Patents by Inventor Jose Manuel MARTINEZ MAGADAN

Jose Manuel MARTINEZ MAGADAN has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230399576
    Abstract: The present invention relates to supramolecular surfactants (SS) with detergent-dispersant of heavy organic compounds (deposits and/or organic scales) and corrosion inhibition properties, and methods for preparing these surfactants. The invention also relates to the corresponding uses and applications of these surfactants to prevent and control the formation of deposits in internal combustion machines, as well as to prevent and protect pipelines, tanks, motors and complements of ferrous materials against corrosion where there is contact with liquid hydrocarbons such as gasoline, turbosine, and diesel, where gasoline may contain oxygenated compounds such as ethers and/or alcohols. The supramolecular surfactants are obtained from the self-assembly process between oxazolidines derived from polyalkyl/polyalkenyl N-hydroxyalkyl succinimides with alkyl/alkenyl-amine-propanoic acids and alkyl/alkenyl-amine-di-propanoic acids.
    Type: Application
    Filed: June 2, 2023
    Publication date: December 14, 2023
    Inventors: Ricardo Cerón Camacho, Raúl Oviedo Roa, Jorge Francisco Ramírez Pérez, Enrique Soto Castruita, Rodolfo Cisneros Dévora, David Aaron Nieto Álvarez, José Manuel Martínez Magadan, Ana Graciela Servín Nájera, Luis Silvestre Zamudio Rivera
  • Patent number: 11384187
    Abstract: The present invention is related to the process of obtaining random terpolymers based on itaconic acid or its isomers, aconitic acid or their isomers and sodium alkenyl sulphonates, through a polymerization in aqueous solution, via free radicals at acid pH in the range of 1.0 to 3.5 and as initiator a redox system. The random terpolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium. Their use as inhibitors of mineral scale such as calcium carbonate, calcium sulphate, strontium and barium, and clay dispersing, iron oxides, carbonate and calcium sulfate allows for their application in the reservoir or production rig, treated water, sea water and/or connate water can be used as means of transportation. The terpolymer can be used to inhibit and disperse mineral scales present in cooling system and boiler employed in the chemical and oil industry, and is compliant with environmental standards established internationally.
    Type: Grant
    Filed: March 13, 2015
    Date of Patent: July 12, 2022
    Assignee: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Mirna Pons Jiménez, Raúl Hernández Altamirano, José Manuel Martínez Magadan, Alejandro Ramirez Estrada, Luis Silvestre Zamudio Rivera
  • Patent number: 11046605
    Abstract: Random copolymers from itaconic acid and/or isomers and sodium alkenyl sulfonates are obtained by polymerization in an aqueous solution via free radicals at an acidic pH in the range from 1.0 to 3.5 and with a redox system as initiator were described. The copolymers can be used as calcium carbonate and calcium, strontium and barium sulfates mineral scale inhibitors and as dispersants of clays, iron oxides, calcium carbonate and strontium, barium and calcium sulfates. Random copolymers prevent and control damage in an oil reservoir, obstruction of water injection and crude oil production pipelines, and in production rigs due to mineral scale precipitation caused by high levels of salinity of the injection water and formation water. Random copolymers are tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and can be added to the reservoir and to injection or production pipelines, treated water, sea water and water that is used as means of transportation.
    Type: Grant
    Filed: October 17, 2019
    Date of Patent: June 29, 2021
    Assignee: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Raul Hernandez Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, Erick Emanuel Luna Rojero, Jose Manuel Martinez Magadan, David Aaron Nieto Alvarez, Mirna Pons Jimenez, Alejandro Ramirez Estrada, Maria del Pilar Arzola Garcia
  • Patent number: 11014875
    Abstract: The present disclosure is related to obtaining and using sulfobetaine and hydroxysultaine-based geminal zwitterionic liquids as wettability modifiers for rocks such as limestone, dolomite, sandstone, quartz or heterogeneous lithologies, under the presence of brines having high content of divalent ions as calcium, magnesium, barium and strontium, at high temperature and high pressure conditions for enhanced oil recovery processes to increase the oil production. The geminal zwitterionic liquids of the present disclosure have also the property of acting as corrosion inhibitors of ferrous metals used in pipelines and equipment for crude oil extraction, production, transport and storage operations. A further advantage shown by zwitterionic liquids derived from their molecular structure is they can be dissolved in distilled water, brine, hydrocarbon solvents, aromatics and alcohols.
