Abstract: Disclosed herein are compounds having the formula: R1—(CO—NH—R2—R3)n and polymers made by moisture curing the compound. R1 is an organic group, a dimeric fatty acid chain, a dimeric linoleic fatty acid chain, a trimeric fatty acid chain, a saturated form of any thereof, a residue of a phenalkamine compound, or a residue of a polyamine. Each R2 is an aliphatic group or an aminoaliphatic group. Each R3 comprises an alkoxysilane group. The value n is a positive integer. The compound may be made by reacting a polyester with an amine having an alkoxysilane group or reacting a polyacid with an isocyanate having an alkoxysilane group. Also disclose are compounds made by reacting an amido amine with an epoxy compound.

Abstract: Disclosed herein are compounds having the formula: R1—(CO—NH—R2—R3)n and polymers made by moisture curing the compound. R1 is an organic group, a dimeric fatty acid chain, a dimeric linoleic fatty acid chain, a trimeric fatty acid chain, a saturated form of any thereof, a residue of a phenalkamine compound, or a residue of a polyamine. Each R2 is an aliphatic group or an aminoaliphatic group. Each R3 comprises an alkoxysilane group. The value n is a positive integer. The compound may be made by reacting a polyester with an amine having an alkoxysilane group or reacting a polyacid with an isocyanate having an alkoxysilane group. Also disclose are compounds made by reacting an amido amine with an epoxy compound.

Abstract: Disclosed herein are compounds having the formula: R1—(CO—NH—R2—R3)n and polymers made by moisture curing the compound. R1 is an organic group, a dimeric fatty acid chain, a dimeric linoleic fatty acid chain, a trimeric fatty acid chain, a saturated form of any thereof, a residue of a phenalkamine compound, or a residue of a polyamine. Each R2 is an aliphatic group or an aminoaliphatic group. Each R3 comprises an alkoxysilane group. The value n is a positive integer. The compound may be made by reacting a polyester with an amine having an alkoxysilane group or reacting a polyacid with an isocyanate having an alkoxysilane group. Also disclose are compounds made by reacting an amido amine with an epoxy compound.

Abstract: Disclosed herein are compounds having the formula: R1—(CO—NH—R2—R3)n and polymers made by moisture curing the compound. R1 is an organic group, a dimeric fatty acid chain, a dimeric linoleic fatty acid chain, a trimeric fatty acid chain, a saturated form of any thereof, a residue of a phenalkamine compound, or a residue of a polyamine. Each R2 is an aliphatic group or an aminoaliphatic group. Each R3 comprises an alkoxysilane group. The value n is a positive integer. The compound may be made by reacting a polyester with an amine having an alkoxysilane group or reacting a polyacid with an isocyanate having an alkoxysilane group. Also disclose are compounds made by reacting an amido amine with an epoxy compound.

Abstract: A method and coating made thereby of: reacting a 3-trialkoxysilylpropyl amine with an organic compound having a carbon-carbon double bond activated by an electron withdrawing group; followed by reacting with an aliphatic polyisocyanate; followed by optionally performing a silicate condensation with a hydrolyzed silicate; followed by application to a surface and moisture curing to form oxygen crosslinks between silicon atoms and loss of alkyl alcohols to form the coating. The compounds before moisture curing are shown below. R1 is an alkyl group; R3 and R4 are organic groups; R5 is the residue of the polyisocyanate; R6 contains the electron withdrawing group; R7 is an alkyl group; R1? is R1 or —(SiR72—O)m—R7; at least one of the R1? groups is —(SiR72—O)m—R7; m is a positive integer; and n is an integer greater than or equal to 2.

Abstract: A polyol having the formula Si(O—R1—OH)m(O—R2)nR3. Each R1 is a divalent radical derived from diethylene glycol, triethylene glycol, dipropylene glycol, or tripropylene glycol, each R2 is an aliphatic group, and R3 is an alkyl group or aromatic group. The value m is 2 or 3 and n is 0 or 1. A process of making the above polyol by: providing a reactant having the formula Si(O—R2)3R3, and reacting the reactant with a diol having the formula HO—R1—OH. An antifouling coating comprising a thermoset formed by reacting a polyisocyanate with the above polyol. The coating is not a foam.

Abstract: A composition having a polyurea made by reacting a polyisocyanate with one of the below compounds. The value x is 2 or 3. A method of: providing a polyisocyanate and one of the below compounds, spraying the polyisocyanate and the compound with a plural component pump onto a surface to form a mixture, and allowing the mixture to cure to a polyurea.

Abstract: A polyol having the formula Si(O—R1—OH)m(O—R2)nR3. Each R1 is a divalent radical derived from diethylene glycol, triethylene glycol, dipropylene glycol, or tripropylene glycol, each R2 is an aliphatic group, and R3 is an alkyl group or aromatic group. The value m is 2 or 3 and n is 0 or 1. A process of making the above polyol by: providing a reactant having the formula Si(O—R2)3R3, and reacting the reactant with a diol having the formula HO—R1—OH. An antifouling coating comprising a thermoset formed by reacting a polyisocyanate with the above polyol. The coating is not a foam.

Abstract: A compound having the formula below, where R is —H or —CH2—CH3; n, x, y, and z are nonnegative integers; R2 is an aliphatic group or oxyaliphatic group; and R3 is an aliphatic group.

