Patents by Inventor Jozef Jacobus Titus Smits

Jozef Jacobus Titus Smits has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20160279566
    Abstract: The present invention relates to a process for removing mercaptans from a gas stream. First, a gas stream comprising at least a mercaptan of the general formula R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms, may be contacted with an absorption medium comprising a solvent, a substituted disulfide of the general formula R2—SS—R3 wherein R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapour pressure below the vapour pressure of any R1—SH thiol and at least one of R2 and R3 is an electron withdrawing group; and at least a catalytic amount of a base. The absorption medium may be retrieved and regenerated in a regeneration unit. The regenerated absorption solution may be recycled and subjected to oxidation.
    Type: Application
    Filed: November 10, 2014
    Publication date: September 29, 2016
    Inventors: Jozef Jacobus Titus SMITS, Sipke Hidde WADMAN
  • Patent number: 8894954
    Abstract: The present invention provides a process for removing mercaptans from a gas stream gas stream, comprising the steps: a) providing a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms; and b) contacting the mercaptan-comprising gas stream with an absorption medium comprising a substituted disulphide and a nitrogen-containing base to obtain a second mercaptan-depleted gas stream, wherein: the substituted disulphide is of the general formula R2—SS—R3 wherein: R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapor pressure below the vapor pressure of any R1—SH thiol.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: November 25, 2014
    Assignee: Shell Oil Company
    Inventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
  • Patent number: 8894955
    Abstract: The present invention provides a process for removing mercaptans from a gas stream. In the process, a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms, and an acid component is contacted with an absorption medium to obtain a mercaptan-depleted gas stream. The absorption medium includes a substituted disulphide and a base. The substituted disulphide is of the general formula R2—SS—R3, wherein R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapor pressure below the vapor pressure of any R1—SH thiol, and at least one of R2 and R3 is an electron withdrawing group.
    Type: Grant
    Filed: December 6, 2011
    Date of Patent: November 25, 2014
    Assignee: Shell Oil Cpmpany
    Inventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
  • Publication number: 20140330057
    Abstract: A process for converting a biomass material comprising a) pyrolyzing a biomass material to produce a biomass-derived pyrolysis product; b) mixing at least part of the biomass-derived pyrolysis product and a petroleum-derived hydrocarbon composition, which petroleum derived hydrocarbon composition has a C7-asphaltenes content of equal to or more than 0.2 wt %, based on the total weight of the petroleum-derived hydrocarbon composition, to produce a hydrocarbon-containing mixture; c) dewatering the hydrocarbon-containing mixture to produce a dewatered hydrocarbon-containing mixture; d) contacting the dewatered hydrocarbon-containing mixture with hydrogen in one or more ebullating bed reactors comprising a catalyst at a temperature in the range from 350 to 500° C. to produce a reaction product.
    Type: Application
    Filed: April 30, 2014
    Publication date: November 6, 2014
    Applicant: SHELL OIL COMPANY
    Inventors: Ivo Johannes DIJS, Arjen NIEUWHOF, Johannes Pieter HAAN, Josiane Marie-Rose GINESTRA, Jozef Jacobus Titus SMITS, Colin John SCHAVERIEN, Leticia ESPINOSA ALONSO, Wouter SPIERING
  • Publication number: 20140294708
    Abstract: The present invention provides a process for removing mercaptans from a gas stream gas stream, comprising the steps: a) providing a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms; and b) contacting the mercaptan-comprising gas stream with an absorption medium comprising a substituted disulphide and a nitrogen-containing base to obtain a second mercaptan-depleted gas stream, wherein: the substituted disulphide is of the general formula R2—SS—R3 wherein: R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapour pressure below the vapour pressure of any R1—SH thiol.
    Type: Application
    Filed: November 30, 2011
    Publication date: October 2, 2014
    Inventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
  • Publication number: 20140083910
    Abstract: The present invention provides a method for removing fine solids from an aqueous bitumen-containing stream, in particular from an aqueous bitumen-containing stream as obtained during an oil sands extraction process, the method at least comprising the steps of: (a) providing an aqueous bitumen-containing stream; (b) subjecting the aqueous bitumen-containing stream to membrane separation using a ceramic membrane, thereby obtaining a bitumen-depleted permeate stream and a bitumen-enriched retentate stream.
    Type: Application
    Filed: July 31, 2013
    Publication date: March 27, 2014
    Applicant: SHELL OIL COMPANY
    Inventors: Jose Luis BRAVO, Arian NIJMEIJER, Jozef Jacobus Titus SMITS
  • Publication number: 20130302233
    Abstract: The present invention provides a process for removing mercaptans from a gas stream. In the process, a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms, and an acid component is contacted with an absorption medium to obtain a mercaptan-depleted gas stream. The absorption medium includes a substituted disulphide and a base. The substituted disulphide is of the general formula R2—SS—R3, wherein R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapour pressure below the vapour pressure of any R1—SH thiol, and at least one of R2 and R3 is an electron withdrawing group.