    Type: Grant
    Filed: November 27, 2015
    Date of Patent: May 25, 2021
    Assignee: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Raül Hernandez Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, César Andrés Flores Sandoval, Alejandro Ramírez Estrada, Rodolfo Cisneros Devora, José Manuel Martínez Magadan, Raúl Oviedo Roa, Jorge Francisco Ramírez Pérez
  • Patent number: 10584048
    Abstract: A process for obtaining random copolymers from itaconic acid and/or isomers and sodium alkenyl sulfonates is by polymerization in an aqueous solution via free radicals at an acidic pH in the range from 1.0 to 3.5 and with a redox system as initiator. The copolymers can be used as calcium carbonate and calcium, strontium and barium sulfates mineral scale inhibitors and as dispersants of clays, iron oxides, calcium carbonate and strontium, barium and calcium sulfates. Random copolymers prevent and control damage in an oil reservoir, obstruction of water injection and crude oil production pipelines, and in production rigs due to mineral scale precipitation caused by high levels of salinity of the injection water and formation water. Random copolymers are tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and can be added to the reservoir and to injection or production pipelines, treated water, sea water and water that is used as means of transportation.
    Type: Grant
    Filed: April 24, 2014
    Date of Patent: March 10, 2020
    Assignee: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Raul Hernandez Altamirano, Violeta Yasmin Mena Cervantes, Luis Silvestre Zamudio Rivera, Erick Emanuel Luna Rojero, Jose Manuel Martinez Magadan, David Aaron Nieto Alvarez, Mirna Pons Jimenez, Alejandro Ramirez Estrada, Maria del Pilar Arzola Garcia
  • Publication number: 20200048123
    Abstract: A process for obtaining random copolymers from itaconic acid and/or isomers and sodium alkenyl sultanates is by polymerization in an aqueous solution via free radicals at an acidic pH in the range from 1.0 to 3.5 and with a redox system as initiator. The copolymers can be used as calcium carbonate and calcium, strontium and barium sulfates mineral scale inhibitors and as dispersants of clays, iron oxides, calcium carbonate and strontium, barium and calcium sulfates. Random copolymers prevent and control damage in an oil reservoir, obstruction of water injection and crude oil production pipelines, and in production rigs due to mineral scale precipitation caused by high levels of salinity of the injection water and formation water. Random copolymers are tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and can be added to the reservoir and to injection or production pipelines, treated water, sea water and water that is used as means of transportation.
    Type: Application
    Filed: October 17, 2019
    Publication date: February 13, 2020
    Inventors: Raul HERNANDEZ ALTAMIRANO, Violeta Yasmin MENA CERVANTES, Luis Silvestre ZAMUDIO RIVERA, Erick Emanuel LUNA ROJERO, Jose Manuel MARTINEZ MAGADAN, David Aaron NIETO ALVAREZ, Mirna PONS JIMENEZ, Alejandro RAMIREZ ESTRADA, Maria del Pilar ARZOLA GARCIA
  • Patent number: 10457863
    Abstract: The present invention refers to the formulation of a foaming agent for extreme conditions of salinity, temperature and concentration of divalent ions, including the improvement in the performance in these conditions with respect to the patent MX2008015989 A. Also, the design is presented of the experimental equipment used to characterize and evaluate foaming agents at laboratory level and conditions of pressure, temperature and salinity, in oil fields. The formulation of the foaming agent derived from this invention is a mixture of sodium alpha olefin sulfonates, alkylamido propyl betaines and triethanolamine, capable of giving it the benefit of being stable in temperature and salinity in a wide range, diluted in synthetic and congenital brines. This formulation is applicable for the control of gas mobility and improved oil recovery processes in naturally fractured reservoirs.
