Patents by Inventor Julien Hernandez

Julien Hernandez has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20140205522
    Abstract: The composition of the invention is based on oxides of cerium, of zirconium and of at least one rare earth metal other than cerium, with a cerium oxide content of greater than 50% by weight and it has, after calcination at 1000° C. for 4 hours, a specific surface area of at least 20 m2/g and an amount of mobile oxygen between 200° C. and 400° C. of at least 0.8 ml O2/g. It is prepared by a process in which, in a reactor, a mixture of compounds of cerium, of zirconium and of the other rare earth metal is reacted continuously with a basic compound with a residence time of the reaction medium in the mixing zone of the reactor of at most 100 milliseconds; the precipitate is heated then brought into contact with a surfactant before being calcine.
    Type: Application
    Filed: June 13, 2012
    Publication date: July 24, 2014
    Applicant: RHODIA OPERATIONS
    Inventors: Simon Ifrah, Emmanuel Rohart, Julien Hernandez, Dominique Horbez, Lama Itani
  • Publication number: 20140147357
    Abstract: The invention relates to a composition essentially consisting of a zirconia-ceria mixed oxide, with a zirconia content of at least 40 wt. % and, after 4 hours of calcination at 1000° C., a specific surface area of at least 25 m2/g and a quantity of mobile oxygen between 200° C. and 400° C. of at least 0.5 ml O2/g. Said composition is produced using a method wherein a mixture of cerium and zirconium compounds is continuously reacted with a basic compound in a reactor, with a maximum residence time of the reactive medium in the mixture zone of the reactor of 100 milliseconds; and the precipitate is heated then brought into contact with a surfactant before being calcinated.
    Type: Application
    Filed: June 25, 2012
    Publication date: May 29, 2014
    Applicant: Rhodia Operations
    Inventors: Simon Ifrah, Lama Itani, Julien Hernandez, Dominique Horbez
  • Patent number: 8734742
    Abstract: A method is described for treating a gas including nitrogen oxides (NOx). The method can include conducting a reduction reaction of the nitrogen oxides with a nitrogen reducing agent. Further described, is a catalyst used for the reduction reaction which is a catalytic system including a composition based on cerium oxide and including niobium oxide in a proportion by a mass of from 2% to 20%.
    Type: Grant
    Filed: September 28, 2011
    Date of Patent: May 27, 2014
    Assignee: Rhodia Operations
    Inventors: Julien Hernandez, Emmanuel Rohart, Rui Jorge Coelho Marques, Deborah Jayne Harris, Clare Jones
  • Publication number: 20140140910
    Abstract: The invention relates to a composition essentially consisting of ceria-zirconia mixed oxide, with a ceria content of at least 60 wt. % and, after 4 hours of calcination at 1000° C., a specific surface area of at least 15 m2/g and a quantity of mobile oxygen between 200° C. and 400° C. of at least 0.7 ml 02/g. Said composition is produced using a method wherein a mixture of cerium and zirconium compounds is continuously reacted with a basic compound in a reactor, with a maximum residence time of the reactive medium in the mixture zone of the reactor of 100 milliseconds; and the precipitate is heated then brought into contact with a surfactant before being calcinated.
    Type: Application
    Filed: June 25, 2012
    Publication date: May 22, 2014
    Applicant: RHODIA OPERATIONS
    Inventors: Simon Ifrah, Lama Itani, Julien Hernandez, Dominique Horbez
  • Publication number: 20140044629
    Abstract: The invention relates to a method for treating a gas containing nitrogen oxides (NOx), in which an NOx-reduction reaction is carried out using a nitrogen-containing reducing agent, which invention is characterized in that the catalyst used for the reduction reaction is a catalytic system containing a composition comprising zirconium, niobium in the following percentages by weight, expressed in terms of the weight of oxide: 10-50% of cerium, 5-20% of niobium and the remainder consisting of zirconium.
