Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is ?1 or ?2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is ?1 or ?2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

Abstract: A polymeric composition having a MFR of less than 2 g/10 min. which when formed into a film has an oxygen transmission rate of equal to or greater than 300 cc/100 in2/24 h at 73° F. and 0% relative humidity per ASTM D 3895 and a water vapor transmission rate of equal to or greater than 0.5 g/100 in2/24 hrs at 100° F. and 100% relative humidity per ASTM F 1249. A polymeric film having a 2% secant modulus in the machine direction of 300 MPa to 700 MPa; an oxygen transmission rate of greater than 300 cc/100 in2/24 h at 100° F., a water vapor transmission rate of greater than 0.5 g/100 in2/24 hrs at 100° F. and 100% relative humidity; an Elmendorf tear strength in the MD of from 50 g to 400 g; an Elmendorf tear strength in the transverse direction of from 150 g to 400 g, a dart drop strength of from 200 g to about 500 g, a haze of from 0% to 85% and, gloss at 45° of from 5% to 70%.