICHELIN
    Inventors: José Carlos Araujo Da Silva, Justin Belz
  • Publication number: 20120157571
    Abstract: A rubber composition that can be used for the manufacture of tires, based on at least one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one coupling agent of general formula I below: (HO)3-nR1nSi—Z—Sm—R2 wherein in which: R1, which are identical or different, each represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R2 represents a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 30 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms; n is an integer equal to 0, 1 or 2; and m is a number greater than or equal to 2.
    Type: Application
    Filed: May 20, 2010
    Publication date: June 21, 2012
    Applicants: Michelin Recherche et Technique S.A., Societe De Technologie Michelin
    Inventors: Karine Longchambon, José Carlos Araujo Da Silva, Nocolas Seeboth
  • Publication number: 20120149818
    Abstract: Reinforced rubber composition, exhibiting improved hysteresis, based on at least (a) an elastomeric matrix predominantly based on natural rubber, (b) a reinforcing filler and (c) a specific polyamine compound present in a proportion of between 0 and 7 mmol per 100 g of elastomer. This rubber composition is intended, for example, for the manufacture of a semi-finished rubber product intended for the tires of motor vehicles.
    Type: Application
    Filed: July 8, 2010
    Publication date: June 14, 2012
    Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., SOCIETE DE TECHNOLOGIE MICHELIN
    Inventors: José Carlos Araujo Da Silva, Justin Belz, Stéphanie De Landtsheer, Nathalie Simon
  • Publication number: 20110303338
    Abstract: Rubber composition, especially for a tire, based on at least one diene elastomer, a reinforcing filler, a crosslinking system and an antioxidant system, wherein said antioxidant system comprises at least two antioxidants “A” and “B”: A. an N-alkyl-N?-phenyl-para-phenylenediamine corresponding to the formula (I): B. a 4,4?,4?-tris(alkylamino)triphenylamine corresponding to the formula (II): in which formulae, R1, R2, R3 and R4, which are identical or different, each represent a linear or branched alkyl group having from 1 to 12 carbon atoms or a cycloalkyl group having from 5 to 8 carbon atoms, the A/B weight ratio being between 0.1 and 5.0.
    Type: Application
    Filed: May 14, 2009
    Publication date: December 15, 2011
    Applicants: Michelin Recherche et Technique S.A., Societe De Technologie Michelin
    Inventors: José Carlos Araujo Da Silva, Arnaud Remy
  • Publication number: 20110306700
    Abstract: The invention relates to a rubber composition that is free of zinc or that contains less than 0.5 phr of zinc, which can be used for the manufacture of tyres, based on at least: one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one blocked mercaptosilane of general formula I below: (R3O)R2R1—Si—Z—S—C(?O)-A in which: R1 and R2, which are identical or different, represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R3 represents a monovalent hydrocarbon-based group chosen from linear or branched alkyls having from 1 to 4 carbon atoms; A represents hydrogen or a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms.
    Type: Application
    Filed: December 18, 2009
    Publication date: December 15, 2011
    Applicant: Michelin Recherche ET Technique S.A.
    Inventors: Laure Belin, Karine Longchambon, José Carlos Araujo Da Silva
  • Publication number: 20110294915
    Abstract: The invention relates to a rubber compound containing no or less than 0.5 phr zinc, which can be used for the manufacture of tyres, the compound being based on at least: a diene elastomer; a sulphur-based crosslinking system; an inorganic filler as reinforcing filler; and a blocked mercaptosilane of the following general formula (I) in which formula (I): R1 which are the same or different, each represent a monovalent hydrocarbon group chosen from alkyls, whether linear or branched, cycloalkyls or aryls, having 1 to 18 carbon atoms; A represents hydrogen or a monovalent hydrocarbon group chosen from alkyls, whether linear or branched, cycloalkyls or aryls, having 1 to 18 carbon atoms; Z represents a divalently bonded group having 1 to 18 carbon atoms; and n is an integer equal to 0, 1 or 2.
