Abstract: The invention relates to an electrochemical cell comprising: —at least one anode comprising metallic lithium or a lithium alloy or at least one anode comprising a current collector at least partially covered with metallic lithium deposited after at least one charge of the cell, the cell not containing metallic lithium at the time of its manufacture, —at least one cathode, - a liquid or gelled electrolyte composition comprising: a) a solvent comprising: i) either a mixture of 1,1,1,3,3,3-hexafluoro-2-methoxypropane (HFMP) and/or 1,1,1,3,3,3-hexafluoro-2-(fluoromethoxy)propane (HFMFP), ethylene monofluorocarbonate (F1EC) and 2,2,2-trifluoroethyl methyl carbonate (F3EMC), ii) or a mixture of 1,1,1,3,3,3-hexafluoro-2-methoxypropane (HFMP) and/or 1,1,1,3,3,3-hexafluo-ro-2-(fluoromethoxy)propane (HFMFP), ethylene monofluorocarbonate (F1EC) and 2,2,2-trifluoroethyl acetate (F3EA), b) at least one salt whose cation is the lithium cation, c) lithium difluorophosphate LiPO2F2 in an amount representing from 0.

Abstract: Disclosed is an electrolyte composition comprising: a) a solvent comprising: i) either a mixture of 1,1,1,3,3,3-hexaflu-oro-2-methoxypropane (HFMP) or of 1,1,1,3,3,3-hexafluoro-2-(fluoromethoxy)propane (HFMFP), of monofluoroethylene carbonate (F1EC) and of 2,2,2-trifluoroethyl methyl carbonate (F3EMC), ii) or a mixture of 1,1,1,3,3,3-hexafluoro-2-methoxypropane (HFMP) or of 1,1,1,3,3,3-hexafluoro-2-(fluoromethoxy)propane (HFMFP), of monofluoroethylene carbonate (F1EC) and of 2,2,2-trifluoroethyl acetate (F3EA), b) at least one lithium salt, the cation of which is the cation of an alkali metal.

Abstract: A gel-type electrolyte comprising a matrix which is a poly(vinylidene fluoride-co-hexafluoropropylene) polymer in which is embedded a liquid mixture comprising at least one lithium salt and a solvent comprising at least one linear carbonate, the poly(vinylidene fluoride-co-hexafluoropropylene) polymer matrix representing 5 to 95% by weight in relation to the weight of the gel-type electrolyte and the liquid mixture representing 95 to 5% by weight in relation to the weight of the gel-type electrolyte. This electrolyte exhibits increased stability with respect to oxidation and reduction.

Abstract: An electrolyte composition comprising: a) a solvent comprising: a mixture of at least two saturated cyclic carbonates, at least one of these saturated cyclic carbonates being fluorinated, at least one ether, said at least one saturated cyclic carbonate representing at most 1.5% by weight of the solvent, said at least one ether representing at least 40% by weight of the solvent; b) at least one lithium salt other than lithium difluorophosphate; c) lithium difluorophosphate in an amount representing from 0.1 to 1% by weight relative to the sum of weight of the solvent and weight of said at least one lithium salt. The use of this composition in an electrochemical cell comprising a lithium anode allows increased performance of the cell when it is discharged under a strong current at low temperature, and limited self-discharging when in operation at ambient temperature.

Abstract: An electrolyte composition for a lithium-ion electrochemical element, comprising: —at least one lithium tetrafluoride or hexafluoride salt, —the salts of lithium bis(fluorosulfonyl)imide LiFSI, —vinylene carbonate, —ethylene sulfate, —at least one organic solvent chosen from the group consisting of cyclic or linear carbonates, cyclic or linear esters, cyclic or linear ethers and a mixture of same. The use of this composition in a lithium-ion electrochemical element increases the service life of the element, in particular under low and high temperature cycling conditions.

Abstract: An electrolyte composition including (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one pyridine-SO3 complex of formula (I) wherein R is selected independently at each occurrence from F, C1 to C10 alkyl, C2 to C10 alkenyl, and C2 to C10 alkynyl, wherein alkyl, alkenyl, and alkynyl may be substituted by one or more substituents selected from F and CN; and n is an integer selected from 1, 2, 3, 4, and 5; and (vi) optionally one or more additives; and its use in electrochemical cells.

Abstract: An electrolyte composition for a lithium-ion electrochemical cell, comprising: at least one tetrafluorinated or hexafluorinated lithium salt, lithium bis(fluorosulfonyl)imide LiFSI salt, vinylene carbonate, ethylene sulfate, lithium difluorophosphate, at least one organic solvent selected from the group consisting of cyclic or carbonates, cyclic or linear esters, cyclic or linear ethers and a mixture thereof, the ratio of the mass of ethylene sulfate to the mass of vinylene carbonate before addition to the solvent being strictly less than 1, the mass percentage of lithium bis(fluorosulfonyl)imidide representing less than 1% of the mass of the group consisting of said at least one tetrafluorinated or hexafluorinated lithium salt, the lithium bis(fluorosulfonyl)imidide salt and said at least one organic solvent. The use of this composition in a lithium-ion electrochemical cell increases the life of the cell, especially under low- and high-temperature cycling conditions.

Abstract: An electrolyte composition (A) containing at least one aprotic organic solvent and at least one compound of formula (I) wherein A+ is selected from Li+, Na+, K+, Cs+, and ammonium; is a bidentate radical derived from a (hetero)aromatic 1,2-, 1,3- or 1,4-diol, from a (hetero)aromatic 1,2-, 1,3- or 1,4-dicarboxylic acid or from a (hetero)aromatic 1,2-, 1,3- or 1,4-hydroxycarboxylic acid by abstracting the two H atoms of pairs of adjacent OH groups; and R1 and R2 are organic substituents.

Abstract: An electrolyte composition including (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one pyridine-SO3 complex of formula (I) wherein R is selected independently at each occurrence from F, C1 to C10 alkyl, C2 to C10 alkenyl, and C2 to C10 alkynyl, wherein alkyl, alkenyl, and alkynyl may be substituted by one or more substituents selected from F and CN; and n is an integer selected from 1, 2, 3, 4, and 5; and (vi) optionally one or more additives; and its use in electrochemical cells.

Abstract: An electrolyte composition (A) containing at least one aprotic organic solvent and at least one compound of formula (I) wherein A+ is selected from Li+, Na+, K+, Cs+, and ammonium; is a bidentate radical derived from a (hetero)aromatic 1,2-, 1,3- or 1,4-diol, from a (hetero)aromatic 1,2-, 1,3- or 1,4-dicarboxylic acid or from a (hetero)aromatic 1,2-, 1,3- or 1,4-hydroxycarboxylic acid by abstracting the two H atoms of pairs of adjacent OH groups; and R1 and R2 are organic substituents.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission is provided, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission is provided, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.