Patents by Inventor Josef K. Rigler

Josef K. Rigler has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4984899
    Abstract: An agitator vessel is equipped with a radially conveying agitator and with at least one baffle, for the thorough mixing of liquids, the at least one baffle has the shape of an airfoil profile and is arranged below the level of liquids and above the blades of the agitator.The agitator vessel is equipped with a radially conveying agitator 3 and at least one baffle 2, the latter having the shape of an airfoil profile.
    Type: Grant
    Filed: June 21, 1989
    Date of Patent: January 15, 1991
    Assignee: Huls AG
    Inventors: Franz-Michael Bollenrath, Josef K. Rigler
  • Patent number: 4618468
    Abstract: A process for controlling bead size in the production of expandable styrene polymers by suspension polymerization is carried out by adding protective colloids to the aqueous phase before polymerization begins, such protective colloids being used which are homogeneously soluble in water over the entire temperature range from 25.degree. to 125.degree. C. and in which the concentration range being employed shall not lower the boundary surface tension water/styrene below 18 N/mm.sup.2. Lastly, the protective colloids are selected according to their molecular weight and the weight ratio of aqueous to organic phase lies in the range of 0.9:1 to 1:1.25, preferably in the range of 1:1. A grain spectrum is maintained predominantly greater than 0.41 to less than 2.5 mm by varying the molecular weights of the protective colloids.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: October 21, 1986
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventors: Josef K. Rigler, Horst Leithauser
  • Patent number: 4609512
    Abstract: A process for controlling bead size in the manufacture of expandable styrene polymers by suspension polymerization, wherein, referred to the aqueous phase, a concentration of ions of calcium, aluminum, metals of the 1st, 2nd, or 6th through 8th side groups of the period table of elements of 3.times.10.sup.31 5 to 3.times.10.sup.-2 % by mass is established, these metal ions being present as cations in the higher oxidation stage of water-soluble, inorganic salts.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: September 2, 1986
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Dirk Reese, Horst Leithauser
  • Patent number: 4517314
    Abstract: Fine particulate expandable styrene polymers suitable for the production of molded bodies with improved minimum mold dwell times, containing 0.01 to 2.0% by weight, referred to the polystyrene or the total of the polymerized monomers, of polyoctenamer having I values from about 10 to 400 ml/g and trans octylene contents from about 20 to 90%.
    Type: Grant
    Filed: October 17, 1984
    Date of Patent: May 14, 1985
    Assignee: Chemische Werke Huls AG
    Inventors: Dirk Reese, Josef K. Rigler
  • Patent number: 4497912
    Abstract: Fine particulate expandable styrene polymers suitable for the production of molded bodies with improved minimum mold dwell times, containing 0.01 to 2.0% by weight, referred to the polystyrene or the total of the polymerized monomers, of polyoctenamer having I values from about 10 to 400 ml/g and trans octylene contents from about 20 to 90%.
    Type: Grant
    Filed: June 18, 1984
    Date of Patent: February 5, 1985
    Assignee: Chemische Werke Huls AG
    Inventors: Dirk Reese, Josef K. Rigler
  • Patent number: 4497911
    Abstract: Process for the production of fine particulate, expandable styrene polymers by suspension-polymerizing styrene or possibly mixtures of styrene and other monomers having at least 50% by weight of styrene in the presence of expanding agents having low boiling points in incompletely filled reactors. The polymer beads to be charged with expanding agents are vigorously stirred during the addition of the expanding agent(s) in such a manner that these beads undergo the least possible contact in time and space with the gas phase and with each other, and so that the surface of the stirred medium retains a topology as free as possible from a funnel shape during stirring.
    Type: Grant
    Filed: July 8, 1982
    Date of Patent: February 5, 1985
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Karl Trukenbrod, Franz-Michael Bollenrath
  • Patent number: 4419458
    Abstract: Fine particulate expandable flame retardant styrene polymers having an improved minimum mold dwell time and reduced block shrinkage are prepared by:(a) mixing together styrene monomer or a mixture of styrene and a cpolymerizable monomer with an organic halogen compound and an expanding agent in an aqueous disperson;(b) adding before or during polymerization to the mixture of (a) from 0.0001 to 0.1% by weight of an epoxidation product of an aliphatic hydrocarbon of which the epoxidated aliphatic chain comprises from 6 to 18 C atoms, this epoxidation product being soluble in the monomers;(c) carrying out a polymerization in the aqueous suspension of (a) and (b) using radical forming initiators at temperatures of 80.degree. C.-130.degree. C. to form expandable particles;(d) pre-forming the expandable particles resulting from (c);(e) ageing the pre-formed particles of (d); and(f) molding the pre-formed and aged particles of (e) in a pressure resistant mold.
    Type: Grant
    Filed: April 19, 1983
    Date of Patent: December 6, 1983
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Ekkehard Wienhofer, Horst Leithauser, Karl Trukenbrod
  • Patent number: 4418156
    Abstract: Fire retardant, expanded styrene polymer shaped objects are prepared by:(a) mixing styrene monomer or a mixture thereof with at least one comonomer, an expanding agent and a fire retardant, organic halogen compound in a aqueous dispersion;(b) adding to (a) either before or during polymerization from about 0.0001 to 0.1 percent by weight esters soluble in the organic phase of (a), these esters of aliphatic dicarboxylic acids and aliphatic epoxy alcohols having at least 11 carbon atoms;(c) polymerizing the aqueous dispersion of (a) and (b) using radical forming initiators at a temperature of about 80.degree. to 130.degree. C.;(d) separating bead polymers having diameters between about 0.4 and 3 mm;(e) pre-foaming the beads;(f) ageing the pre-foamed beads; and(g) final forming the aged and pre-foamed beads in a pressure resistant mold.
