Abstract: Particulate filters are used to remove particulate matter such as soot and ash in the emissions control systems of vehicles, including gasoline direct injection (GDI) engines. Methods are provided to predict the long-term performance and durability of emissions control systems having particulate filters. The methods account for factors such as thermal aging, soot accumulation and regeneration, and ash loading.

Abstract: Particulate filters are used to remove particulate matter such as soot and ash in the emissions control systems of vehicles, including gasoline direct injection (GDI) engines. Methods are provided to predict the long-term performance and durability of emissions control systems having particulate filters. The methods account for factors such as thermal aging, soot accumulation and regeneration, and ash loading.

Abstract: A method for preparing an internal combustion (IC) engine component of a hybrid automotive powertrain for shutdown so as to enable clean restart is disclosed herein. The method includes determining if the IC engine is about to enter a shutdown mode. The method includes determining a number of engine run cycles to fill an intake manifold of the IC engine with clean air, if it is determined the IC engine is about to enter the shutdown mode. The method includes running the IC engine for the determined number of cycles to fill the intake manifold of the IC engine with clean air before shutting the IC engine down.

Abstract: A nanocatalyst, dual catalyst and methods for improving the efficiency and output of a biomass gasification process are provided where the catalysts comprise a volatile organometallic compound(s) and/or a nanoalloy catalyst. By the catalyst and method, a very high biomass gasification conversion efficiency of over 85% can be achieved. The subject nanocatalyst cracks and gasifies lignin, which is generally inert in conventional gasification, at relatively low gasification temperatures. The subject disclosure also provides a means to increase gas yields and lower lignin content in the resulting product relative to conventional gasification. Alternatively, oil production may be increased, if desired. Moreover, the resulting gas may achieve a Fischer-Tropsch reactor favorable H2:CO ratio of about 9:1. The energy input to the gasification is correspondingly reduced to reduce costs and the environmental impact associated with the gasification process.

Abstract: A method for preparing an internal combustion (IC) engine component of a hybrid automotive powertrain for shutdown so as to enable clean restart is disclosed herein. The method includes determining if the IC engine is about to enter a shutdown mode. The method includes determining a number of engine run cycles to fill an intake manifold of the IC engine with clean air, if it is determined the IC engine is about to enter the shutdown mode. The method includes running the IC engine for the determined number of cycles to fill the intake manifold of the IC engine with clean air before shutting the IC engine down.

Abstract: The present invention relates to a method for improving biomass gasification. By the present invention, volatile organometallics are contacted with a biomass before or during gasification. By this method, the biomass improves gas yields while reducing solid (tar) and liquid yields. In addition, the volatile organometallics interact with lignin in the biomass to produce methanol, which, in turn, results in a stable liquid or oil by-product or otherwise stabilizes the gasification process of the biomass. The presently disclosed method can also lead to increased syngas production and is potentially CO2 neutral. The energy input to the gasification is correspondingly reduced to reduce costs and the environmental impact associated with the gasification process.

Abstract: A nanocatalyst, dual catalyst and methods for improving the efficiency and output of a biomass gasification process are provided where the catalysts comprise a volatile organometallic compound(s) and/or a nanoalloy catalyst. By the catalyst and method, a very high biomass gasification conversion efficiency of over 85% can be achieved. The subject nanocatalyst cracks and gasifies lignin, which is generally inert in conventional gasification, at relatively low gasification temperatures. The subject disclosure also provides a means to increase gas yields and lower lignin content in the resulting product relative to conventional gasification. Alternatively, oil production may be increased, if desired. Moreover, the resulting gas may achieve a Fischer-Tropsch reactor favorable H2:CO ratio of about 9:1. The energy input to the gasification is correspondingly reduced to reduce costs and the environmental impact associated with the gasification process.

Abstract: The present invention relates to a method for improving biomass gasification. By the present invention, volatile organometallics are contacted with a biomass before or during gasification. By this method, the biomass improves gas yields while reducing solid (tar) and liquid yields. In addition, the volatile organometallics interact with lignin in the biomass to produce methanol, which, in turn, results in a stable liquid or oil by-product or otherwise stabilizes the gasification process of the biomass. The presently disclosed method can also lead to increased syngas production and is potentially CO2 neutral. The energy input to the gasification is correspondingly reduced to reduce costs and the environmental impact associated with the gasification process.

Abstract: A method of enhancing the operation of diesel fuel combustion systems in a combustion system includes supplying a fuel and additive that includes a manganese compound to a diesel fuel combustion system. The fuel is then combusted in the combustion chamber to produce at least one byproduct including the manganese compound. The manganese compound is supplied in an amount effective to complex with the combustion byproduct. The diesel fuel combustion system operation is enhanced by improving the attributes of lubricating oil loaded with the combustion byproduct soot particles.

Abstract: A hydrocarbonaceous fuel additive, fuel composition, and method all lower both carbon particulate emissions and improve slag properties in combustion systems including, for instance, utility furnaces and boiler systems. The mixed metal catalyst may include a transition metal-containing compound, an alkali metal compound, and a magnesium-containing compound.

Abstract: An emissions control system for the after treatment of a fuel combustion process exhaust stream includes an exhaust passageway. The exhaust passageway allows for passage of an exhaust stream containing exhaust byproducts from the combustion of a fuel that includes a manganese compound. The exhaust stream includes a manganese compound which complexes with at least one of the exhaust byproducts.

Abstract: A hydrocarbonaceous fuel additive, fuel composition, and method all lower both carbon particulate emissions and improve slag properties in combustion systems including, for instance, utility furnaces and boiler systems. The mixed metal catalyst may include a transition metal-containing compound, an alkali metal compound, and a magnesium-containing compound.

Abstract: A method of enhancing the operation of diesel fuel combustion systems in a combustion system includes supplying a fuel and additive that includes a manganese compound to a diesel fuel combustion system. The fuel is then combusted in the combustion chamber to produce at least one byproduct including the manganese compound. The manganese compound is supplied in an amount effective to complex with the combustion byproduct. The diesel fuel combustion system operation is enhanced by improving the attributes of lubricating oil loaded with the combustion byproduct soot particles.

Abstract: An additive and a method for reducing carbon and fly ash results from the combustion of a mixture of coal and a manganese-containing compound. The manganese compound may be mixed with coal either before or in a combustion chamber. The manganese compound may be an inorganic or organometallic compound. The organometallic compound may include methylcyclopentadienyl manganese tricarbonyl.

Abstract: The invention provides a method and a system for detecting metal concentrations, such as manganese, in liquid hydrocarbon matrices.