Abstract: A waterborne precursor polymer dispersion composition comprising the reaction product obtained by free-radical emulsion polymerization of a monomer mixture comprising: (A) at least one alkyl (meth)acrylate; and (B) at least one ethylenically unsaturated compound comprising: (Bi) at least one first functional group; wherein the at least one first functional group comprises at least one ethylenically unsaturated group; and (Bii) at least one second functional group; wherein the at least one second functional group comprises at least one functional group different than the ethylenically unsaturated group; wherein the second functional group is capable of reacting with a crosslinker component; and wherein the crosslinker component is not reactive with component (A) in free-radical polymerization; in the presence of: (C) an aqueous medium; and (D) at least one acid surfactant salt with pKaH from 2.

Abstract: The present invention provides a method of preparing a furan derivative comprising the steps of (a) converting a monosaccharide to provide a keto-intermediate product; and (b) dehydrating the keto-intermediate product to provide a furan derivative; wherein the keto-intermediate product is pre-disposed to forming keto-furanose tautomers in solution. The method may further comprise a step of oxidizing the furan derivative to provide a furandicarboxylic acid or a furandicarboxylic acid derivative.

Abstract: Pressure sensitive adhesive compositions are disclosed comprising acrylic emulsions that are emulsion polymerization products of (a) a monomer mixture comprising, based on the total weight of monomers in the monomer mixture, from 50 to 99 weight percent 2-ethylhexyl acrylate and from 1 to 50 weight percent an unsaturated monomer, (b) a surfactant, and (c) an initiator. Methods for preparing pressure sensitive adhesive compositions are also disclosed. Food contact articles comprising the disclosed pressure sensitive adhesive compositions are also disclosed. In some embodiments, the disclosed food contact articles have an overall migration of less than 25 mg/dm2, as measured in accordance with EN 1186, or less than 10 mg/dm2, as measured in accordance with EN 1186.

Abstract: The present disclosure is directed to a water-based adhesive composition. In an embodiment, the water-based pressure-sensitive adhesive composition includes a plurality of particles having a polymodal particle size distribution. The particles are composed of (A) a first polymer, and (B) a second polymer different than the first polymer. The particles have a d50 greater than 450 nm and a polydispersity index, PDi, from 0.5 to 2.0. (C) The composition has a solids content greater than or equal to 65.5 wt %. Further disclosed are articles with the water-based pressure-sensitive adhesive composition.

Abstract: The present disclosure is directed to a water-based pressure-sensitive adhesive composition. In an embodiment, the water-based pressure-sensitive adhesive composition includes (A) an acrylic dispersion composed of particles of (i) an acrylic-based polymer with a glass transition temperature (Tg) less than ?20° C., and (ii) a surfactant. The water-based pressure-sensitive adhesive composition also includes (B) an ethylene-based polymer dispersion comprising an ethylene and vinyl acetate copolymer and an ethylene acid copolymer. Further disclosed are articles with the water-based pressure-sensitive adhesive composition.

Abstract: The present disclosure is directed to a water-based pressure-sensitive adhesive composition. In an embodiment, the water-based pressure-sensitive adhesive composition includes (A) an acrylic dispersion composed of particles of (i) an acrylic-based polymer with a glass transition temperature (Tg) less than -20° C., and (ii) a surfactant. The water-based pressure-sensitive adhesive composition also includes (B) an ethylene ester dispersion composed of (i) particles of an ethylene ester copolymer having from 1 wt % to less than 50 wt% acrylate comonomer, and (ii) a dispersant. Further disclosed are articles with the water-based pressure-sensitive adhesive composition.

Abstract: The present disclosure is directed to a water-based pressure-sensitive adhesive composition. In an embodiment, the water-based pressure-sensitive adhesive composition includes (A) an acrylic dispersion composed of particles of (i) an acrylic-based polymer with a glass transition temperature (Tg) less than -20° C., and (ii) a surfactant. The water-based pressure-sensitive adhesive composition also includes (B) an ethylene vinyl acetate (EVA) dispersion comprising (i) particles of an ethylene and vinyl acetate copolymer having from 10 wt% to less than 50 wt% vinyl acetate comonomer, and (ii) a dispersant. Further disclosed are articles with the water-based pressure-sensitive adhesive composition.

