Abstract: A process for preparing an organic film on a selected zone at the surface of a photosensitive semiconductor substrate, including (i) bringing a liquid solution which includes at least one organic adhesion primer into contact with at least the selected zone; (ii) polarizing the surface of the substrate to an electric potential more cathodic than the reduction potential of the organic adhesion primer; and (iii) exposing the selected zone to light radiation, the energy of which is at least equal to that of the band gap of the photosensitive semiconductor substrate.

Abstract: A process for mask-free localized grafting of organic molecules capable of being electrically activated, onto a composite surface comprising conductive and/or semiconductive portions, by placing said organic molecules in contact with said composite surface, in which said grafting is performed electrochemically in a single step on chosen, defined areas of said conductive and/or semiconductive portions, said areas being brought to a potential higher than or equal to a threshold electrical potential determined relative to a reference electrode, said threshold electrical potential being the potential above which grafting of said organic molecules takes place.

Abstract: The present invention relates to a process for preparing an organic film on a selected zone at the surface of a photosensitive semiconductor substrate, characterized in that it comprises the following steps: (i) bringing a liquid solution comprising at least one organic adhesion primer into contact with at least said selected zone; (ii) polarization of the surface of said substrate to an electric potential more cathodic than the reduction potential of the adhesion primer used in step (i); and (iii) exposure of said selected zone to light radiation, the energy of which is at least equal to that of the band gap of said semiconductor.

Abstract: The present invention concerns a method for localized grafting of an organic film in a selected area of an electrically conducting or semiconducting substrate, in the presence of a liquid solution containing at least one organic adhesion primer and at least one radically polymerizable monomer, different from the organic adhesion primer, by applying an electric potential to the substrate in the presence of a polarized microelectrode. The present invention also concerns an insulating organic film grafted on a conducting or semiconducting substrate, capable of being prepared using said method.

Abstract: The present invention provides a method for encapsulating biocompatible polymers. The method comprises using a solid support comprising at least one electrically conducting and/or semiconducting region containing a reducible oxide on its surface, wherein at least one zone of this surface is functionalized with an electrografted organic film obtained from electroactive organic precursors each comprising at least one functional group of interest, and wherein the number of functional groups of interest accessible for the formation of a covalent, ionic or hydrogen bond with a complementary group within said film represents at least 90% of the total number of functional organic groups of interest, and wherein the density of the accessible functional groups of interest is between 104/?m2 and 1010/?m2. The method further comprises attaching molecules of interest or objects bearing a complementary function to the solid support.

Abstract: The invention relates to a method of bonding a polymer surface to an electrically conductive or semiconductive surface, which method is characterized in that it comprises: a) the electrografting of an organic film onto the conductive or semiconductive surface; and then b) an operation of bonding the polymer surface to the conductive or semiconductive surface thus grafted. It also relates to applications of this method and to structures obtained by its implementation.

Abstract: The invention concerns a solid support comprising a functionalized electricity conductor or semiconductor surface coated with a functionalized electrografted organic layer wherein at least 90% of the number of functional groups of interest is accessible. The invention also concerns the method for preparing such a support and uses thereof, in particular as adhesive primer for fixing molecules of interest or objects bearing a complementary function (molecular adhesive).

Abstract: The invention relates to a method of bonding a polymer surface to an electrically conductive or semiconductive surface, which method is characterized in that it comprises: a) the electrografting of an organic film onto the conductive or semiconductive surface; and then b) an operation of bonding the polymer surface to the conductive or semiconductive surface thus grafted. It also relates to applications of this method and to structures obtained by its implementation.

Abstract: The invention concerns a mask-free localised grafting of organic molecules capable of being electrically activated, on a composite surface comprising conductive and/or semiconductive portions, by contacting said organic molecules with said composite surface, whereby the grafting is carried out electrochemically in one single step on specific selected zones of said conductive and/or semiconductive portions, said zones being brought to a potential not less than an electric potential threshold determined relative to a reference electrode, said electric potential threshold being the potential beyond which the grafting of said organic molecules occurs.

Abstract: A process for mask-free localized grafting of organic molecules capable of being electrically activated, onto a composite surface comprising conductive and/or semiconductive portions, by placing said organic molecules in contact with said composite surface, in which said grafting is performed electrochemically in a single step on chosen, defined areas of said conductive and/or semiconductive portions, said areas being brought to a potential higher than or equal to a threshold electrical potential determined relative to a reference electrode, said threshold electrical potential being the potential above which grafting of said organic molecules takes place.