    Type: Application
    Filed: February 28, 2012
    Publication date: February 13, 2014
    Applicants: MAGNESIUM ELEKTRON LIMITED, RHODIA OPERATIONS
    Inventors: Laure Bisson, Julien Hernandez, Rui Miguel Jorge Coelho Marques, Emmanuel Rohart, Mila Bortun, Deborah Jayne Harris, Clare Jones
  • Publication number: 20140013659
    Abstract: A dispersion includes an apolar organic phase, at least one amphiphilic agent, and solid objects based on particles of an iron compound in crystallized form of small size.
    Type: Application
    Filed: December 19, 2011
    Publication date: January 16, 2014
    Inventors: Lauriane D'Alencon, Julien Hernandez, Virginie Harle, Michael Lallemand
  • Patent number: 8524183
    Abstract: A composition is described that includes oxides of zirconium, cerium and another rare earth different from cerium, having a cerium oxide content not exceeding 50 wt % and, after calcination at 1000° C. for 6 hours, a maximal reducibility temperature not exceeding 500° C. and a specific surface of at least 45 m2/g. The composition can be prepared according to a method that includes continuously reacting a mixture that includes compounds of zirconium, cerium and another rare earth having a basic compound for a residence time not exceeding 100 milliseconds, wherein the precipitate is heated and contacted with a surfactant before calcination.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: September 3, 2013
    Assignee: Rhodia Operations
    Inventors: Simon Ifrah, Emmanuel Rohart, Julien Hernandez, Stéphane Denaire
  • Publication number: 20130210617
    Abstract: A composition based on cerium and niobium oxide in a proportion of niobium oxide of 2% to 20% is described. This composition can include zirconium oxide, optionally 50% of cerium oxide, 2% to 20% of niobium oxide, and at most 48% of zirconium oxide. Also described, is the use of the composition for treating exhaust gases.
    Type: Application
    Filed: July 5, 2011
    Publication date: August 15, 2013
    Applicant: Rhodia Operations
    Inventors: Julien Hernandez, Rui Jorge Coelho Marques, Emmanuel Rohart
  • Publication number: 20130195743
    Abstract: A method is described for treating a gas including nitrogen oxides (NOx). The method can include conducting a reduction reaction of the nitrogen oxides with a nitrogen reducing agent. Further described, is a catalyst used for the reduction reaction which is a catalytic system including a composition based on cerium oxide and including niobium oxide in a proportion by a mass of from 2% to 20%.
    Type: Application
    Filed: September 28, 2011
    Publication date: August 1, 2013
    Applicants: MAGNESIUM ELEKTRON LIMITED, RHODIA OPERATIONS
    Inventors: Julien Hernandez, Emmanuel Rohart, Rui Jorge Coelho Marques, Deborah Jayne Harris, Clare Jones
  • Publication number: 20130164201
    Abstract: A composition based on cerium, zirconium and tungsten is described. The composition has a content expressed as an oxide, of which cerium is from 5% to 30% of the composition, tungsten is from 2% to 17% of the composition, and the remainder of the composition is zirconium. After aging at 750° C. under an air atmosphere including 10% water, it has a two-phase crystallographic structure having a tetragonal zirconia phase and a monoclinic zirconia phase, with no presence of a crystalline phase including tungsten. The composition can be used as a catalyst, especially in an SCR process.
    Type: Application
    Filed: May 17, 2011
    Publication date: June 27, 2013
    Applicants: MAGNESIUM ELEKTRON LIMITED, RHODIA OPERATIONS
    Inventors: Julien Hernandez, Emmanuel Rohart, Rui Jorge Coelho Marques, Deborah Jane Harris, Clare Jones
  • Publication number: 20130052108
    Abstract: A composition is described that includes oxides of zirconium, cerium and another rare earth different from cerium, having a cerium oxide content not exceeding 50 wt % and, after calcination at 1000° C. for 6 hours, a maximal reducibility temperature not exceeding 500° C. and a specific surface of at least 45 m2/g. The composition can be prepared according to a method that includes continuously reacting a mixture that includes compounds of zirconium, cerium and another rare earth having a basic compound for a residence time not exceeding 100 milliseconds, wherein the precipitate is heated and contacted with a surfactant before calcination.
