Abstract: The present disclosure relates to a novel staged-synthesis method for introduction of various metals in the structure of zeolite frameworks by isomorphous substitution. This new method is based on a hydrothermal synthesis in which the metal addition to the precursor suspensions (gel) is delayed. This so-called “staged-synthesis method” allows to obtain nanosized silanol highly homo-geneous crystalline zeolite structures with a control of the metal location.

Abstract: The present disclosure relates to a novel method for introducing various metals in the structure of zeolite frameworks by isomorphous substitution. This new method is based on a hydrothermal reaction of the metal with the zeolite. This method allows obtaining zeolite with a structure and with control of the metal location.

Abstract: The present disclosure relates to a novel staged-synthesis method for introduction of various metals in the structure of zeolite frameworks by isomorphous substitution. This new method is based on a hydrothermal synthesis in which the metal addition to the precursor suspensions (gel) is delayed. This so-called “staged-synthesis method” allows to obtain nanosized silanol highly homo- geneous crystalline zeolite structures with a control of the metal location.

Abstract: The present disclosure relates to a novel method for introducing various metals in the structure of zeolite frameworks by isomorphous substitution. This new method is based on a hydrothermal reaction of the metal with the zeolite. This method allows obtaining zeolite with a structure and with control of the metal location.

Abstract: The present disclosure relates to an RHO-type zeolite comprising caesium and M1 wherein M1 is selected from Na and/or Li remarkable in that it has a Si/Al molar ratio comprised between 1.2 and 3.0 as determined by 29Si magic angle spinning nuclear magnetic resonance, in that the RHO-type zeolite has a specific surface area comprised between 40 m2g?1 and 250 m2g?1 as determined by N2 adsorption measurements, in that the RHO-type zeolite being in the form of one or more nanoparticles with an average crystal size comprised between 10 nm and 400 nm as determined by scanning electron microscopy wherein said nanoparticles form monodispersed nanocrystals or form aggregates of nanocrystals having an average size ranging from 100 nm to 500 nm, as determined by scanning electron microscopy.

Abstract: The present disclosure relates to a chabazite-type zeolite, comprising at least two cages composed of 4- and 8-membered rings connected by one 6-membered double ring, remarkable in that it has a Si/Al molar ratio comprised between 1 and 15, in that it comprises caesium and potassium with a Cs/K molar ratio of at most 5.0 and in that it forms nanoparticles with an average crystal size comprised between 5 nm and 250 nm and with a specific surface area comprised between 50 m2g?1 and 200 m2g?1. Amorphous precursors, devoid of an organic structure-directing agent, as well as a method for preparation of these amorphous precursors in the absence of such organic structure-directing agent and method for preparation of the chabazite-type zeolite, are also described. Finally, the use of the chabazite-type zeolite as a sorbent for carbon dioxide is also demonstrated.

Abstract: Some embodiments are directed to a method for the preparation of defect-free nanosized synthetic zeolite materials, to the defect-free nanosized synthetic zeolite materials, to stable colloidal suspensions of the defect-free synthetic zeolite materials, and to the use of the defect-free nanosized synthetic zeolite materials and the stable colloidal suspensions in various applications.

Abstract: Some embodiments are directed to a method for the preparation of defect-free nanosized synthetic zeolite materials, to the defect-free nanosized synthetic zeolite materials, to stable colloidal suspensions of the defect-free synthetic zeolite materials, and to the use of the defect-free nanosized synthetic zeolite materials and the stable colloidal suspensions in various applications.