Abstract: A polyol having the formula X(O—R1—OH)m(O—R2)nHq. X is Si, C, B, Ti, P, Al, Mg, or Ca. Each R1 is derived from dipropylene glycol or tripropylene glycol, and each R2 is an aliphatic group. m is 2, 3, or 4; n is 0, 1, or 2; and q is 1 or 2 when X is C, and is 0 when X is not C. A thermoset formed by reacting a polyisocyanate with the polyol. An antifouling coating containing the thermoset and optionally a biocide. An antifouling coating that is not foam formed by reacting Si(O—R1—OH)m(O—R2)nR3 with a polyisocyanate. Each R3 is an alkyl group or aromatic group.

Abstract: A compound having the formula below, where R is —H or —CH2—CH3; n, x, y, and z are nonnegative integers; R2 is an aliphatic group or oxyaliphatic group; and R3 is an aliphatic group.

Abstract: A polymer made by reacting a polyisocyanate with a compound having the formula below. R1 is an organic group. R2 is an aliphatic group. R3 is an aliphatic group. The polyisocyanate reactants are at least 50 mol % aromatic polyisocyanates. The reaction forms urea groups from the isocyanate groups of the polyisocyanate and the NH groups of the compound.

Abstract: A composition having a polyurea made by reacting a polyisocyanate with one of the below compounds. The value x is 2 or 3. A method of: providing a polyisocyanate and one of the below compounds, spraying the polyisocyanate and the compound with a plural component pump onto a surface to form a mixture, and allowing the mixture to cure to a polyurea.

Abstract: The compound below. R1 is an alkyl group or —(SiR72—O)m—R8. R7 is an alkoxy group. The value m is a nonnegative integer. R8 is an alkyl group or R3 and R4 are organic groups. R5 is an aliphatic group or a residue of a homopolymer of an aliphatic polyisocyanate. R6 has an electron withdrawing group that is bound to a carbon atom that is bound to the CHR4 group. The value n is an integer greater than or equal to 2. A method of: reacting a 3-trialkoxysilylpropyl amine with an organic compound having a carbon-carbon double bond activated by an electron withdrawing group to form a secondary amino propylalkoxysilane, and reacting the secondary amino propylalkoxysilane with an aliphatic polyisocyanate or a polymer thereof.

Abstract: A method of making a solid, crosslinked polymer by performing a reaction in a mixture of: 1) an imine selected from polyaldimines, hydroxyaldimines, polyketimines, and hydroxyketimines; 2) a polyisocyanate; and 3) a hydroxyl compound, if the imine is not a hydroxyimine. The imine and the hydroxyl compound are the only isocyanate-reactive compounds in the mixture. The hydroxyl compound is an alcohol, a glycol, or a polyol. The polymer comprises urea linkages formed from the imine and polyisocyanate and urethane linkages formed from the hydroxyl group of the hydroxyimine or the hydroxyl compound and the polyisocyanate, and the molar ratio of urea linkages to urethane linkages is at least 2:1. The reaction is performed in the absence of solvent.

Abstract: The below compound, which may be made by reacting a 3-trialkoxysilylpropyl amine with an acrylic acid ester, a methacrylic acid ester, a diester of maleic acid, a diester of fumaric acid, or acrylonitrile to form a secondary amino propylalkoxysilane, and reacting the secondary amino propylalkoxysilane with an isocyanate. R1 is an alkyl group, X is —CHR3—CHR4—CO—O—R2 or —CH2—CH2—CN, R2 is an organic group, R3 is —H or —CO—O—R2, R4 is —H or —CH3, but R4 is —H if R3 is —CO—O—R2, R5 is an aliphatic group or a residue of hexamethylene diisocyanate cyclic trimer or hexamethylene diisocyanate cyclic dimer, and n is 2 or 3. The below compound, which may be made by reacting a 3-trialkoxysilylpropyl amine with acrylonitrile. R1 is an alkyl group.

Abstract: A polymer made by reacting a polyisocyanate with a compound having the formula below. R1 is an organic group. R2 is an aliphatic group. R3 is an aliphatic group. The polyisocyanate reactants are at least 50 mol % aromatic polyisocyanates. The reaction forms urea groups from the isocyanate groups of the polyisocyanate and the NH groups of the compound.

Abstract: A method of making a polymer by providing an imine and reacting the imine with a polyisocyanate in the presence of a hydroxyl group. The imine is a polyaldimine, hydroxyaldimine, polyketimine, or hydroxyketimines. The polymer has urea linkages formed from the imine and polyisocyanate and urethane linkages formed from the hydroxyl group and the polyisocyanate. The polymer has at least as many urea linkages as urethane linkages. A polymer having urea units and urethane units having a molar ratio of at least about 2:1. A polymer comprising a urea-urethane repeat unit.

Abstract: A polymer made by reacting a polyisocyanate with a compound having the formula below. R1 is an organic group. R2 is an aliphatic group or oxyaliphatic group. R3 is an aliphatic group. The reaction forms urea groups from the isocyanate groups of the polyisocyanate and the NH groups of the compound.

Abstract: A polyurethane coating made by: applying to a surface a polyol composition and an isocyanate composition, such that a mixture of the polyol composition and the isocyanate composition is formed during the application; and allowing the mixture to cure to the polyurethane coating. The polyol composition has a polyol monomer having the chemical formula: R1 is a divalent radical selected from aliphatic, aromatic, and ether-containing group. R2 is a monovalent radical selected from aliphatic, aromatic, ester-containing group, ether-containing group, and acrylic-containing group. R2 is free of —O—CH2—CH(OH)— groups, and the polyol monomer is free of epoxy groups and amino hydrogens. The isocyanate composition comprises an isocyanate compound having at least two isocyanate groups. The polyol composition or the isocyanate composition comprises a water scavenger. The polyol composition or the isocyanate composition comprises a polyurethane catalyst.