    Type: Application
    Filed: December 18, 2009
    Publication date: December 1, 2011
    Applicants: Michelin Recherche et Technique S.A., Societe De Technologie Michelin
    Inventors: Laure Belin, Karine Longchambon, José Carlos Araujo Da Silva
  • Publication number: 20110294953
    Abstract: The invention relates to a blocked mercaptosilane of general formula I below: (HO)2R1—Si—Z—S—C(?O)-A in which: R1 represents a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; A represents hydrogen or a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms.
    Type: Application
    Filed: December 18, 2009
    Publication date: December 1, 2011
    Inventors: Nicolas Seeboth, Karine Longchambon, Laure Belin, Jóse Carlos Araujo Da Silva
  • Publication number: 20110203712
    Abstract: Rubber composition, especially for a tire, based on at least one diene elastomer, a reinforcing filler, a crosslinking system and an antioxidant system, wherein said antioxidant system contains at least two antioxidants “A” and “B”: A. an N-alkyl-N?-phenyl-para-phenylenediamine corresponding to the formula (I): B. a 4,4?-bis(alkylamino)triphenylamine corresponding to the formula (II): in which formulae, R1, R2 and R3, which are identical or different, each represent a linear or branched alkyl group having from 1 to 12 carbon atoms or a cycloalkyl group having from 5 to 8 carbon atoms, the A/B weight ratio being between 0.2 and 5.0. Such an antioxidant system gives the composition of the invention a better long-term resistance to fatigue and to crack propagation.
    Type: Application
    Filed: April 29, 2011
    Publication date: August 25, 2011
    Applicant: Michelin Recherche et Technique S.A.
    Inventors: José Carlos Araujo Da Silva, Pierre-Antoine Niore, Arnaud Remy
  • Publication number: 20110152458
    Abstract: A subject-matter of the present invention is a rubber composition intended for the manufacture of tyres or of tyre semi-finished products, based on at least one isoprene elastomer, an inorganic filler as reinforcing filler and a polyfunctional organosiloxane coupling agent capable of providing the bonding between the reinforcing inorganic filler and the isoprene elastomer, comprising per molecule, grafted to its silicon atoms, on the one hand at least one hydroxyl or hydrolysable functional group allowing it to be grafted to the reinforcing inorganic filler and, on the other hand, at least one group bearing at least one azodicarbonyl functional group —CO—N?N—CO— allowing it to be grafted to the isoprene elastomer.
    Type: Application
    Filed: March 2, 2011
    Publication date: June 23, 2011
    Applicant: Michelin Recherche et Technique S.A.
    Inventors: Jose Carlos ARAUJO DA SILVA, Karine LONGCHAMBON, Sebastien STERIN
  • Publication number: 20110009547
    Abstract: Rubber composition which can be used in particular for the manufacture of tyres or tyre semi-finished products, such as treads, the said composition being based on at least a diene elastomer, a reinforcing inorganic filler, a coupling agent and a hydroxysilane of formula (I): R1(R2)nSi(OH)3-n in which: n is equal to 0, 1 or 2; R1 represents a hydrocarbon group having at least 4 carbon atoms; R2 represents an alkyl having from 1 to 4 carbon atoms, the R2 alkyls being identical or different if n is equal to 2.
    Type: Application
    Filed: November 14, 2008
    Publication date: January 13, 2011
    Inventors: Jose Carlos Araujo Da Silva, Laure Belin, Karine Longchambon, Nicolas Seeboth
  • Publication number: 20100317795
    Abstract: A rubber composition based on at least one diene elastomer, containing less than 2 phr of zinc, phr meaning parts per hundred parts of rubber (elastomer), and based on at least one reinforcing filler and one sulphur-based crosslinking system, comprising a zinc carboxylate of formula: (RCOO)2Zn, in which R represents a hydrocarbon group chosen from cyclic or non-cyclic, linear or branched alkyl groups having 1 to 16 carbon atoms, aryl groups, aralkyl groups or alkaryl groups having 1 to 16 carbon atoms. Also disclosed is a process for preparing such a rubber composition which is suitable for manufacturing tires or semi-finished products made of rubber intended for these tires.
