Abstract: The present invention relates to coating compositions in pulverulent form which are solid below 30.degree. C. and liquid above 150.degree. C. and containA) 10 to 99 parts by weight of a copolymer component containing at least one copolymer which is prepared from olefinically unsaturated compounds, has a weight average molecular weight of 1500 to 75,000 and contains in chemically bound form(i) 1 to 30% by weight of cyclic carboxylic acid anhydride groups (calculated as C.sub.4 H.sub.2 O.sub.3) and(ii) 0.3 to 10% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O), andB) 1 to 90 parts by weight of a polyol component containing at least one organic polyol having at least two hydroxyl groups per molecule,provided that for every anhydride group of component A) there are 0.1 to 10 hydroxyl groups of component B).

Abstract: The present invention relates to heat-curable coating compositions containingA) a prepolymer having an average of 2-4 ketoxime-blocked NCO groups, having an average moleculer weight of 500-15,000 and prepared from aliphatic, cycloaliphatic and aromatic polyisocyanates and one or more polyhydroxy components which contain 0 to 30% by weight of ethylene oxide units andB) a crosslinking agent of the formula ##STR1## wherein R and R.sup.1 represent H or C.sub.1 -C.sub.4 -alkyl, the ratio of equivalents of blocked NCO groups in A) to NH.sub.2 groups in B) being 1.35:1 to 0.

Abstract: The present invention relates to binder compositions containingA) 10 to 99 parts by weight of a copolymer component containing at least one copolymer prepared from olefinically unsaturated compositions having a weight average molecular weight of 1,500 to 75,000 and having in chemically bound form both(i) 1 to 30% by weight of cyclic carboxylic anhydride groups (calculated as C.sub.4 H.sub.2 O.sub.3) and(ii) 1 to 29% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O) andB) 1 to 90 parts by weight of a hydroxyl component containing at least one organic polyol having at least two hydroxyl groups per molecule,provided that for every anhydride group of component A) there are 0.1 to 10 hydroxyl groups of component B).

Abstract: Solutions of a) a fluorine-containing polyisocyanate in b) an isocyanate-inert solvent are used to impart water, oil and dirt resistance to porous inorganic substrates impregnated therewith. The fluorine-containing polyisocyanate is preferably selected from fluorine-containing polyisocyanates having a fluorine content in the form of perfluorinated alkyl groups of from about 15 to about 60% by weight and an isocyanate content of from about 0.5 to about 15% by weight. These isocyanates are obtained by reaction of (cyclo)aliphatic isocyanates with fluorine-containing mono- and polyhydric alcohols, and selected fluorine-containing alcohols suitable for the production of these polyisocyanates.

Abstract: The present invention relates to coating compositions containing(A) 70 to 98% by weight, based on the sum of components (A) and (B), of(a) isocyanate-free polymers of ethylenically unsaturated monomers and/or polyurethanes or blocked isocyanate prepolymers, and(b) optional organic solvents,wherein component (A) contains no significant quantities of groups capable of reacting with component (B) or starting materials thereof and has a viscosity (at 23.degree. C.) of 2000 to 100,000 mPa.s;(B) 2 to 30% by weight, based on the sum of components (A) and (B), of a polyaddition product prepared in and dispersed in component (A), wherein the polyaddition product is a polyurethane, polyurethane urea, polyurea, or mixture thereof, containing ionic groups and/or potentially ionic groups in a quantity corresponding to from 0.

Abstract: The present invention relates to a composition which is suitable for the preparation of coatings, sealants and/or fillers and contains one or more binder components and as reactive thinner an octadienyl ether which may contain ester groups and which has a viscosity at 23.degree. C. of at most 5,000 mPas and a content of 1 to 80% by weight of octadienyl groups, --C.sub.8 H.sub.13, 0 to 35% by weight of hydroxyl groups and 0 to 30% by weight of carboxyl groups.

Abstract: The present invention relates to a process for the production of polyisocyanates containing uretdione and/or isocyanurate groups bya) partially oligomerizing the isocyanate groups of organic diisocyanates to form uretdione and/or isocyanurate groups in the presence of catalysts containing trivalent phosphorus,b) terminating the oligomerization reaction at the desired degree of oligomerization by converting the catalyst into a catalytically inactive oxidized form by the addition of an oxidizing agent andc) subsequently removing unreacted diisocyanate by thin-layer distillation.The present invention also relates to the polyisocyanates containing uretdione and/or isocyanurate groups obtained by this process.Finally, the present invention also relates to the use of these polyisocyanates, optionally blocked with blocking agents for isocyanate groups, as the isocyanate component in polyurethane coating compositions.