    Type: Grant
    Filed: April 19, 1983
    Date of Patent: November 29, 1983
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Ekkehard Wienhofer, Horst Leithauser, Karl Trukenbrod
  • Patent number: 4407977
    Abstract: Fine particulate expandable flame retardant styrene polymers having an improved minimum mold dwell time and reduced block shrinkage are prepared by:(a) mixing together styrene monomer or a mixture of styrene and a copolymerizable monomer with an organic halogen compound and an expanding agent in an aqueous dispersion;(b) adding before or during polymerization to the mixture of (a) from 0.0001 to 0.1% by weight of an expoxidation product of an aliphatic hydrocarbon of which the epoxidated aliphatic chain comprises from 6 to 18 C atoms, this epoxidation product being soluble in the monomers;(c) carrying out a polymerization in the aqueous suspension of (a) and (b) using radical forming initiators at temperatures of 80.degree. C.-130.degree. C. to form expandable particles;(d) pre-forming the expandable particles resulting from (c);ageing the pre-formed particles of (d); and(f) molding the pre-formed and aged particles of (e) in a pressure resistant mold.
    Type: Grant
    Filed: May 20, 1982
    Date of Patent: October 4, 1983
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventors: Josef K. Rigler, Ekkehard Wienhofer, Horst Leithauser, Karl Trukenbrod
  • Patent number: 4393146
    Abstract: Fire retardant, expanded styrene polymer shaped objects are perpared by:(a) mixing styrene monomer or a mixture thereof with at least one comonomer, an expanding agent and a fire retardant, organic halogen compound in a aqueous dispersion;(b) adding to (a) either before or during polymerization from about 0.0001 to 0.1 percent by weight esters soluble in the organic phase of (a), these esters of aliphatic dicarboxylic acids and aliphatic epoxy alcohols having at least 11 carbon atoms;(c) polymerizing the aqueous dispersion of (a) and (b) using radical forming initiators at a temperature of about 80.degree. to 130.degree. C.;(d) separating bead polymers having diameters between about 0.4 and 3 mm;(e) pre-foaming the beads;(f) ageing the pre-foamed beads; and(g) final forming the aged and pre-foamed beads in a pressure resistant mold.
    Type: Grant
    Filed: May 20, 1982
    Date of Patent: July 12, 1983
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Ekkehard Wienhofer, Horst Leithauser, Karl Trukenbrod
  • Patent number: 4337319
    Abstract: Self-extinguishing, fine particulate, expandable styrene polymers for the manufacture of molded articles, containing bromine compounds and one synergist. The synergist, referred to the styrene polymer, is at least one hydrocarbon present in amounts from about 0.1 to 3% by weight and forms stable radicals at temperatures above 300.degree. C.
    Type: Grant
    Filed: November 12, 1980
    Date of Patent: June 29, 1982
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Hans-Josef Ratajczak, Horst Leithauser, Karl Trukenbrod
  • Patent number: 4286071
    Abstract: Self-extinguishing, fine particulate, expandable styrene polymers for the manufacture of molded articles, containing bromine compounds and one synergist. The synergist, referred to the styrene polymer, is at least one hydrocarbon present in amounts from about 0.1 to 3% by weight and forms stable radicals at temperatures above 300.degree. C.
    Type: Grant
    Filed: January 30, 1980
    Date of Patent: August 25, 1981
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Hans-Josef Ratajczak, Horst Leithauser, Karl Trukenbrod
  • Patent number: 4255525
    Abstract: Small particulate expandable styrene polymer molding compositions are prevented from acquiring static charges by coating with betaines.
    Type: Grant
    Filed: August 29, 1979
    Date of Patent: March 10, 1981
    Assignee: Chemische Werhe Huls AG
    Inventors: Josef K. Rigler, Wolfgang Schafer, Horst Leithauser, Karl Trukenbrod, Werner Bollmann
  • Patent number: 4228244
    Abstract: The process for the preparation of shaped bodies based on expanded styrene polymers comprising: the polymerization of styrene or a mixture thereof with at least one monomer copolymerizable therewith, the addition of an expanding agent, pre-forming of the resulting expandable particles, ageing of the pre-formed particles, and molding thereof in a pressure resistant mold, is improved in the decrease of the minimum mold dwell time by carrying the polymerization in the presence of 0.0005 to less than 0.01% by weight based on the styrene polymer of organic bromine compounds which give a chain transfer constant of at least 200 and at 100.degree. C. in bidistilled water the bromine compounds split off less than one molar % of hydrogen bromide per equivalent of bromine present in the molecule.
    Type: Grant
    Filed: August 29, 1979
    Date of Patent: October 14, 1980
    Assignee: Chemische Werke Huls AG
    Inventors: Josef K. Rigler, Horst Leithauser, Karl Trukenbrod, Werner Ogrzewalla