Abstract: A composite filler comprising thermally processed porous inorganic mixed particles of silica and at least one heteroparticle selected from the group consisting of zirconia, hafnia, or yttria and a polymer occupying the pores of the porous inorganic mixed particles, wherein the porous inorganic mixed particles are thermally processed at a temperature of from 650 to 900° C., as well as a dental restorative comprising a resin and a composite filler, and optionally other fillers, wherein said resin has a refractive index that increases upon curing, and wherein the opacities of the both uncured and cured restorative are less than 45.

Abstract: A composite filler comprising thermally processed porous inorganic mixed particles of silica and at least one heteroparticle selected from the group consisting of zirconia, hafnia, or yttria and a polymer occupying the pores of the porous inorganic mixed particles, wherein the porous inorganic mixed particles are thermally processed at a temperature of from 650 to 900° C., as well as a dental restorative comprising a resin and a composite filler, and optionally other fillers, wherein said resin has a refractive index that increases upon curing, and wherein the opacities of the both uncured and cured restorative are less than 45.

Abstract: A dental composite or coating that comprises at least one photopolymerizable resin, at least one inorganic filler, a photoinitator, and at lease one interference platelet. The dental composite is able to adapt and match the color and shade of adjacent tooth structure in the cavity in which it is placed, without the need for conventional dyes and pigments, although it may be desirable to use dyes and pigments in a specific shade series.

Abstract: A composite filler comprising thermally processed porous inorganic mixed particles of silica and at least one heteroparticle selected from the group consisting of zirconia, hafnia, or yttria and a polymer occupying the pores of the porous inorganic mixed particles, wherein the porous inorganic mixed particles are thermally processed at a temperature of from 650 to 900° C., as well as a dental restorative comprising a resin and a composite filler, and optionally other fillers, wherein said resin has a refractive index that increases upon curing, and wherein the opacities of the both uncured and cured restorative are less than 45.

Abstract: The invention provides a dental curing device comprising a light source having a wavelength capable of inducing polymerization of a photopolymer, and a noncontact thermal detector in alignment with said light source and capable of measuring the temperature or temperature change of the photopolymer upon polymerization.

Abstract: A composite filler comprising thermally processed porous inorganic mixed particles of silica and at least one heteroparticle selected from the group consisting of zirconia, hafnia, or yttria and a polymer occupying the pores of the porous inorganic mixed particles, wherein the porous inorganic mixed particles are thermally processed at a temperature of from 650 to 900° C., as well as a dental restorative comprising a resin and a composite filler, and optionally other fillers, wherein said resin has a refractive index that increases upon curing, and wherein the opacities of the both uncured and cured restorative are less than 45.

Abstract: The invention provides a dental curing device comprising a light source having a wavelength capable of inducing polymerization of a photopolymer, and a noncontact thermal detector in alignment with said light source and capable of measuring the temperature or temperature change of the photopolymer upon polymerization.

Abstract: The present invention relates to a system comprising photopolymerizable composites and an associated light polymerization device. The composite comprises a photopolymerizable resin and a luminophore, and optionally inorganic fillers and a photobleaching agent. The polymerization device comprises a light source and a photodetector. The composite and the device are coupled via a feedback loop to indicate the degree of polymerization, or to indicate that polymerization is complete. The invention relates to any photopolymerizable composite or coating including industrial, protective, biomedical and dental composites and coatings.

Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.

Abstract: The present invention relates to bioactive hetero-coagulated mixed materials that have high strength and durability, that are prepared using an aqueous process, and that have a high transparency when placed into a monomer, polymer, or resin of approximately the same refractive index.

Abstract: The present invention relates to hetero-coagulated silica-alumina mixed oxide compositions that have a sharp refractive index and narrow refractive index dispersion between about 1.46 and 1.60.

Abstract: The present invention relates to bioactive hetero-coagulated mixed materials that have high strength and durability, that are prepared using an aqueous process, and that have a high transparency when placed into a monomer, polymer, or resin of approximately the same refractive index.

Abstract: This invention relates to a method of making a composition comprising a colloid comprising particles having a colloidal silica core and a shell, said method comprising the steps of: simultaneously introducing into a vessel a first liquid stream containing silica core particles, a second liquid stream containing a polymer having amine functionalities; and a third liquid stream having a pH adjusting substance such that said vessel is maintained at a pH below 6.0, and followed by readjusting the pH of the colloid to a pH between about 7-10; the addition of a cross-linking reagent, and adjusting the pH of the colloid to approximately physiological conditions, wherein the core-shell colloid contains between 10 and 30 ?mol amine-monomer/m2 core surface area.

Abstract: The present invention relates to hetero-coagulated silica-alumina mixed oxide compositions that have a sharp refractive index and narrow refractive index dispersion between about 1.46 and 1.60.

Abstract: Disclosed in this specification is an aqueous dispersion for treating a textile. The dispersion generally includes surface-functionalized inorganic oxides in combination with a fluorochemical. Significantly lower concentrations of fluorochemicals are present in comparison to prior art dispersions.

Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.

Abstract: The present invention discloses a method of making core-shell polymer particles, comprising forming a linking-group-containing polymer by derivatizing a hydroxy-group-containing polymer, comprising hydroxy groups on adjacent carbon atoms with a linking agent, that is a compound comprising both an aldehyde moiety and an amine moiety, wherein one or more acetal moieties are formed in the linking-group-containing polymer, each acetal formed by the reaction of the aldehyde moiety in the linking agent with two hydroxy groups in the linking-group-containing polymer, wherein the amine moiety then becomes a linking group pendent from the linking-group-containing polymer, wherein the linking group is capable of reacting with a precursor group in the precursor polymer. Also disclosed are compositions comprising insoluble core-shell particles made by the method.

Abstract: The present invention discloses an ink printing method using an image-recording element, which provides an image having excellent image quality and superior dry time, comprising insoluble cationic core-shell polymeric particles each comprising a core comprising cationic core polymer having at least 10 mole percent of a cationic mordant monomeric unit and a shell comprising hydrophilic shell polymer that is substantially less cationic than the cationic core polymer, wherein the shell is at least 10% by weight of the core.

Abstract: Disclosed are embodiments and methods relating to the treatment of textile, such as a textile substrate, with an aqueous dispersion of surface-functionalized particles and a fluorochemical, or a textile substrate treated with an aqueous dispersion of surface-functionalized particles, a fluorochemical, and a flame retardant chemical. Textiles treated in accordance with the disclosed embodiments (e.g., fluorine concentration of from 20 to 900 ppm) demonstrate an average burn rate less than about 4.0 inch/minute, and an average weight loss is less than about 40% of the original weight. During burning of the treated textile, flaming drips extinguish (on average) in less than about 2 seconds, or does not increase the peak heat release rate by more than about 70%, and the mass loss rate by more than about 50%.

Abstract: The invention relates to a composition comprising a colloid which is stable under physiological pH and ionic strength, said colloid comprising particles having a silica core and a shell: a) wherein said shell comprises a cross-linked poly(ethylene)imine polymer having amine functionalities; b) wherein the particles have a volume-weighted mean particle size diameter of less than 200 nm, and c) wherein greater than 50% of said polymer in the colloid is bound to the core surfaces, wherein the polymer having amine functionalities has an average molecular weight less than 100,000 g/mol, the composition has a H of between 6 and 8; and d) wherein the colloid contains between 300 and 6000 .?mol amine-monomer/g core particles.