Abstract: A process for extraction of copper from an arsenical copper sulfide concentrate is provided. The process includes atmospheric oxidative leaching of a feed slurry including the arsenical copper sulfide concentrate and an acidic iron sulfate-containing leach solution, in the presence of oxygen, to produce a leach slurry including copper and arsenic dissolved into the leach solution. After dissolving the copper and arsenic, and before precipitating the arsenic dissolved during the oxidative leaching, pre-precipitation solids are recovered from the leach slurry to produce the pre-precipitation solids and a resulting pregnant leach solution including the copper and arsenic. Scorodite-containing seed is introduced to the pregnant leach solution including the copper and arsenic to induce precipitation of the arsenic dissolved during the oxidative leaching, as scorodite.

Abstract: A process for extraction of copper from an arsenical copper sulfide concentrate is provided. The process includes atmospheric oxidative leaching of a feed slurry including the arsenical copper sulfide concentrate and an acidic iron sulfate-containing leach solution, in the presence of oxygen, to produce a leach slurry including copper and arsenic dissolved into the leach solution. After dissolving the copper and arsenic, scorodite-containing seed is introduced to the leach slurry to induce precipitation of the arsenic dissolved during the oxidative leaching, as scorodite.