Abstract: This invention relates to an electric arc heater process and apparatus for the essentially complete decomposition of hazardous materials including polychlorinated biphenyls. Finely divided liquid or gaseous hazardous material is injected into a primary gas stream which has been superheated in an electric arc heater. The mixture is directed into a primary reactor for complete decomposition with dwell times in the reactor being in the order of 0.05 to 0.15 seconds. The decomposition products are neutralized with the gases being released to atmosphere and any remaining particulates being collected for ultimate disposal. Large solid hazardous material is first shredded then heated in a roaster or rotary kiln to vaporize the primary gas stream. A soaking reactor is provided where increased dwell times are required for the decomposition of thermally stable compounds which may be formed in the primary reactor. When these compounds are absent the soaking reactor can be by-passed.

Abstract: An electric arc heater having outlet gas admission. The mounting flange of an electric arc heater has a channel extending about its circumference which is enclosed by a detachably fastened plate to form a manifold. A passageway for the material to be admitted is provided between an outer surface of the mounting flange and the manifold. A plurality of peripherally spaced passageways are provided in the plate intermediate the manifold and the flow path of the arc heated gas exiting the arc heater outlet providing for the uniform distribution of the added material into the arc heated gas. By varying the position of these passageways a broad range of admission paths ranging from substantially parallel to the flow path of the arc heated gas to substantially perpendicular can be achieved without the use of additional downstream admission collars and seals.