    Type: Grant
    Filed: December 13, 2017
    Date of Patent: October 29, 2019
    Assignee: INSTITUTO MEXICANO DEL PETRÓLEO
    Inventors: Alejandro Ortega Rodríguez, Norma Araceli García Muñoz, José Manuel Martínez Magadán, Raúl Oviedo Roa, Sonia Ángeles Martínez Reyes, Marco Antonio Vélez Domínguez, Maribel Amador Ramírez, Ana Patricia Medina Montiel, Nansy Mónica Sánchez Casas, Elizabeth Cervantes Flores, Agustín Durán Álvarez, Simón López Ramírez, Cecilia de los Ángeles Durán Valencia
  • Patent number: 10442981
    Abstract: The present invention is related to the obtaining and use of zwitterionic geminal liquids based on hydroxypropyl betaine, as wettability modifiers of rocks such as limestone, dolomite, sandstone, quartz or heterogeneous lithologies, in the presence of brines with high content of divalent ions as calcium, magnesium, barium and strontium, at high temperature and high pressure conditions during the application of enhanced oil recovery processes. The zwitterionic geminal liquids based hydroxypropyl betaine of the present invention have also the property of acting as inhibitors/dispersing of asphaltenes, both at extraction and production operations of petroleum industry, thus allowing to increase the level of crude oil production. An additional advantage presented by zwitterionic geminal liquid based on hydroxypropyl betaine which can be dissolved in distilled water, brine, aliphatic hydrocarbons or other polar and nonpolar solvents.
    Type: Grant
    Filed: November 17, 2015
    Date of Patent: October 15, 2019
    Assignee: INSTITUTO MEXICANO DEL PETRÓLEO
    Inventors: Violeta Yázmin Mena Cervantes, Raúl Hernández Altamirano, Luis Silvestre Zamudio Rivera, Alejandro Ramírez Estrada, Jorge Francisco Ramírez Pérez, José Manuel Martínez Magadan, Rodolfo Cisneros Devora
  • Publication number: 20180171215
    Abstract: The present invention refers to the formulation of a foaming agent for extreme conditions of salinity, temperature and concentration of divalent ions, including the improvement in the performance in these conditions with respect to the patent MX2008015989 A. Also, the design is presented of the experimental equipment used to characterize and evaluate foaming agents at laboratory level and conditions of pressure, temperature and salinity, in oil fields. The formulation of the foaming agent derived from this invention is a mixture of sodium alpha olefin sulfonates, alkylamido propyl betaines and triethanolamine, capable of giving it the benefit of being stable in temperature and salinity in a wide range, diluted in synthetic and congenital brines. This formulation is applicable for the control of gas mobility and improved oil recovery processes in naturally fractured reservoirs.
    Type: Application
    Filed: December 13, 2017
    Publication date: June 21, 2018
    Inventors: Alejandro ORTEGA RODRÍGUEZ, Norma Araceli GARCÍA MUÑOZ, José Manuel MARTÍNEZ MAGADÁN, Raúl OVIEDO ROA, Sonia Ángeles MARTÍNEZ REYES, Marco Antonio VÉLEZ DOMÍNGUEZ, Maribel AMADOR RAMÍREZ, Ana Patricia MEDINA MONTIEL, Nansy Mónica SÁNCHEZ CASAS, Elizabeth CERVANTES FLORES, Agustín DURÁN ÁLVAREZ, Simón LÓPEZ RAMÍREZ, Cecilia de los Ángeles DURÁN VALENCIA
  • Publication number: 20170320817
    Abstract: The present invention is related to obtaining and using sulfobetaine and hidroxisultaine-based geminal zwitterionic liquids as wettability modifiers for rocks such as limestone, dolomite, sandstone, quartz or heterogeneous lithologies, under the presence of brines having high content of divalent ions as calcium, magnesium, barium and strontium, at high temperature and high pressure conditions for enhanced oil recovery processes to increase the oil production. The geminal zwitterionic liquids of the present invention have also the property of acting as corrosion inhibitors of ferrous metals used in pipelines and equipment for crude oil extraction, production, transport and storage operations. A further advantage shown by zwitterionic liquids derived from their molecular structure is they can be dissolved in distilled water, brine, hydrocarbon solvents, aromatics and alcohols.