    Type: Application
    Filed: December 6, 2011
    Publication date: November 14, 2013
    Inventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
  • Patent number: 6570028
    Abstract: Process for the manufacture of diglycidylesters of &agr;,&agr;′-branched dicarboxylic acids, comprising (a) the reaction of the &agr;,&agr;′-branched dicarboxylic acid with a halo substituted monoepoxide such as an epihalohydrin, in a 1.1-20 acid equivalent ratio relative to the &agr;,&agr;′-branched aliphatic dicarboxylic acid, optionally in the presence of water and water-miscible solvent, and in the presence of a catalyst in an amount of at most 45 mol % of the acid equivalent amount of the &agr;,&agr;′-branched aliphatic dicarboxylic acid, at a temperature in the range of from 30 to 110° C., during a period in the range of from 0.5 to 2.5 hr, (b) addition of alkali metal hydroxide or alkali metal alkanolate up to an acid equivalent ratio as to the &agr;,&agr;′-branched aliphatic dicarboxylic acid in the range of from 0.9:1 to 1.2:1, and reaction at a temperature of from 0 to 80° C.
    Type: Grant
    Filed: October 31, 2000
    Date of Patent: May 27, 2003
    Assignee: Resolution Performance Products LLC
    Inventors: Denis Marie Charles Heymans, Leo Wim Van Noort, Jozef Jacobus Titus Smits, Hendrik Stichter
  • Patent number: 6265531
    Abstract: A glycidylester of the general formula I in which R1 and R4 are the same or different C1-C6 alkyl or C6-C10 cycloalkyl groups, and R2 and R3 are the same or different and are H or C1-C6 alkyl or C6-C10 cycloalkyl groups. The glycidylester is used in a thermosetting resin composition, comprising also a curing compound and preferably an advanced resin product. The thermosetting resin composition can be applied for outdoor durable coatings, having excellent resistance against acid rain.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: July 24, 2001
    Assignee: Shell Oil Company
    Inventors: Johannes Adrianus Van Doorn, Jozef Jacobus Titus Smits
  • Patent number: 6235870
    Abstract: Process for the preparation of compounds of the formula wherein Hal represents chlorine, bromine or iodine and preferably chlorine, wherein Ra represents hydrogen or a residue comprising one or more additional groups of the formula, from compounds wherein R2 represents hydrogen or a residue comprising one or more additional groups of the formula by reaction with gaseous hydrogen halide in the presence of a catalytic amount of an organic acid; process for the preparation of epoxy compounds starting from the reaction to produce a compound of formula (III) which is converted to a compound of formula (A) that is dehydrohalogenated to form the epoxy rings of a diepoxy compound.
    Type: Grant
    Filed: September 29, 1999
    Date of Patent: May 22, 2001
    Assignee: Shell Oil Company
    Inventors: Jozef Jacobus Titus Smits, Judith Johanna Berendina Walhof
  • Patent number: 6172182
    Abstract: Process for the manufacture of epoxy compounds having the formula wherein Rb represents a group selected from those of the formulae Rg&Parenopenst;Q&Parenclosest;b-alkyl(Q&Parenclosest;a—˜, by reaction of a compound with an alkylene oxide, in the presence of a certain catalyst.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: January 9, 2001
    Assignee: Shell Oil Company
    Inventors: Jan Hermen Hendrik Meurs, Jozef Jacobus Titus Smits, Judith Johanna Berendina Walhof
  • Patent number: 6005063
    Abstract: Process for the preparation of compound of the formula: ##STR1## wherein R.sub.c represents a residue comprising one or more additional groups of the formula: ##STR2## by heating a compound of the formula (A) ##STR3## at a temperature in the range of from 120 to 220.degree. C. in the presence of hydrogen halide addition salt of tertiary amine;process for the preparation of epoxy compounds starting from the reaction of a polyphenol compound and glycidol; andepoxy resins obtained by this process showing a significantly lower content of intermingled clorine and being substantially free of usual build-up products.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: December 21, 1999
    Assignee: Shell Oil Company
    Inventors: Johannes Adrianus Van Doorn, Jozef Jacobus Titus Smits, Eric Johannes Vos
  • Patent number: 6001954
    Abstract: Process for the preparation of compounds of the formula ##STR1## wherein Hal represents chlorine, bromine or iodine and preferably chlorine, wherein R.sub.a represents hydrogen or a residue comprising one or more additional groups of the formula, ##STR2## from compounds ##STR3## wherein R.sub.2 represents hydrogen or a residue comprising one or more additional groups of the formula ##STR4## by reaction with gaseous hydrogen halide in the presence of a catalytic amount of an organic acid. Epoxy resins are prepared via the reaction of a compound of formula (A) in the presence of a basic compound.
    Type: Grant
    Filed: February 6, 1998
    Date of Patent: December 14, 1999
    Assignee: Shell Oil Company
    Inventors: Jozef Jacobus Titus Smits, Judith Johanna Berendina Walhof