Abstract: A calibrated lithographic model may be used to generate a lithographic model output based on an integrated circuit (IC) design layout. Next, at least a chemical parameter may be extracted from the lithographic model output. A calibrated defect rate model may then be used to predict a defect rate for the IC design layout based on the chemical parameter.

Abstract: A computational lithography process uses machine learning models. An aerial image produced by a lithographic mask is first calculated using a two-dimensional model of the lithographic mask. This first aerial image is applied to a first machine learning model, which infers a second aerial image. The first machine learning model was trained using a training set that includes aerial images calculated using a more accurate three-dimensional model of lithographic masks. The two-dimensional model is faster to compute than the three-dimensional model but it is less accurate. The first machine learning model mitigates this inaccuracy.

Abstract: Initial source shapes for source mask optimization are determined based on a layout of the lithographic mask. In one approach, a layout of a lithographic mask is received. Different sections of the lithographic mask, referred to as clips, are selected. These clips are applied to a machine learning model which infers source shapes from the clips. The inferred source shapes are used as the initial source shapes for source mask optimization.

Abstract: A calibrated lithographic model may be used to generate a lithographic model output based on an integrated circuit (IC) design layout. Next, at least a chemical parameter may be extracted from the lithographic model output. A calibrated defect rate model may then be used to predict a defect rate for the IC design layout based on the chemical parameter.

Abstract: In the method for the epoxidation of an olefin, the olefin is continuously reacted with hydrogen peroxide in a mixed reactor in the presence of a water soluble epoxidation catalyst, comprising a manganese complex, the reaction is carried out in a reaction mixture comprising an aqueous liquid phase and an organic liquid phase with mixing of the liquid phases, reaction mixture is continuously withdrawn from the mixed reactor and separated into a separated aqueous phase and a separated organic phase, and part of the separated aqueous phase is continuously recycled into the mixed reactor, with the combined hold-up time of aqueous phase in withdrawing, separating phases and recycling aqueous phase being kept at less than 15 minutes.

Abstract: Epoxidation of an olefin is carried out by continuously reacting the olefin with hydrogen peroxide in the presence of a water soluble epoxidation catalyst, comprising a manganese complex, in a reaction mixture comprising an aqueous liquid phase and an organic liquid phase using a loop reactor with mixing of the liquid phases, and during the reaction the concentration of hydrogen peroxide in the aqueous liquid phase is maintained at less than 1.0% by weight.

Abstract: The method for the epoxidation of propene comprises continuously reacting propene with hydrogen peroxide in the presence of a homogeneous epoxidation catalyst in a reaction mixture comprising an aqueous liquid phase and an organic liquid phase using a loop reactor with mixing of the liquid phases, withdrawing aqueous phase from the loop reactor and extracting it by liquid-liquid-extraction using propene as extractant to provide an extract comprising propene and propene oxide.

Abstract: Epoxidation of an olefin is carried out by continuously reacting the olefin with hydrogen peroxide in the presence of a homogeneous epoxidation catalyst in a reaction mixture comprising an aqueous liquid phase and an organic liquid phase, using a loop reactor with mixing of the liquid phases. The loop reactor comprises a measuring section in which the liquid phases are temporarily separated, at least one pH electrode is arranged in the measuring section in contact with the separated aqueous phase, a pH of the separated aqueous phase is determined with the pH electrode and the pH is maintained in a predetermined range by adding acid or base to the loop reactor.

Abstract: In the method for the epoxidation of an olefin, the olefin is continuously reacted with hydrogen peroxide in a mixed reactor in the presence of a water soluble epoxidation catalyst, comprising a manganese complex, the reaction is carried out in a reaction mixture comprising an aqueous liquid phase and an organic liquid phase with mixing of the liquid phases, reaction mixture is continuously withdrawn from the mixed reactor and separated into a separated aqueous phase and a separated organic phase, and part of the separated aqueous phase is continuously recycled into the mixed reactor, with the combined hold-up time of aqueous phase in withdrawing, separating phases and recycling aqueous phase being kept at less than 15 minutes.

Abstract: Epoxidation of an olefin is carried out by continuously reacting the olefin with hydrogen peroxide in the presence of a water soluble epoxidation catalyst, comprising a manganese complex, in a reaction mixture comprising an aqueous liquid phase and an organic liquid phase using a loop reactor with mixing of the liquid phases, and during the reaction the concentration of hydrogen peroxide in the aqueous liquid phase is maintained at less than 1.0% by weight.

Abstract: A method for production of a methionine salt in a reactive rectification column containing a weir having a height of 100 mm or more is provided.

Abstract: Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.

Abstract: A method for production of a methionine salt in a reactive rectification column containing a weir having a height of 100 mm or more is provided.

Abstract: A reaction system suitable for production of a methionine salt contains a reactive rectification column containing a weir having a height of 100 mm or more.

Abstract: Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.

Abstract: Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.

Abstract: A reaction system suitable for production of a methionine salt contains a reactive rectification column containing a weir having a height of 100 mm or more.

Abstract: Apparatus and processes are provided for forming epoxide compounds. In one embodiment, a process for the manufacture of an epoxide is provided including adding an oxidant, a water-soluble manganese complex and a terminal olefin to form a multiphasic reaction mixture, reacting the terminal olefin with the oxidant in the multiphasic reaction mixture having at least one organic phase in the presence of the water-soluble manganese complex, separating the reaction mixture into the at least one organic phase and an aqueous phase, and reusing at least part of the aqueous phase. The invention is also related to a device for performing the above process.

Abstract: The invention relates to a layered construction for a Gunn diode. The layered construction comprises a series of stacked layers consisting of a first highly doped nd GaAs layer (3), a graded AlGaAs layer (5), which is placed upon the first highly doped layer (3), whereby the aluminum concentration of this layer, starting from the boundary surface to the first nd GaAs layer (3), decreases toward the opposite boundary surface of the AlGaAs layer (5), and of a second highly doped n+ layer (7). An undoped intermediate layer (4, 6) serving as a diffusion or segregation stop layer is placed on at least one boundary surface of the AlGaAs layer (5) to one of the highly doped layers (3, 7) and prevents an unwanted doping of the graded layer.

Abstract: The present invention is directed to an improved process for producing methionine in which the by-product methionyl-methionine is quickly converted to the product methionine by a hydrolysis reaction. The process is performed at high temperatures (200° C. to 280° C.) and short residence times (20 s to 200 s) and results in an improved yield of end product methionine.