    Type: Application
    Filed: November 27, 2015
    Publication date: November 9, 2017
    Inventors: Raúl HERNÁNDEZ ALTAMIRANO, Violeta Yasmín MENA CERVANTES, Luis Silvestre ZAMUDIO RIVERA, César Andrés FLORES SANDOVAL, Alejandro RAMÍREZ ESTRADA, Rodolfo CISNEROS DEVORA, José Manuel MARTÍNEZ MAGADAN, Raúl OVIEDO ROA, Jorge Francisco RAMÍREZ PÉREZ
  • Publication number: 20170121440
    Abstract: Random terpolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and that for their application in the reservoir or production rig, treated water, sea water and/or connate water can be used as means of transportation. Furthermore, the terpolymer also can be used to inhibit and disperse mineral scales presents in cooling system and boiler employed in the chemical and oil industry. Also, random terpolymers of the present invention have the characteristic of complying with environmental standards established internationally and are classified as particularly non-toxic, so it can be used in pipes and equipment of the petrochemical industry and with the use characteristic freshwater and seawater from offshore and onshore facilities.
    Type: Application
    Filed: March 13, 2015
    Publication date: May 4, 2017
    Applicant: INSTITUTO MEXICANO DEL PETRÓLEO
    Inventors: Mirna PONS JIMÉNEZ, Raúl HERNÁNDEZ ALTAMIRANO, José Manuel MARTÍNEZ MAGADAN, Alejandro RAMIREZ ESTRADA, Luis Silvestre ZAMUDIO RIVERA
  • Patent number: 9469804
    Abstract: A foaming composition with wettability-modifying and corrosion inhibitory properties is used to control the channeling of fluids in naturally fractured carbonate reservoirs, favorably alter the rock wettability in crude oil enhanced recovery processes and control uniform corrosion problems occurring in production rigs under high temperature and ultra-high salinity conditions by the synergistic effect resulting from the supramolecular interaction of alkyl amido propyl hydroxysultaines or alkyl hydroxysultaines with sodium alkyl hydroxysulfonates and sodium alkenyl sulfonates having the formula (1). The foaming compositions with wettability-modifying and corrosion inhibitory properties are tolerant to high concentrations of divalent ions such as calcium, magnesium, strontium and barium and are suitable for use in the reservoir, seawater and/or congenital water characteristic of the reservoir for transporting the crude oil from the reservoir.
    Type: Grant
    Filed: November 25, 2013
    Date of Patent: October 18, 2016
    Assignee: INSTITUTO MEXICO DEL PETROLEO
    Inventors: Raul Hernandez Altamirano, Luis Silvestre Zamudio Rivera, Violeta Yasmin Mena Cervantes, Erick Emanuel Luna Rojero, Enrique Serrano Saldana, Jose Manuel Martinez Magadan, Raul Oviedo Roa, David Aaron Nieto Alvarez, Eduardo Buenrostro Gonzalez, Rodolfo Cisneros Devora, Maria del Pilar Arzola Garcia, Mirna Pons Jimenez, America Elizabeth Mendoza Aguilar, Sung Jae Ko Kim, Jorge Francisco Ramirez Perez, Tomas Eduardo Chavez Miyauchi, Yosadara Ruiz Morales
  • Publication number: 20160168447
    Abstract: The present invention is related to the obtaining and use of zwitterionic geminal liquids based on hydroxypropyl betaine, as wettability modifiers of rocks such as limestone, dolomite, sandstone, quartz or heterogeneous lithologies, in the presence of brines with high content of divalent ions as calcium, magnesium, barium and strontium, at high temperature and high pressure conditions during the application of enhanced oil recovery processes. The zwitterionic geminal liquids based hydroxypropyl betaine of the present invention have also the property of acting as inhibitors/dispersing of asphaltenes, both at extraction and production operations of petroleum industry, thus allowing to increase the level of crude oil production. An additional advantage presented by zwitterionic geminal liquid based on hydroxypropyl betaine which can be dissolved in distilled water, brine, aliphatic hydrocarbons or other polar and nonpolar solvents.
