Patents by Inventor Joseph David Rigney
Joseph David Rigney has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8512874Abstract: A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.Type: GrantFiled: June 4, 2007Date of Patent: August 20, 2013Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney, Gillion Herman Marijnissen, Eric Richard Irma Carolus Vergeldt, Annejan Bernard Kloosterman
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Publication number: 20120282485Abstract: Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases maybe: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.Type: ApplicationFiled: July 10, 2012Publication date: November 8, 2012Applicant: General Electric CompanyInventors: Benard Patrick Bewlay, Pazhayannur Ramanathan Subramanian, Joseph David Rigney, Richard Didomizio, Voramon Supatarawanich Dheeradhada
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Patent number: 8247085Abstract: Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases may be: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.Type: GrantFiled: November 21, 2008Date of Patent: August 21, 2012Assignee: General Electric CompanyInventors: Bernard Patrick Bewlay, Pazhayannur Ramanathan Subramanian, Joseph David Rigney, Richard DiDomizio, Voramon Supatarawanich Dheeradhada
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Patent number: 8039116Abstract: Nb—Si based alloy articles comprising a Nb—Si based alloy upon which is disposed an environmentally-resistant coating are described. They include a coating comprising at least one phase selected from the group consisting of M(Al,Si)3, M5(Al,Si)3, and M3Si5Al2, wherein M is one or more of Nb, Ti, Hf, Cr. Such coating can improve the environmental (e.g., in oxidation-promoting environments) resistance of a Nb—Si based alloy and alloy articles. Methods for preparing these articles are described as well.Type: GrantFiled: August 8, 2007Date of Patent: October 18, 2011Assignee: General Electric CompanyInventors: Bernard Patrick Bewlay, Ramgopal Darolia, Voramon Supatarawanich Dheeradhada, Richard DiDomizio, Michael Francis Xavier Gigliotti, Joseph David Rigney, Pazhayannur Ramanathan Subramanian
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Patent number: 7981520Abstract: A coating suitable for use as protective oxide-forming coatings on Nb-based substrates, and particularly monolithic niobium-based alloys, exposed to high temperatures and oxidative environments. The coating contains aluminum, may further contain silicon, and optionally contains niobium, titanium, hafnium, and/or chromium, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. The intermetallic phases may be M(Al,Si)3, M5(Al,Si)3, and/or M3Si5Al2 where M is niobium, titanium, hafnium, and/or chromium.Type: GrantFiled: September 26, 2008Date of Patent: July 19, 2011Assignee: General Electric CompanyInventors: Bernard Patrick Bewlay, Pazhayannur Ramanathan Subramanian, Joseph David Rigney, Richard DiDomizio, Voramon Supatarawanich Dheeradhada
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Publication number: 20110146848Abstract: Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases may be: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.Type: ApplicationFiled: November 21, 2008Publication date: June 23, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Bernard Patrick Bewlay, Pazhayannur Ramanathan Subramanian, Joseph David Rigney, Richard DiDomizio, Voramon Supatarawanich Dheeradhada
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Publication number: 20110003170Abstract: A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.Type: ApplicationFiled: June 4, 2007Publication date: January 6, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Ramgopal Darolia, Joseph David Rigney, Gillion Herman Marijnissen, Eric Richard Irma Carolus Vergeldt, Annejan Bernard Kloosterman
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Publication number: 20090042056Abstract: A coating suitable for use as protective oxide-forming coatings on Nb-based substrates, and particularly monolithic niobium-based alloys, exposed to high temperatures and oxidative environments. The coating contains aluminum, may further contain silicon, and optionally contains niobium, titanium, hafnium, and/or chromium, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. The intermetallic phases may be M(Al,Si)3, M5(Al,Si)3, and/or M3Si5Al2 where M is niobium, titanium, hafnium, and/or chromium.Type: ApplicationFiled: September 26, 2008Publication date: February 12, 2009Applicant: GENERAL ELECTRIC COMAPNYInventors: Bernard Patrick Bewlay, Pazhayannur Ramanathan Subramanian, Joseph David Rigney, Richard DiDomizio, Voramon Supatarawanich Dheeradhada
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Publication number: 20090042054Abstract: Nb—Si based alloy articles comprising a Nb—Si based alloy upon which is disposed an environmentally-resistant coating are described. They include a coating comprising at least one phase selected from the group consisting of M(Al,Si)3, M5(Al,Si)3, and M3Si5Al2, wherein M is one or more of Nb, Ti, Hf, Cr. Such coating can improve the environmental (e.g., in oxidation-promoting environments) resistance of a Nb—Si based alloy and alloy articles. Methods for preparing these articles are described as well.Type: ApplicationFiled: August 8, 2007Publication date: February 12, 2009Inventors: Bernard Patrick Bewlay, Ramgopal Darolia, Voramon Supatarawanich Dheeradhada, Richard DiDomizio, Michael Francis Xavier Gigliotti, Joseph David Rigney, Pazhayannur Ramanathan Subramanian