    Type: Application
    Filed: January 10, 2011
    Publication date: February 28, 2013
    Applicant: RHODIA OPERATIONS
    Inventors: Simon Ifrah, Emmanuel Rohart, Julien Hernandez, Stéphane Denaire
  • Publication number: 20120046163
    Abstract: A composition is described that includes a perovskite of the formula LaMO3, where M is at least one element selected from among iron, aluminium or manganese, in the form of particles dispersed on an alumina or aluminium oxyhydroxide substrate, wherein after calcination at 700° C. for 4 hours, the perovskite is in the form of a pure crystallographic phase, and in that the size of the perovskite particles does not exceed 15 nm. The described composition can be used in the field of catalysis.
    Type: Application
    Filed: February 25, 2010
    Publication date: February 23, 2012
    Applicant: RHODIA OPERATIONS
    Inventors: Simon Ifrah, Olivier L'archer, Rui Jorge Coelho Marques, Michael Lallemand, Julien Hernandez
  • Publication number: 20110263784
    Abstract: The invention relates to a novel method of preparing silicas and to highly-structured silicas having the following characteristics: a specific surface area CTAB (SCTAB) of between 40 and 525 m2g/g; a specific surface area BET (SBET) of between 45 and 550 m2g; an object size distribution width Ld ((d84?D16)/d50), which is measured by XDC particle size analysis after deagglomeration with ultrasound, of at least 0.91; and a pore-size distribution such that ratio V(d5?d50)/V(d5?d100) is at least 0.66. The invention also relates to the use of said silicas as polymer reinforcing fillers.
    Type: Application
    Filed: June 22, 2011
    Publication date: October 27, 2011
    Applicant: RHODIA CHIMIE
    Inventors: Rémi VALERO, Julien Hernandez
  • Publication number: 20110178227
    Abstract: Precipitated silicas including clusters of large primary silica particles having at the surface thereof small primary silica particles, have a specific surface area CTAB (SCTAB) ranging from 60 to 400 m2/g; a cluster average size d50, as measured by XDC grading after ultrasound deagglomeration, such that d50 (nm)>(6214/SCTAB (m2/g)+23; a pore volume distribution such that V(d5-d50)/V(d5-d100)>0.906?(0.0013×SCATB (m2/g)); and a pore size distribution such that Mode (nm)>(4166/SCTAB (m2/g))?9.2; such silicas are useful reinforcing fillers for polymers.
    Type: Application
    Filed: March 9, 2009
    Publication date: July 21, 2011
    Applicant: RHODIA OPERATIONS
    Inventors: Emmanuelle Allain, Julien Hernandez, Lionel Ventelon, Laurent Guy, Marc Airiau
  • Publication number: 20110152405
    Abstract: A diene rubber composition for tires based on at least (i) one diene elastomer, (ii) one reinforcing inorganic filler and (iii) one coupling agent which provides the bonding between the inorganic filler and the elastomer. The inorganic filler comprises at least one silica capable of being obtained by the preparation process of the type comprising the reaction of a silicate with an acidifying agent, whereby a silica suspension is obtained, followed by the separation and the drying of this suspension. The reaction of the silicate with the acidifying agent is carried out according to the following successive stages: (i) an aqueous suspension of precipitated silica, exhibiting a pH of between 2.5 and 5.3, is brought into contact (mixing) with acidifying agent and silicate, in such a way that the pH of the reaction medium is maintained between 2.5 and 5.3, (ii) silicate is added to the reaction medium obtained, so as to increase the pH of the reaction medium up to a value of between 4.7 and 6.3.
    Type: Application
    Filed: March 9, 2009
    Publication date: June 23, 2011
    Applicants: SOCIETE DE TECHNOLOGIE MICHELIN, Michelin Recherche et Technique S.A.