    Type: Application
    Filed: December 21, 2007
    Publication date: December 16, 2010
    Inventors: José Carlos Araujo Da Silva, Anne Veyland
  • Publication number: 20100063189
    Abstract: Rubber composition, especially for a tyre, based on at least one diene elastomer, a reinforcing filler, a crosslinking system and an antioxidant system, wherein said antioxidant system comprises at least two antioxidants “A” and “B”: A. an N-alkyl-N?-phenyl-para-phenylenediamine corresponding to the formula (I): B. a 4,4?-bis(alkylamino)triphenylamine corresponding to the formula (II): in which formulae, R1, R2 and R3, which are identical or different, each represent a linear or branched alkyl group having from 1 to 12 carbon atoms or a cycloalkyl group having from 5 to 8 carbon atoms, the A/B weight ratio being between 0.2 and 5.0. Such an antioxidant system gives the composition of the invention a better long-term resistance to fatigue and to crack propagation.
    Type: Application
    Filed: November 8, 2007
    Publication date: March 11, 2010
    Applicant: Michelin Recherche Et Technique S.A.
    Inventors: José Carlos Araujo Da Silva, Pierre-Antoine Niore, Arnaud Remy
  • Publication number: 20090234066
    Abstract: Tyre and rubber composition for tyre, based on at least one isoprene elastomer (for example natural rubber), an inorganic filler as reinforcing filler (for example silica) and a coupling system which provides the bonding between the said reinforcing inorganic filler and the isoprene elastomer, the said coupling system comprising, in combination: as first coupling agent, a silane sulphide compound; as second coupling agent, an at least bifunctional organosilicon compound (for example an organosilane or an organosiloxane) which can be grafted to the elastomer by means of an azodicarbonyl functional group (—CO—N?N—CO—).
    Type: Application
    Filed: May 11, 2006
    Publication date: September 17, 2009
    Inventors: Jose Carlos Araujo Da Silva, Nathalie Binde, Pierre Robert, Sebastien Sterin, Anne Veyland
  • Publication number: 20090209709
    Abstract: A subject-matter of the present invention is a rubber composition intended for the manufacture of tyres or of tyre semi-finished products, based on at least one isoprene elastomer, an inorganic filler as reinforcing filler and a polyfunctional organosiloxane coupling agent capable of providing the bonding between the reinforcing inorganic filler and the isoprene elastomer, comprising per molecule, grafted to its silicon atoms, on the one hand at least one hydroxyl or hydrolysable functional group allowing it to be grafted to the reinforcing inorganic filler and, on the other hand, at least one group bearing at least one azodicarbonyl functional group —CO—N?N—CO— allowing it to be grafted to the isoprene elastomer.
    Type: Application
    Filed: May 11, 2006
    Publication date: August 20, 2009
    Applicant: Michelin Recherche et Technique S.A.
    Inventors: Jose Carlos Araujo Da Silva, Karine Longchambon, Sabastien Sterin
  • Publication number: 20090186961
    Abstract: Tyre and rubber composition for tyre or tyre semi-finished product, based on at least one isoprene elastomer (for example natural rubber), an inorganic filler as reinforcing filler (for example silica) and a coupling system which provides the bonding between the said reinforcing inorganic filler and the isoprene elastomer, the said coupling system comprising, in combination: a monofunctional covering agent (for example a polyorganosiloxane oil) capable of bonding to the surface functional sites of the inorganic filler; and as coupling agent, an at least bifunctional organosilicon compound (for example an organosilane or an organosiloxane) which can be grafted to the elastomer by means of an azodicarbonyl functional group (—CO—N?N—CO—).
    Type: Application
    Filed: May 11, 2006
    Publication date: July 23, 2009
    Applicant: MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Jose Carlos Araujo Da Silva, Nathalie Binde, Pierre Robert, Sebastien Sterin, Anne Veyland