Abstract: The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containinga) a polyisocyanate component andb) an isocyanate-reactive component containing at least one compound corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.1 and R.sup.2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less andn represents an integer with a value of at least 2,and curing the coating composition at a temperature of 100.degree. C. or less.

Abstract: The present invention is directed to a process for the preparation of amines containing urethane and urea groups. The amines are produced by reacting A) isocyanate prepolymers containing urethane groups and in which the isocyanate groups are reversibly blocked with secondary monoamines with B) amines having molecular weights of from 60 to 500, which are at least difunctional and which have a total of at least two primary or secondary amino groups, with splitting off of the secondary monoamine. The invention is also directed to the amines so produced and to the use as a hardener for an epoxide resin.

Abstract: The present invention relates to a binder composition containinga) 20 to 70% by weight of oligomerization products of 1,6-diisocyanatohexane, the oligomerization products having isocyanate groups at least partially blocked with blocking agents for isocyanate groups and containing at least 50% by weight, based on the weight of the oligomerization products, of blocked uretdione diisocyanates corresponding to formula (I) ##STR1## wherein R represents the residue formed by removal of the active hydrogen atom from a monofunctional blocking agent, andb) 30 to 80% by weight of a polyol component containing a mixture ofb1) 100 parts by weight of an alkoxylation product of bisphenol A corresponding to formula (II) ##STR2## wherein R' is hydrogen or a methyl group and n is a whole or fractional number from 1 to 2,b2) 20 to 200 parts by weight castor oil andb3) 0 to 40 parts by weight of other organic polyhydroxyl compounds.

Abstract: The present invention relates to compositions suitable for use as binders and containingA) 10 to 99 parts by weight of at least one copolymer which has a weight average molecular weight of 1500 to 75,000, is prepared from olefinically unsaturated compounds and containsi) 0.1 to 8.0% by weight of free hydroxyl groups andii) 1 to 29% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O) andB) 1 to 90 parts by weight of at least one organic polyanhydride containing at least two cyclic carboxylic acid anhydride groups per molecule,provided that 0.1 to 10 anhydride groups of component B) are present for each epoxide group of component A).The invention also relates to the use of the binder compositions as binders for thermosetting coating or sealing compositions, or, in the presence of catalysts, as binders for coating or sealing compositions which can be hardened at room temperature.

Abstract: The present invention relates to bis-oxazolidines corresponding to formula (II) ##STR1## wherein R represents a branched, saturated, aliphatic hydrocarbon radical containing 5 to 8 carbon atoms.The present invention also relates to oxazolidine mixtures, which are also suitable as hardeners for plastics precursors containing isocyanate groups, consisting essentially ofa) bis-oxazolidines corresponding to formula (II) above andb) 0.03 to 0.3 moles per mole of component (a), of compounds corresponding to formula (III) ##STR2## wherein R represents a saturated, branched, aliphatic hydrocarbon radical containing 5 to 8 carbon atoms.The present invention additionally relates to a process for the production of these oxazolidine mixtures and to their use in combination with polymer precursors containing isocyanate groups for coating or sealing compositions.

Abstract: The present invention relates to a process for the preparation of a coating composition bya) treating moisture-containing auxiliaries and additives at 60.degree. to 120.degree. C. with urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight andb) after completion of the isocyanate/water reaction, combining the mixture obtained in step a) with iscyanate prepolymers having (cyclo)aliphatically bound isocyanate groups.The present invention also relates to the coating composition obtained by this process and to a composition containing urethane group-containing isocyanates having (cyclo)aliphatically bound isocyanate groups, an (average) NCO functionality of 0.8 to less than 2.0 and an NCO content of 5 to 17% by weight and moisture-containing auxiliaries or additives.

Abstract: The present invention is directed to a process for the production of high-gloss patent leather from two-component polyurethane compositions by reacting hydroxyl group-containing oligourethanes with polyisocyanates, characterized in that the oligourethanes have been synthesized fromA) at least 2 macrodiols in a molar ratio of about 1:6 to 6:1 wherein1) the first macrodiol has an average molecular weight of 254 to about 650 and contains an aromatic ring or a saturated or unsaturated cycloaliphatic ring and2) the second macrodiol has an average molecular weight of about 1,200 to 3,000, provided that the molecular weight of macrodiol A/2 is at least 3 times the molecular weight of macrodiol A/1, andB) at least one diisocyanate,wherein the macrodiol:diisocyanate molar ratio is about 1.0:0.9 to 1.0:0.3.The present invention is also directed to the high-gloss patent leather prepared in accordance with the above process.

