Patents by Inventor Joseph E. Babiarz

Joseph E. Babiarz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8013162
    Abstract: Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of formulae (5)-(7) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: September 6, 2011
    Assignee: Ciba Corporation
    Inventors: Mervin G. Wood, Robert Detlefsen, James Galbo, Wanda Martin, Paul Kondracki, Michael P. DiFazio, Joseph E. Babiarz
  • Patent number: 7947832
    Abstract: Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula (8)-(10) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: May 24, 2011
    Assignee: BASF SE
    Inventors: Mervin G. Wood, Robert Detlefsen, James Galbo, Wanda Martin, Paul Kondracki, Michael P. DiFazio, Joseph E. Babiarz
  • Publication number: 20090199351
    Abstract: Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula (8)-(10) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.
    Type: Application
    Filed: April 9, 2009
    Publication date: August 13, 2009
    Inventors: Mervin G. Wood, Robert Detlefsen, James Galbo, Wanda Martin, Paul Kondracki, Michael P. DiFazio, Joseph E. Babiarz
  • Publication number: 20090202725
    Abstract: Sterically hindered hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of formulae (5)-(7) These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation. The compounds are effective for example in stabilizing water borne coatings, aqueous inks, aqueous ink jet media and photocured aqueous systems.
    Type: Application
    Filed: April 9, 2009
    Publication date: August 13, 2009
    Inventors: Mervin G. Wood, Robert Detlefsen, James Galbo, Wanda Martin, Paul Kondracki, Michael P. DiFazio, Joseph E. Babiarz
  • Patent number: 7550599
    Abstract: Sterically hindered alkoxyamine and hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water. The sterically hindered amines are for example of the formula where for example E and E? are 2-hydroxycyclohexyloxy, 2-hydroxy-2-methylpropoxy, benzyloxy, methoxy, propoxy, hexyloxy, heptyloxy, octyloxy or cyclohexyloxy, Rx is for example —NH2+CH2CH2OH Cl?, —NH3+?OAc, ?NOH, —NHCH(CH3)COO?K+, —NHCH2CH2N(CH3)2+?OAc, —NHCH2CH2SO3?K+, —NHCH(COO?K+)CH2CH2SCH3, —NHCH2COO?K+, —OCH(CH3)COO?K+, —OCH2CH2N(CH3)2+?OAc, —OCH2CH2SO3?K+, —OCH(COO?K+)CH2CH2SCH3 or —OCH2COO31K+, and where R5 comprises repeating units of —(OCH2CH2)—, —(OCH2CH2(CH3))—, —(CH2CHCOOH)—, —(CH2C(CH3)COOH)—, —(CH2CHCOOCH3)—, —(NHCH2CH2)—, —(CH2CHOH)—, —(CH2CHCONH2)— or —(CH2CH(NHCOH))—. These compounds are particularly effective in stabilizing aqueous polymer systems against the deleterious effects of oxidative, thermal and actinic radiation.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: June 23, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Mervin G. Wood, Robert Detlefsen, James Galbo, Wanda Martin, Paul Kondracki, Michael P. DiFazio, Joseph E. Babiarz
  • Patent number: 7291662
    Abstract: The present invention discloses mono-, bis- and tris-nonylcyclohexylphosphite esters, polyolefin compositions stabilized against the deleterious effects of melt processing, heat aging and exposure to combustion products of natural gas which comprise the nonylcyclohexylphosphite esters as stabilizers, and a process towards stabilizing polyolefin compositions by incorporating in or applying thereto the nonylcyclohexylphosphite esters.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: November 6, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Roswell E. King, Joseph E. Babiarz, Samuel Evans, Sai P. Shum
  • Publication number: 20040210056
    Abstract: Sterically hindered alkoxyamine and hydroxy substituted alkoxyamine stabilizer compounds are made water compatible via certain backbones with affinity towards water.