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Publication number: 20080142122Abstract: Niobium silicide articles are described. They include a surface region enriched with at least about 25 atom % germanium, which can enhance the properties of the article. Methods for preparing these articles are described as well. According to one method, an article is formed from a niobium silicide composite material which contains a selected amount of germanium. The article is then heat-treated under conditions sufficient to increase the level of germanium in the surface region to at least about 25 atom %, based on the total composition of the surface region. In another embodiment, a germanium-containing material is applied over a niobium-silicide article, and then diffused into the surface region of the article by way of a heat treatment.Type: ApplicationFiled: December 19, 2006Publication date: June 19, 2008Applicant: GENERAL ELECTRICInventors: Bernard Patrick Bewlay, Richard DiDomizio, Pazhayannur Ramanathan Subramanian, Voramon Supatarawanich Dheeradhada, Joseph David Rigney, Ramgopal Darolia
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Patent number: 7335429Abstract: A coating and coating process for incorporating surface features on an air-cooled substrate surface of a component for the purpose of promoting heat transfer from the component. The coating process generally comprises depositing a first metallic coating material on the surface of the component using a first set of coating conditions to form a first environmental coating layer, and then depositing a second metallic coating material using a second set of coating conditions that differ from the first set, such that an outer environmental coating layer is formed having raised surface features that cause the surface of the outer environmental coating layer to be rougher than the surface of the first environmental coating layer.Type: GrantFiled: March 11, 2005Date of Patent: February 26, 2008Assignee: General Electric CompanyInventors: Ching-Pang Lee, Robert Edward Schafrik, Ramgopal Darolia, Joseph David Rigney
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Patent number: 7326441Abstract: A coating and process for depositing the coating on a substrate. The coating is a nickel aluminide overlay coating of predominantly the beta (NiAl) and gamma-prime (Ni3Al) intermetallic phases, and is suitable for use as an environmental coating and as a bond coat for a thermal barrier coating (TBC). The coating can be formed by depositing nickel and aluminum in appropriate amounts to yield the desired beta+gamma prime phase content. Alternatively, nickel and aluminum can be deposited so that the aluminum content of the coating exceeds the appropriate amount to yield the desired beta+gamma prime phase content, after which the coating is heat treated to diffuse the excess aluminum from the coating into the substrate to yield the desired beta+gamma prime phase content.Type: GrantFiled: December 1, 2004Date of Patent: February 5, 2008Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney, Gillion Herman Marijnissen, Eric Richard Irma Carolus Vergeldt, Annejan Bernard Kloosterman
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Patent number: 7318955Abstract: Thermal barrier coating (TBC) and a method of depositing a TBC having a modulated columnar microstructure that exhibits increased impact resistance. The TBC is deposited to have a columnar microstructure in which columns extend from a substrate surface. The columns having inner regions contacting the surface, outer regions near an outermost surface of the TBC, and interior regions therebetween. The inner regions of the columns are substantially normal to the substrate surface and at least one of the interior and outer regions of the columns are nonaligned with its respective inner regions, so that the columns of the columnar microstructure are continuous but modulated between the inner and outer regions to reduce tensile stresses within the columns resulting from particle impact.Type: GrantFiled: September 14, 2004Date of Patent: January 15, 2008Assignee: General Electric CompanyInventors: Ramgopal Darolia, Brett Allen Rohrer Boutwell, Brian Thomas Hazel, Bangalore Aswatha Nagaraj, Joseph David Rigney, Roger D. Wustman
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Patent number: 7264888Abstract: An overlay coating for articles used in hostile thermal environments. The coating has a predominantly gamma prime-phase nickel aluminide (Ni3Al) composition suitable for use as an environmental coating and as a bond coat for a thermal barrier coating. The coating has a composition of, by weight, at least 6% to about 15% aluminum, about 2% to about 5% chromium, optionally one or more reactive elements in individual or combined amounts of up to 4%, optionally up to 2% silicon, optionally up to 60% of at least one platinum group metal, and the balance essentially nickel. A thermal-insulating ceramic layer may be deposited on the coating.Type: GrantFiled: October 29, 2004Date of Patent: September 4, 2007Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney, William Scott Walston
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Patent number: 7244467Abstract: A process for forming a beta-phase nickel aluminide (NiAl) overlay coating that is suitable for use as a bond coat for a thermal barrier coating (TBC). The overlay coating is deposited by a method that produces a generally columnar grain structure in which grains extend through the coating such that at least some grain boundaries are open at the coating surface. The coating is then peened with a particulate media, followed by heating the overlay coating to a temperature sufficient to cause the overlay coating to recrystallize and form new grain boundaries that are not open to the outer surface of the coating and significantly less susceptible to accelerated oxidation than the original grain boundaries. The particulate media is formed of a composition containing nickel and aluminum, such that an oxide scale that forms on the surface of the coating after the peening operation is substantially free of deleterious oxide compounds, notably iron-containing spinels.Type: GrantFiled: July 15, 2003Date of Patent: July 17, 2007Assignee: General Electric CompanyInventors: Theodore Robert Grossman, Ramgopal Darolia, Joseph David Rigney
