Abstract: The thermoplastic polyurethane compositions described herein have very good recovery properties, rebound resilience, or both, while also having good softness (i.e. low hardness). It has been difficult to provide thermoplastic polyurethane compositions with this combination of properties. Some compositions described herein also provide low haze and/or good clarity properties. These combination of properties make the thermoplastic polyurethane compositions described herein useful materials for application that require fast recovery, good rebound resilience, or both while also requiring soft materials, and in some embodiments low haze and/or good clarity.

Abstract: The invention relates to compositions and methods for solid freeform fabrication of medical devices, components and applications in which the composition includes a thermoplastic polyurethane which is particularly suited for such processing. The useful thermoplastic polyurethanes are derived from (a) an aromatic diisocyanate component, (b) a polyol component, and (c) a chain extender component where the molar ratio of (c) to (b) is at least 4.25.

Abstract: The invention relates to compositions and methods for solid freeform fabrication of medical devices, components and medical applications, in which the composition includes a thermoplastic polyurethane which is particularly suited for such processing. The useful thermoplastic polyurethanes are derived from (a) an aromatic diisocyanate component, (b) a polyol component, and (c) a chain extender component where the molar ratio of (c) to (b) is from 2.4 to 4.7.

Abstract: The thermoplastic polyurethane compositions described herein have very good recovery properties, rebound resilience, or both, while also having good hardness. It has been difficult to provide thermoplastic polyurethane compositions with this combination of properties. Some compositions described herein also provide low haze and/or good clarity properties. These combination of properties make the thermoplastic polyurethane compositions described herein useful materials for application that require fast recovery, good rebound resilience, or both while also requiring hard materials, and in some embodiments low haze and/or good clarity.

Abstract: This technology relates to an integrated article that includes (a) a flexible foam region and (b) a non-foam region. The flexible foam region and the non-foam region are each made of a polyurethane composition. In some embodiments, the flexible foam region is a midsole, and wherein the non-foam region is an outsole. The flexible foam region is made from a flexible polyurethane injection molded foam. The non-foam region is made from a non-foamed polyurethane, which may be extruded or thermoformed. The invention relates to this integrated article, as well as the methods of making and using the same.

Abstract: The present invention relates to systems and methods for solid freeform fabrication, especially selective laser sintering, as well as various articles made using the same, where the systems and methods utilize certain thermoplastic polyurethanes which are particularly suited for such processing. The useful thermoplastic polyurethanes are derived from (a) a polyisocyanate component, (b) a polyol component, and (c) an optional chain extender component; wherein the resulting thermoplastic polyurethane has a melting enthalpy of at least 5.5 J/g, a Tc (crystallization temperature) of more than 70° C., a ?(Tm:Tc) of from 20 to 75 degrees, where ?(Tm:Tc) is the difference between the Tm (melting temperature) and Tc.

Abstract: The present invention relates to systems and methods for solid freeform fabrication, especially fused deposition modeling, as well as various articles made using the same, where the systems and methods utilize certain thermoplastic polyurethanes which are particularly suited for such processing. The useful thermoplastic polyurethanes are derived from (a) a polyisocyanate component, (b) a polyol component, and (c) an optional chain extender component where the resulting thermoplastic polyurethane has a crystallization temperature above 80° C. and retains more than 20% of its shear storage modulus at 100° C. relative to its shear storage modulus at 20° C.

Abstract: The disclosed technology relates to a system and approach to achieve temporary adhesion of a hot-melt bonding film to a substrate, including for example a textile, leather, synthetic leather, or nonwoven substrate, so that the hot-melt film stays in place before and during the hot-melt bonding of the substrate to one or more other parts, and can even be re-positioned if needed, and then still stay in place before and during the hot-melt bonding process. In particular, an adhesive system is disclosed comprising a hot-melt adhesive and (ii) a pressure sensitive adhesive, where the hot-melt adhesive is in the form of a continuous film and where the pressure sensitive adhesive is distributed on at least one surface of said continuous film in a discontinuous pattern. In preferred embodiments said hot-melt adhesive comprises a thermoplastic polyurethane and said pressure-sensitive adhesive comprises an acrylic polymer dispersion.

Abstract: A flexibly multilayer composite comprising at least one barrier layer of high hardness TPU having a Shore D hardness of at least 80, a soft segment content of less than 5%, and a low gasoline vapor transmission rate of less than 1 g/M2/day. The composite also has at least one layer of soft TPU static dissipative polymer having a surface resistivity of less than 1.0×1012 ohms/square a Shore durometer of form 60 A to 60 D, and a gum residue of less than 20 mg per 100 ml of gasoline after 1 week exposure. The composite may have an optional third layer of an abrasion resistant TPU. The abrasion resistant TPU layer may contain reinforcement material, such as fabric.

Abstract: A flexibly multilayer composite comprising at least one barrier layer of high hardness TPU having a Shore D hardness of at least 80, a soft segment content of less than 5%, and a low gasoline vapor transmission rate of less than 1 g/M2/day. The composite also has at least one layer of soft TPU static dissipative polymer having a surface resistivity of less than 1.0×1012 ohms/square a Shore durometer of form 60 A to 60 D, and a gum residue of less than 20 mg per 100 ml of gasoline after 1 week exposure. The composite may have an optional third layer of an abrasion resistant TPU. The abrasion resistant TPU layer may contain reinforcement material, such as fabric.

Abstract: The present invention provides an offset printing blanket or sleeve including one or more layers that are made with a soft thermoplastic polyurethane composition that provides excellent compression set and excellent resistance to apolar solvents, such as naphthenic mineral spirits. The subject invention more specifically reveals a printing blanket comprising: a base layer; a compressible layer, and a printing surface layer, wherein the compressible layer and/or the printing surface layer is comprised of a thermoplastic polyurethane composition, wherein the thermoplastic polyurethane composition made by reacting (a) at least one polyester polyol intermediate with (b) at least one diisocyanate and (c) at least one chain extender; wherein the polyester polyol intermediate comprises an intermediate derived from at least one dialkylene glycol and at least one dicarboxylic acid or an ester or anhydride thereof.

Abstract: A liner for repairing damaged pipes, such as underground sewer or gas pipes is disclosed. The liner comprises a TPU coating on fibrous mat of non-woven fabric. The TPU coating contains a barrier layer to retard the migration of styrene from the liner to the media used to force the liner against the damaged pipe and to activate the thermoset resin. The thermoset resin converts the liner from a flexible state to a rigid state as the liner is cured in place inside the pipe.