Abstract: This present disclosure relates to processes and apparatuses for toluene methylation in an aromatics complex for producing paraxylene. More specifically, the present disclosure relates to processes and apparatuses for toluene methylation within an aromatics complex for producing paraxylene wherein an embodiment uses a riser reactor, another embodiment uses a pre-reactor producing dimethyl ether, and another embodiment uses partial regeneration of the catalyst.

Abstract: Embodiments of methods and apparatuses for recovery of ethylene from FCC absorber off-gas comprising a heavy cut comprising ethylene, ethane and heavier hydrocarbons and a light cut comprising hydrogen, nitrogen and methane. An exemplary method includes passing the FCC absorber off-gas to an adsorption zone containing an adsorbent selective for the adsorption of the light cut, the adsorption zone adsorbing at least a portion of the light cut and recovering an adsorption zone effluent stream comprising the heavy cut. The adsorption zone effluent is passed to a demethanizer column to provide an overhead stream comprising hydrogen, nitrogen, methane, ethylene and ethane and a net bottoms stream comprising ethylene, ethane and the heavier hydrocarbons.

Abstract: Processes and apparatuses for producing a C8 aromatic isomer product are provided. The process comprises introducing a reformate stream comprising aromatic hydrocarbons to a reformate splitter column to provide a plurality of streams. One or more streams comprising at least one stream from the plurality of streams is passed to a reformate upgrading unit to obtain an upgraded reformate stream. The upgraded reformate stream is passed to an aromatics stripper column to provide an aromatics stripper sidedraw stream comprising C8 aromatic hydrocarbons. The aromatics stripper sidedraw stream is passed to a xylene separation unit to provide the C8 aromatic isomer product and a raffinate product stream. At least a portion of the raffinate product stream is processed in a liquid phase isomerization unit to obtain an isomerized stream.

Abstract: Processes for producing a propylene stream having at least 95% propylene and a reduced level of dienes. A selective hydrogenation zone converts dienes into olefins in a stream having at least C3 and C4 olefins from a feed stream including butene and C4 dienes. The selective hydrogenation zone may be disposed between a demethanizer and a deethanzier or it may be disposed downstream of both the demethanizer and the deethanizer. A C3 splitter and an acetylene conversion zone may be utilized.

Abstract: A process is presented for removing the fouling problems associated with the product recovery in a methanol to olefins conversion process. The process includes passing the quenched MTO process stream to a product separator, wherein an intermediate stream is generated and includes water and heavier hydrocarbons. The intermediate stream is processed to remove the buildup of heavier hydrocarbons.

Abstract: A process is presented for removing the fouling problems associated with the product recovery in a methanol to olefins conversion process. The process includes passing the quenched MTO process stream to a product separator, wherein an intermediate stream is generated and includes water and heavier hydrocarbons. The intermediate stream is processed to remove the buildup of heavier hydrocarbons.

Abstract: 1-butene is recovered as a purified product from an MTO synthesis and especially from an integrated MTO synthesis and hydrocarbon pyrolysis system in which the MTO system and its complementary olefin cracking reactor are combined with a hydrocarbon pyrolysis reactor in a way that facilitates the flexible production and recovery of olefins and other petrochemical products, particularly butene-1 and MTBE.

Abstract: A process and apparatus is presented for the removal of solid particles from a gas stream. The process and apparatus includes adding a second stream of liquid that is sprayed over the openings in trays in a quench tower. The second spray stream provides for a veil of liquid to wash out solid particles from the vapor stream.

Abstract: Multistable shape-shifting surfaces that retain their effectiveness as physical barriers while undergoing changes in shape and that can remain stable in the various shapes. The shape changes include any motion that makes the surface more effective at performing its function, such as expansion, shrinkage, twisting, encircling, wiggling, swallowing or constricting. The shape-shifting surfaces include tiled arrays of polygonal cells, each cell including specifically-designed compliant flexures attached to specifically-shaped overlapping thin plates or shells. The surfaces remain stable by leveraging them during deformation to an extent that they cannot spontaneously return to the unstressed shape. Applications for such surfaces include micro-scale cellular engineering and macro-scale biomedical applications, recreational uses, national security, and environmental protection.

Abstract: Multistable shape-shifting surfaces that retain their effectiveness as physical barriers while undergoing changes in shape and that can remain stable in the various shapes. The shape changes include any motion that makes the surface more effective at performing its function, such as expansion, shrinkage, twisting, encircling, wiggling, swallowing or constricting. The shape-shifting surfaces include tiled arrays of polygonal cells, each cell including specifically-designed compliant flexures attached to specifically-shaped overlapping thin plates or shells. The surfaces remain stable by leveraging them during deformation to an extent that they cannot spontaneously return to the unstressed shape. Applications for such surfaces include micro-scale cellular engineering and macro-scale biomedical applications, recreational uses, national security, and environmental protection.

Abstract: A process and apparatus is presented for the removal of solid particles from a gas stream. The process and apparatus includes adding a second stream of liquid that is sprayed over the openings in trays in a quench tower. The second spray stream provides for a veil of liquid to wash out solid particles from the vapor stream.

Abstract: 1-butene is recovered as a purified product from an MTO synthesis and especially from an integrated MTO synthesis and hydrocarbon pyrolysis system in which the MTO system and its complementary olefin cracking reactor are combined with a hydrocarbon pyrolysis reactor in a way that facilitates the flexible production and recovery of olefins and other petrochemical products, particularly butene-1 and MTBE.

Abstract: A process is presented for improving the quality of an oxygenate feedstream to an oxygenate to olefins conversion reactor. The process includes passing the feedstream to a fractionation column having a sufficient number of trays to remove the sodium in the form of sodium hydroxide. The fractionation column is also sized to have a sufficient number of trays to minimize the amount of oxygenates being passed out with the removed sodium hydroxide.