    Type: Application
    Filed: November 17, 2015
    Publication date: June 16, 2016
    Inventors: Violeta Yázmin MENA CERVANTES, Raúl HERNÁNDEZ ALTAMIRANO, Luis Silvestre ZAMUDIO RIVERA, Alejandro RAMÍREZ ESTRADA, Jorge Francisco RAMÍREZ PÉREZ, José Manuel MARTÍNEZ MAGADAN, Rodolfo CISNEROS DEVORA
  • Publication number: 20140319063
    Abstract: A process for obtaining random copolymers from itaconic acid and/or isomers and sodium alkenyl sulfonates is by polymerization in an aqueous solution via free radicals at an acidic pH in the range from 1.0 to 3.5 and with a redox system as initiator. The copolymers can be used as calcium carbonate and calcium, strontium and barium sulfates mineral scale inhibitors and as dispersants of clays, iron oxides, calcium carbonate and strontium, barium and calcium sulfates. Random copolymers prevent and control damage in an oil reservoir, obstruction of water injection and crude oil production pipelines, and in production rigs due to mineral scale precipitation caused by high levels of salinity of the injection water and formation water. Random copolymers are tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and can be added to the reservoir and to injection or production pipelines, treated water, sea water and water that is used as means of transportation.
    Type: Application
    Filed: April 24, 2014
    Publication date: October 30, 2014
    Inventors: Raul HERNANDEZ ALTAMIRANO, Violeta Yasmin MENA CERVANTES, Luis Silvestre ZAMUDIO RIVERA, Erick Emanuel LUNA ROJERO, Jose Manuel MARTINEZ MAGADAN, David Aaron NIETO ALVAREZ, Mirna PONS JIMENEZ, Alejandro RAMIREZ ESTRADA, Maria del Pilar ARZOLA GARCIA
  • Publication number: 20140151041
    Abstract: The present invention relates to a method of obtaining and using foaming compositions with wettability-modifying and corrosion inhibitory properties that control the channeling of fluids in naturally fractured carbonate reservoirs, favorably alter the rock wettability in crude oil enhanced recovery processes and control uniform corrosion problems occurring in production rigs under high temperature and ultra-high salinity conditions by the synergistic effect resulting from the supramolecular interaction of alkyl amido propyl hydroxysultaines or alkyl hydroxysultaines with sodium alkyl hydroxysulfonates and sodium alkenyl sulfonates having the formula (1). The foaming compositions with wettability-modifying and corrosion inhibitory properties are tolerant to high concentrations of divalent ions such as calcium, magnesium, strontium and barium and are suitable for use in the reservoir, seawater and/or congenital water characteristic of the reservoir for transporting the crude oil from the reservoir.
    Type: Application
    Filed: November 25, 2013
    Publication date: June 5, 2014
    Inventors: Raul HERNANDEZ ALTAMIRANO, Luis Silvestre ZAMUDIO RIVERA, Violeta Yasmin MENA CERVANTES, Erick Emanuel LUNA ROJERO, Enrique SERRANO SALDANA, Jose Manuel MARTINEZ MAGADAN, Raul OVIEDO ROA, David Aaron NIETO ALVAREZ, Eduardo BUENROSTRO GONZALEZ, Rodolfo CISNEROS DEVORA, Maria del Pilar ARZOLA GARCIA, Mirna PONS JIMENEZ, America Elizabeth MENDOZA AGUILAR, Sung Jae Ko KIM, Jorge Francisco RAMIREZ PEREZ, Tomas Eduardo CHAVEZ MIYAUCHI