Abstract: The present invention relates to isocyante prepolymers containing ether and ester groups, having an isocyanate content of 1.9% to 25% by weight and based on the reaction product ofA) a polyisocyanate component containing at least one organic polyisocyanate having an average molecular weight of 168 to 1000,B) an organic polyhydroxyl component containing at least one polyhydroxyl compound containing ether and ester groups, having an average hydroxyl functionality of 2 to 3 and an average hydroxyl number of 40 to 90 and based on the esterification products ofi) polyether polyols having an average hydroxyl number of 200 to 600 withii) from 25 to 67 equivalent-%, based on the hydroxyl groups of component (i) and the carboxyl groups of component (ii), of an organic carboxylic acid component containing at least one organic monocarboxylic acid or a mixture of at least one organic monocarboxylic acid with up to 20 carboxyl equivalent-%, based on all the carboxylic acids, of polybasic organic carboxylic acids.

Abstract: The present invention relates to a process for the production of isocyanurate group-containing polyisocyanates by partially trimerizing the isocyanate groups of (cyclo)aliphatic diisocyanates in the presence of catalysts which accelerate the trimerization of isocyanate groups and optionally in the presence of an inert solvent, terminating the trimerization reaction at the desired degree of trimerization and removing unreacted starting diisocyanate and any other volatile constituents, characterized in that at least one monohydric alcohol containing ester groups corresponding to the formula ##STR1## is added to the reaction mixture prior to removing the excess starting diisocyanate in a quantity of 1 to 30% by weight, based on the weight of the diisocyanate starting material, and reacted with a portion of the isocyanate groups to form urethane groups, provided that after the trimerization and urethanization reactions, the reaction mixture contains at least 10% by weigth of unreacted starting diisocyanate, based

Abstract: The present invention relates to polyisocyanate mixtures prepared from 1,6-diisocyanatohexane (HDI) and 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethyl cyclohexane (IPDI), which have a uretdione content (calculated as C.sub.2 N.sub.2 O.sub.2) of 8 to 25% by weight and an isocyanurate content (calculated as C.sub.3 N.sub.3.sub.O.sub.3) of not more than 24% by weight and containa) 20 to 60% by weight of uretdione diisocyanatesb) 0 to 40% by weight of isocyanurate triisocyanatesc) 15 to 60% by weight of higher homologues of the polyisocyanates of components a) and b) containing more than one uretdione ring and/or isocyanurate ring andd) a total of not more than 1% by weight of (HDI) and (IPDI).The present invention also relates to a process for the preparation of these polyisocyanate mixtures and to their use, optionally blocked with blocking agents for isocyanate groups, as the isocyanate component in polyurethane coating compositions.

Abstract: This present invention relates to a process for the preparation of O-silylated aliphatic hydroxyl, compounds by the reaction of aliphatic hydroxyl compounds with triorganochlorosilanes and removal of the resulting gaseous hydrogen chloride from the reaction mixture, characterized in that the reaction is carried out in the presence of phase transfer catalysts in the absence of solvent.The invention also relates to the use of the O-silylated hydroxyl compounds obtained by this process as starting materials for the preparation of isocyanates containing ester groups by a reaction with isocyanato carboxylic acid chlorides.

Abstract: Binders for moisture-hardening coating or sealing compositions contain modified copolymers having a weight average molecular weight of from 1,500 to 75,000 determined by gel permeation chromatography of olefinically unsaturated compounds containing chemically incorporated moieties which are addition-reactive to amino wherein the modified copolymers contain both(i) intramolecular carboxylic anhydride moieties and(ii) olefinically unsaturated (meth)acrylate moieties in chemically bound form as the moieties which are addition-reactive to amino, with the anhydride equivalent weight being in the range from 392 to 9,800 and the (meth)acrylate equivalent weight in the range from 284 to 7,100.

Abstract: The present invention is directed to a diisocyanate which corresponds to the formula ##STR1## The present invention is also directed to the preparation of this diisocyanate and to its use for the production of polyisocyanate polyaddition products.