Abstract: Measurement unit for an ion-sensitive solid-state electrode, that serves to measure pH in a measurement solution, with a layered structure including an ion-sensitive glass layer with a first ring-shaped contact surface, an electrically conducting layer that directly or via at least one intermediate layer adheres to the ion-sensitive glass layer, and a substrate that adheres to the electrically conducting layer and is provided with a second ring-shaped contact surface; and with a holding member that is provided with a first ring-shaped sealing surface, a second ring-shaped sealing surface, and an annular section; wherein the first ring-shaped sealing surface is sealingly connected to the first ring-shaped contact surface, wherein the second ring-shaped sealing surface is connected to the second ring-shaped contact surface of the substrate, and wherein the first and second ring-shaped sealing surfaces of the holding member are sealingly connected by the annular section.

Abstract: A measuring element is disclosed for an ion-sensitive solid-contact electrode for measuring ion activity in a measurement medium. An ion-sensitive solid-contact electrode having such a measuring element and an electrochemical sensor having such a solid-contact electrode are also disclosed. The measuring element can include an ion-sensitive layer arranged to contact a measurement medium when in operation, and conductive to lithium ions; and a single-phase electrically conductive layer, which includes metallic lithium or a lithium-(0)-alloy. A solid-state electrolyte layer can be arranged between the ion-sensitive layer and the electrically conductive layer.

Abstract: A measuring element is disclosed for an ion-sensitive solid-contact electrode for measuring ion activity in a measurement medium. An ion-sensitive solid-contact electrode having such a measuring element and an electrochemical sensor having such a solid-contact electrode are also disclosed. The measuring element can include an ion-sensitive layer arranged to contact a measurement medium when in operation, and conductive to lithium ions; and a single-phase electrically conductive layer, which includes metallic lithium or a lithium-(0)-alloy. A solid-state electrolyte layer can be arranged between the ion-sensitive layer and the electrically conductive layer.

Abstract: An electrochemical sensor (1, 101) has a sensor element (15, 115) with a measuring surface (8, 108) that faces a measuring medium (5) during use. The sensor element has a planar measuring element (2, 102). A sensor shaft (4, 104) has an aperture (13, 113) with a bezel (11, 111) at an end which, during use, faces the measuring medium. The sensor element is installed in the area of the aperture. The electrochemical sensor also has an annular sealing element (9, 109), which is arranged between the sensor element and the bezel. An insulator element (10, 110) is firmly and inseparably connected to the measuring element, exposing or recessing the measuring surface. Thus, the sealing element, which protects the electrochemical sensor against the ingress of measuring medium, is arranged sealingly between the insulator element and the bezel.

Abstract: A measuring element is disclosed for an ion-sensitive solid-contact electrode for measuring ion activity in a measurement medium. An ion-sensitive solid-contact electrode having such a measuring element and an electrochemical sensor having such a solid-contact electrode are also disclosed. The measuring element can include an ion-sensitive layer arranged to contact a measurement medium when in operation, and conductive to lithium ions; and a single-phase electrically conductive layer, which includes metallic lithium or a lithium-(0)-alloy. A solid-state electrolyte layer can be arranged between the ion-sensitive layer and the electrically conductive layer.

Abstract: Measurement unit for an ion-sensitive solid-state electrode, that serves to measure pH in a measurement solution, with a layered structure including an ion-sensitive glass layer with a first ring-shaped contact surface, an electrically conducting layer that directly or via at least one intermediate layer adheres to the ion-sensitive glass layer, and a substrate that adheres to the electrically conducting layer and is provided with a second ring-shaped contact surface; and with a holding member that is provided with a first ring-shaped sealing surface, a second ring-shaped sealing surface, and an annular section; wherein the first ring-shaped sealing surface is sealingly connected to the first ring-shaped contact surface, wherein the second ring-shaped sealing surface is connected to the second ring-shaped contact surface of the substrate, and wherein the first and second ring-shaped sealing surfaces of the holding member are sealingly connected by the annular section.

Abstract: An ion-sensitive electrode, that serves to measure an ion activity in a measurement solution, in particular a pH value, is configured with a layered structure including a glass layer as ion-sensitive glass membrane, and a substrate as first holding member, which directly or via at least one intermediate layer adheres to the ion-sensitive glass membrane, wherein the ion-sensitive glass membrane is held under compressive stress by the first holding member over the whole range or part of the range of the specified operating temperature of the ion-sensitive electrode.

Abstract: An electrochemical sensor (1, 101) has a sensor element (15, 115) with a measuring surface (8, 108) that faces a measuring medium (5) during use. The sensor element has a planar measuring element (2, 102). A sensor shaft (4, 104) has an aperture (13, 113) with a bezel (11, 111) at an end which, during use, faces the measuring medium. The sensor element is installed in the area of the aperture. The electrochemical sensor also has an annular sealing element (9, 109), which is arranged between the sensor element and the bezel. An insulator element (10, 110) is firmly and inseparably connected to the measuring element, exposing or recessing the measuring surface. Thus, the sealing element, which protects the electrochemical sensor against the ingress of measuring medium, is arranged sealingly between the insulator element and the bezel.

Abstract: A measuring element is disclosed for an ion-sensitive solid-contact electrode for measuring ion activity in a measurement medium. An ion-sensitive solid-contact electrode having such a measuring element and an electrochemical sensor having such a solid-contact electrode are also disclosed. The measuring element can include an ion-sensitive layer arranged to contact a measurement medium when in operation, and conductive to lithium ions; and a single-phase electrically conductive layer, which includes metallic lithium or a lithium-(0)-alloy. A solid-state electrolyte layer can be arranged between the ion-sensitive layer and the electrically conductive layer.