Abstract: The present disclosure is directed to a water-based pressure-sensitive adhesive composition. In an embodiment, the water-based pressure-sensitive adhesive composition includes (A) an acrylic dispersion composed of particles of (i) an acrylic-based polymer with a glass transition temperature (Tg) less than ?20° C., and (ii) a surfactant. The water-based pressure-sensitive adhesive composition also includes (B) an ethylene acid dispersion composed of (i) particles of an ethylene acid copolymer having from 3 wt % to less than 50 wt % acid comonomer and a melt index from 1 g/10 min to 100 g/10 min, and (ii) at least one of a dispersant or a neutralizing agent. Further disclosed are articles with the water-based pressure-sensitive adhesive composition.

Abstract: Adhesive compositions are disclosed comprising acrylic copolymers formed from a monomer mixture comprising, based on the total weight of monomers in the monomer mixture, from 59 to 97.9 weight percent 2-ethylhexyl acrylate, from 0.1 to 10 weight percent styrene, from 0 to 25 weight percent methyl methacrylate, and from 2 to 30 weight percent ethyl acrylate, wherein the ratio of ethyl acrylate to styrene (by weight) is greater than 4.5 to 1. Methods for preparing adhesive compositions are disclosed comprising feeding an aqueous initial charge to a reactor, heating the aqueous initial charge to from about 30 to 110° C., gradually feeding a monomer mixture into the reactor over a period of time (less than 3 hours), in the presence of a free-radical polymerization initiator, thereby forming the acrylic adhesive composition, wherein the amount of free monomer in the reactor does not exceed 17 percent by weight, based on the total weight of the reactor contents, during gradual feeding.

Abstract: Provided is a pressure sensitive adhesive article comprising (a) a substrate (Sa) (b) in contact with the substrate (Sa), a layer (Lb) of a pressure sensitive composition (Cb) that comprises one or more acrylic polymer (POLb) having Tg of 20° C. or lower, and (c) in contact with the layer (Lb), a layer (Lc) that comprises, (i) one or more acrylic polymer (POLc1) having Tg of 20° C. or lower, and (ii) one or more acrylic tackifier polymer having Tg of ?10° C. or higher. Also provided are a method of making the pressure sensitive adhesive article and a bonded article made by using the pressure sensitive adhesive article.

Abstract: A tackifier polymeric additive including an emulsion polymerization reaction product of: (a) at least one aromatic monomer; (b) at least one acrylate or methacrylate monomer; and (c) at least one chain transfer agent; and a tackified acrylic adhesive composition including (I) at least one acrylic adhesive polymer; and (II) the above tackifier polymeric additive.

Abstract: The Notice states that an abstract of the technical disclosure is required. In response, Applicant submits herewith a Preliminary Amendment including an abstract in compliance with 37 CFR § 1.72(b). The abstract is based on that submitted in parent U.S. application Ser. No. 15/556,084 (issued as U.S. Pat. No. 11,193,106) and international application no. PCT/US2016/020621, of which U.S. application Ser. No. 15/556,084 is the US national stage application. The submitted abstract differs from the abstract of the parent application only by a correction of “may further comprising” to “may further comprise”. Thus, the abstract contains no new matter.

Abstract: The present invention provides a method of preparing a furan derivative comprising the steps of (a) converting a monosaccharide to provide a keto-intermediate product; and (b) dehydrating the keto-intermediate product to provide a furan derivative; wherein the keto-intermediate product is pre-disposed to forming keto-furanose tautomers in solution. The method may further comprising a step of oxidizing the furan derivative to provide a furandicarboxylic acid or a furandicarboxylic acid derivative.