    Type: Application
    Filed: February 19, 2004
    Publication date: October 21, 2004
    Inventors: Mervin G. Wood, Robert Detlefsen, James Galbo, Wanda Martin, Paul Kondracki, Michael P. DiFazio, Joseph E. Babiarz
  • Patent number: 6211378
    Abstract: An environmentally friendly process for the preparation of the 4-functionalized N—OR derivatives of 2,2,6,6-tetraalkylpiperidines involves the hydrogen peroxide of the corresponding N—H compound to form the corresponding N-oxyl derivative, reacting two equivalents of the N-oxyl compound with one equivalent of a compound having an allylic hydrogen, a benzylic hydrogen or an activated methine hydrogen to form one equivalent of the corresponding N—OH compound and one equivalent of the corresponding N—OR compound, and recycling the N—OH compound back to the corresponding N-oxyl compound using hydrogen peroxide or air.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: April 3, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Joseph E. Babiarz, Stephen D. Pastor, Glen T. Cunkle
  • Patent number: 5607987
    Abstract: Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
    Type: Grant
    Filed: April 5, 1996
    Date of Patent: March 4, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Ramanathan Ravichandran, Mark S. Holt, Volker H. von Ahn, Joseph E. Babiarz, David G. Leppard
  • Patent number: 5574166
    Abstract: Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: November 12, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Ramanathan Ravichandran, Mark S. Holt, Volker H. von Ahn, Joseph E. Babiarz, David G. Leppard
  • Patent number: 5563242
    Abstract: Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 8, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Ramanathan Ravichandran, Mark S. Holt, Volker H. von Ahn, Joseph E. Babiarz, David G. Leppard
  • Patent number: 5554760
    Abstract: Soluble and thermally stable benzotriazole UV absorbers typified by those of formula I ##STR1## where R.sub.1 is hydrogen or chloro, R.sub.2 is alkyl or --CH.sub.2 CH.sub.2 COOR.sub.4 where R.sub.4 is hydrogen, alkyl or alkyl substituted with hydroxyl, and R.sub.3 is .alpha.-cumyl, provide excellent light stability protection to electro coat, base coat or clear coat finishes. The new soluble, crystalline form of 2-(2-hydroxy-3-.alpha.-cumyl-5-tert-octylphenyl)-2H-benzotriazole is particularly effective.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 10, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Roland A. E. Winter, Ramanathan Ravichandran, Mark S. Holt, Volker H. von Ahn, Joseph E. Babiarz, David G. Leppard
  • Patent number: 5492954
    Abstract: N,N,N',N'-Tetrasubstituted 1,4-diamino-2-butenes where the substituents are alkyl, cycloalkyl, aralkyl, aryl or mixtures thereof provide effective antioxidant protection to lubricants and/or synthetic polymers.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: February 20, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph E. Babiarz, Glen T. Cunkle, Werner Rutsch
  • Patent number: 5414028
    Abstract: Carbohydrate substituted dibenzo[d,f][1,3,2]dioxaphosphepin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: May 9, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Stephen D. Pastor, Joseph E. Babiarz
  • Patent number: 5391808
    Abstract: N,N,N',N'-Tetrasubstituted 1,4-diamino-2-butenes where the substituents are alkyl, cycloalkyl, aralkyl, aryl or mixtures thereof provide effective antioxidant protection to lubricants and/or synthetic polymers.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: February 21, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph E. Babiarz, Glen T. Cunkle, Werner Rutsch
  • Patent number: 5356962
    Abstract: Carbohydrate substituted dibenzo[d,g][1,3,2]dioxaphosphocin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.
    Type: Grant
    Filed: February 17, 1994
    Date of Patent: October 18, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Stephen D. Pastor, Joseph E. Babiarz
  • Patent number: 5310889
    Abstract: Carbohydrate substituted dibenzo[d,f][1,3,2]dioxaphosphepin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: May 10, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Stephen D. Pastor, Joseph E. Babiarz
  • Patent number: 5310891
    Abstract: Carbohydrate substituted phosphites of Formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: May 10, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Joseph E. Babiarz, Stephen D. Pastor
  • Patent number: 5310890
    Abstract: Carbohydrate substituted dibenzo[d,g][1,3,2]dioxaphosphocin compounds of formula I ##STR1## where A is a carbohydrate residue are effective stabilizers for polymers processed at elevated temperatures and subject to thermal or oxidative degradation.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: May 10, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Stephen D. Pastor, Joseph E. Babiarz
  • Patent number: 5290940
    Abstract: 2,6-Diarylpiperidin-1-yl substituted 2-butene stabilizers of the formula I or IIT--CH.sub.2 --CH.dbd.CH--CH.sub.2 --T (I)T--CH.sub.2 --CH.dbd.CH--CH.sub.2 --N(E.sub.1)(E.sub.2) (II)where T is a 2,6-diarylpiperidin-1-yl moiety and E.sub.1 and E.sub.2 are independently alkyl, cycloalkyl, aralkyl or aryl, are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and actinic radiation.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: March 1, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Glen T. Cunkle, Joseph E. Babiarz