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Patent number: 7172820Abstract: A strengthened bond coat for improving the adherence of a thermal barrier coating to an underlying metal substrate to resist spallation without degrading oxidation resistance of the bond coat. The bond coat comprises a bond coating material selected from the group consisting of overlay alloy coating materials, aluminide diffusion coating materials and combinations thereof. Particles comprising a substantially insoluble bond coat strengthening compound and having a relatively fine particle size of about 2 microns or less are dispersed within at least the upper portion of the bond coat in an amount sufficient to impart strengthening to the bond coat, and thus limit ratcheting or rumpling thereof.Type: GrantFiled: October 13, 2005Date of Patent: February 6, 2007Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney, Gillion Herman Marijnissen, Eric Richard Irma Carolus Vergeldt, Annejan Bernard Kloosterman
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Patent number: 7163718Abstract: A process for forming diffusion aluminide coatings on an uncoated surface of a substrate, without interdiffusing a sufficient amount of aluminum into a coating layer to adversely affect the coating growth potential and mechanical properties of said coating layer. A metal substrate is provided comprising an external surface and an internal passage therein defined by an internal surface, at least a portion of the external surface of the substrate being coated with a coating layer selected from the group consisting of ?-NiAl-base, MCrAlX, a line-of-sight diffusion aluminide, a non-line-of-sight diffusion aluminide, a pack diffusion aluminide, and a slurry diffusion aluminide on said substrate. The metal substrate is subjected to an aluminum vapor phase deposition process.Type: GrantFiled: October 15, 2003Date of Patent: January 16, 2007Assignee: General Electric CompanyInventors: Nripendra Nath Das, Joseph David Rigney, Jeffrey Allan Pfaendtner, Matthew David Saylor
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Patent number: 7150922Abstract: A beta-phase nickel aluminide (NiAl) overlay coating (24) and method for modifying the grain structure of the coating (24) to improve its oxidation resistance. The coating (24) is deposited by a method that produces a grain structure characterized by grain boundaries (44) exposed at the outer coating surface (36). The grain boundaries (44) may also contain precipitates (40) as a result of the alloyed chemistry of the coating (24). During or after deposition, the overlay coating (24) is caused to form new grain boundaries (34) that, though open to the outer surface (36) of the coating (24), are free of precipitates or contain fewer precipitates (40) than the as-deposited grain boundaries (44). New grain boundaries (34) are preferably produced by causing the overlay coating (24) to recrystallize during coating deposition or after deposition as a result of a surface treatment followed by heat treatment.Type: GrantFiled: December 13, 2002Date of Patent: December 19, 2006Assignee: General Electric CompanyInventors: Irene Spitsberg, Joseph David Rigney, Ramgopal Darolia, Elissa Hae-Kyung Lee, Jeffrey Allan Pfaendtner
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Patent number: 6979498Abstract: A strengthened bond coat for improving the adherence of a thermal barrier coating to an underlying metal substrate to resist spallation without degrading oxidation resistance of the bond coat. The bond coat comprises a bond coating material selected from the group consisting of overlay alloy coating materials, aluminide diffusion coating materials and combinations thereof. Particles comprising a substantially insoluble bond coat strengthening compound and having a relatively fine particle size of about 2 microns or less are dispersed within at least the upper portion of the bond coat in an amount sufficient to impart strengthening to the bond coat, and thus limit ratcheting or rumpling thereof.Type: GrantFiled: November 25, 2003Date of Patent: December 27, 2005Assignee: General Electric CompanyInventors: Ramgopal Darolia, Joseph David Rigney, Gillion Herman Marijnissen, Eric Richard Irma Carolus Vergeldt, Annejan Bernard Kloosterman
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Patent number: 6974637Abstract: An article and TBC coating system thereon that in combination exhibit significantly improved spallation resistance. The article comprises a substrate formed of a metal alloy containing ruthenium and one or more refractory elements (e.g., tantalum, tungsten, molybdenum, rhenium, hafnium, etc.). The substrate is protected by a coating system comprising an aluminum-containing bond coat on the surface of the substrate and a ceramic coating bonded to the substrate by the bond coat. The bond coat, preferably an aluminide, is deposited so as to be substantially free of ruthenium, though ruthenium is present in the bond coat as a result of diffusion from the substrate into the bond coat.Type: GrantFiled: December 19, 2003Date of Patent: December 13, 2005Assignee: General Electric CompanyInventors: Jeffrey Allan Pfaendtner, Deborah A. Schorr, Ramgopal Darolia, Joseph David Rigney, Irene Spitsberg, William Scott Walston