Abstract: Pressure sensitive adhesive compositions are disclosed comprising acrylic emulsions that are emulsion polymerization products of (a) a monomer mixture comprising, based on the total weight of monomers in the monomer mixture, from 50 to 99 weight percent 2-ethylhexyl acrylate and from 1 to 50 weight percent an unsaturated monomer, (b) a surfactant, and (c) an initiator. Methods for preparing pressure sensitive adhesive compositions are also disclosed. Food contact articles comprising the disclosed pressure sensitive adhesive compositions are also disclosed. In some embodiments, the disclosed food contact articles have an overall migration of less than 25 mg/dm2, as measured in accordance with EN 1186, or less than 10 mg/dm2, as measured in accordance with EN 1186.

Abstract: Adhesive compositions are disclosed comprising acrylic copolymers formed from a monomer mixture comprising, based on the total weight of monomers in the monomer mixture, from 59 to 97.9 weight percent 2-ethylhexyl acrylate, from 0.1 to 10 weight percent styrene, from 0 to 25 weight percent methyl methacrylate, and from 2 to 30 weight percent ethyl acrylate, wherein the ratio of ethyl acrylate to styrene (by weight) is greater than 4.5 to 1. Methods for preparing adhesive compositions are disclosed comprising feeding an aqueous initial charge to a reactor, heating the aqueous initial charge to from about 30 to 110° C., gradually feeding a monomer mixture into the reactor over a period of time (less than 3 hours), in the presence of a free-radical polymerization initiator, thereby forming the acrylic adhesive composition, wherein the amount of free monomer in the reactor does not exceed 17 percent by weight, based on the total weight of the reactor contents, during gradual feeding.

Abstract: The present invention provides a method of preparing a furan derivative comprising the steps of (a) converting a monosaccharide to provide a keto-intermediate product; and (b) dehydrating the keto-intermediate product to provide a furan derivative; wherein the keto-intermediate product is pre-disposed to forming keto-furanose tautomers in solution. The method may further comprising a step of oxidizing the furan derivative to provide a furandicarboxylic acid or a furandicarboxylic acid derivative.

Abstract: The present disclosure provides methods to produce ketones suitable for use as fuels and lubricants by catalytic conversion of an acetone-butanol-ethanol (ABE) fermentation product mixture that can be derived from biomass.

Abstract: The present disclosure generally relates to the catalytic conversion of alcohols into hydrocarbon ketones suitable for use as fuels. More specifically, the present disclosure relates to the catalytic conversion of a mixture of isopropanol-butanol-ethanol (IBE) or acetone-butanol-ethanol (ABE), into ketones suitable for use as fuels. The ABE or IBE mixtures may be obtained from the fermentation of biomass or sugars.

Abstract: Methods for providing effective, efficient and convenient ways of producing 2,5-furandicarboxylic acid are presented. In addition, compositions of 2,5-furandicarboxylic acid including 2,5-furandicarboxylic acid and at least one byproduct are presented. In some aspects, 4-deoxy-5-dehydroglucaric acid is dehydrated to obtain the 2,5-furandicarboxylic acid. A solvent, catalyst, and/or reactant may be combined with the 4-deoxy-5-dehydroglucaric acid to produce a reaction product including the 2,5-furandicarboxylic acid. In some arrangements, the reaction product may additionally include water and/or byproducts.

Abstract: Methods for providing effective, efficient and convenient ways of producing 2,5-furandicarboxylic acid, are presented, in addition, compositions of 2,5-furandicarboxylic acid including 2;5-furandicarboxylic acid and at least one byproduct are presented. In some aspects, 4-deoxy-5-dehydroglucaric acid is dehydrated to obtain the 2,5-furandicarboxylic acid, A solvent catalyst and/or reactant may be combined with the 4-deoxy-5-dehydroglucaric acid to produce a reaction product including the 2,5-furandicarboxylic acid. In some arrangements, the reaction product may additionally include water and/or byproducts.