    Inventors: Damien Thomasson, Emmanuelle Allain, Julien Hernandez
  • Patent number: 7884153
    Abstract: The invention concerns a method for preparing anisotropic silica aggregates comprising the following steps: a) contacting at least one polymer with non-aggregated silica particles and/or highly dispersed in an aqueous medium, with a ratio R, polymer weight to silica particle surface, ranging between 0.03 and 2 mg/m; 2; and whereof the electrostatic value of the silica particle surface is not less than the value of the charge of the silica particle surface measured in an aqueous phase without added salts at a pH not less than 7; b) consolidating the aggregates obtained at step a) either by heat treatment, or by precipitation of a mineral compound.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: February 8, 2011
    Assignees: Rhodia Chimie, C.N.R.S.
    Inventors: Lionel Ventelon, Julien Hernandez, Françoise Lafuma, Christophe Chassenieux, Christelle Perreur
  • Publication number: 20100221541
    Abstract: The invention relates to a novel method of preparing silicas and to highly-structured silicas having the following characteristics: a specific surface area CTAB (SCTAB) of between 40 and 525 m2/g; a specific surface area BET (SBET) of between 45 and 550 m2/g; an object size distribution width Ld ((d84?d16)/d50), which is measured by XDC particle size analysis after deagglomeration with ultrasound, of at least 0.91; and a pore-size distribution such that ratio V(d5?d50)/V(d5?d100) is at least 0.66. The invention also relates to the use of said silicas as polymer reinforcing fillers.
    Type: Application
    Filed: August 20, 2009
    Publication date: September 2, 2010
    Applicant: RHODIA CHIMIE,
    Inventors: Remi Valero, Julien Hernandez
  • Publication number: 20070219305
    Abstract: The invention concerns a method for preparing anisotropic silica aggregates comprising the following steps: a) contacting at least one polymer with non-aggregated silica particles and/or highly dispersed in an aqueous medium, with a ratio R, polymer weight to silica particle surface, ranging between 0.03 and 2 mg/m; 2; and whereof the electrostatic value of the silica particle surface is not less than the value of the charge of the silica particle surface measured in an aqueous phase without added salts at a pH not less than 7; b) consolidating the aggregates obtained at step a) either by heat treatment, or by precipitation of a mineral compound.
    Type: Application
    Filed: July 7, 2004
    Publication date: September 20, 2007
    Inventors: Lionel Ventelon, Julien Hernandez, Francoise Lafuma
  • Publication number: 20070181845
    Abstract: Thermal and/or acoustic insulation materials based on dried precipitated silica, having a total pore volume of from 1 to 5 cm3/g and optionally containing reinforcing fillers and/or opacifying agents, are prepared by: (A) filtering an aqueous dispersion D containing precipitated silica particles in a filter press, whereby a compacted filter cake is obtained; and then (B) drying the filter cake in the compacted state as obtained after step (A).
    Type: Application
    Filed: June 29, 2004
    Publication date: August 9, 2007
    Inventors: Julien Hernandez, Catherine Enjalbert
  • Patent number: 7250463
    Abstract: Diene rubber compositions are described containing a diene elastomer, a reinforcing inorganic filler, and a coupling agent wherein the inorganic filler includes a silica having the following characteristics: (a) a BET specific surface area between 45 and 400 m2/g; (b) a CTAB specific surface area between 40 and 380 m2/g; (c) an average particle size (by mass), dw, of 20 to 300 nm; and at least one of the following characteristics, preferably two and more preferably all three: (d) a particle size distribution such that dw?/CTAB)?30; (e) a porosity which meets the criterion L/FI??0.0025 CTAB+0.85; (f) an amount of silanols per unit of surface area, NSiOH/nm2; NSiOH/nm2??0.027 CTAB+10.5. These diene rubber compositions can be used for the manufacture of tires or of semi-finished products intended for tires.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: July 31, 2007
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Olivier Durel, Arnaud Lapra, Julien Hernandez, Rémi Valero