Abstract: An electrode unit for a medical resectoscope for the electrosurgical resection of tissue in a fluid-filled cavity in a patient includes an elongated rod-shaped electrode shaft which on its distal end has an electrode support and a cutting electrode that is fastened to the electrode support and may be acted on by alternating current. A spatula element that is designed for supporting tissue and that extends distally beyond the cutting electrode is situated on the electrode support, the spatula element having two support flanks that extend distally on both sides of the cutting electrode to form outer edges of the spatula element, at least one of the support flanks having an inwardly directed indentation to form a constriction in the area of the cutting electrode.

Abstract: An electrode unit for a medical resectoscope for the electrosurgical resection of tissue in a fluid-filled cavity in a patient includes an elongated rod-shaped electrode shaft which on its distal end has an electrode support and a cutting electrode that is fastened to the electrode support and may be acted on by alternating current. A spatula element that is designed for supporting tissue and that extends distally beyond the cutting electrode is situated on the electrode support, the spatula element having two support flanks that extend distally on both sides of the cutting electrode to form outer edges of the spatula element, at least one of the support flanks having an inwardly directed indentation to form a constriction in the area of the cutting electrode.

Abstract: The present invention aims to provide a heat-curable composition that is capable of providing a cured product having low vapor permeability, a low linear expansion coefficient, and a low refractive index. The present invention relates to a curable composition including a fluorine-containing polymer having a hydroxyl value of 100 mgKOH/g or higher and a refractive index of 1.42 or lower and an epoxy compound.

Abstract: The invention provides a hydrophilizing agent which is to be added to a polymer having a large contact angle to produce a porous polymer film that has a small contact angle and that can maintain this small contact angle even after 168-hour contact with an aqueous sodium hypochlorite solution. The hydrophilizing agent contains a fluoropolymer having a contact angle of 50° or smaller and a weight reduction rate of 7% or lower.

Abstract: The present invention aims to provide a heat-curable composition that is capable of providing a cured product having low vapor permeability, a low linear expansion coefficient, and a low refractive index. The present invention relates to a curable composition including a fluorine-containing polymer having a hydroxyl value of 100 mgKOH/g or higher and a refractive index of 1.42 or lower and an epoxy compound.

Abstract: The present invention aims to provide a composition having excellent hydrophilicity, water permeability, mechanical strength, chemical durability, and low-fouling property, and capable of producing a porous polymer membrane from which a hydrophilic agent is less likely to be eluted. The composition of the present invention includes a vinylidene fluoride resin and a copolymer (A) including a vinyl alcohol unit and a fluoromonomer unit.

Abstract: The present invention aims to provide a porous polymer membrane that is excellent not only in water permeability and alkali resistance but also in mechanical strength. The porous polymer membrane of the present invention includes a fluoropolymer (A) that includes a vinylidene fluoride unit and a tetrafluoroethylene unit.

Abstract: A fluoropolymer including a vinylidene fluoride unit, a tetrafluoroethylene unit, and a unit represented by the following formula (1): —CHX1—CX2(OR)—??(1) wherein one of X1 and X2 is a hydrogen atom, and the other is a fluorine atom; and R is a hydrogen atom or a C1-C8 alkyl group.

Abstract: An object of the present invention is to provide porous polymer membranes with good water permeability and good hydrophilicity. The present invention relates to a porous polymer membrane including a copolymer (A) containing vinyl alcohol units and tetrafluoroethylene units, wherein an alternating ratio of the vinyl alcohol units and the tetrafluoroethylene units is at least 30%.

Abstract: A fluoropolymer including a vinylidene fluoride unit, a tetrafluoroethylene unit, and a unit represented by the following formula (1): —CHX1—CX2(OR)- ??(1) wherein one of X1 and X2 is a hydrogen atom, and the other is a fluorine atom; and R is a hydrogen atom or a C1-C8 alkyl group.

Abstract: The present invention aims to provide a porous polymer membrane that is excellent not only in water permeability and alkali resistance but also in mechanical strength. The porous polymer membrane of the present invention includes a fluoropolymer (A) that includes a vinylidene fluoride unit and a tetrafluoroethylene unit.

Abstract: A solid catalyst used in, for example, production of a perfluoroalkyl iodide telomer is effectively and continuously recovered and the recovered catalyst is continuously recycled to the reactor for reuse. A slurry containing a reaction product and the catalyst is drawn from the reaction system, and the catalyst in the drawn slurry is classified by means of a hydrocyclone, whereby a high-concentration slurry whose catalyst concentration is higher than that of the drawn slurry and a low-concentration slurry whose catalyst concentration is lower than that of the drawn slurry are obtained, and the high-concentration slurry is recycled to the reaction system.

Abstract: A solid catalyst used in, for example, production of a perfluoroalkyl iodide telomer is effectively and continuously recovered and the recovered catalyst is continuously recycled to the reactor for reuse. A slurry containing a reaction product and the catalyst is drawn from the reaction system, and the catalyst in the drawn slurry is classified by means of a hydrocyclone, whereby a high-concentration slurry whose catalyst concentration is higher than that of the drawn slurry and a low-concentration slurry whose catalyst concentration is lower than that of the drawn slurry are obtained, and the high-concentration slurry is recycled to the reaction system.

Abstract: The present invention provides a metallic copper catalyst for use in an ethylene addition reaction to polyfluoroalkyl iodides, a process for efficiently producing a polyfluoroalkylethyl iodide using such a metal copper catalyst in an ethylene addition reaction to a polyfluoroalkyl iodide, and a process for efficiently producing a polyfluoroalkylethyl iodide from a polyfluoroalkyl iodide using the same metallic copper catalyst in a telomerization reaction and a subsequent ethylene addition reaction.

Abstract: A process for preparing a fluorine-containing alcohol compound, the process comprising the step of reacting water with a halogenated fluorine compound in the presence of a catalyst for preparing a fluorine-containing alcohol compound, the catalyst obtained by supporting an ammine complex containing at least one component selected from the group consisting of the elements in Group 1B, Group 2B, Group 6A, Group 7A and Group 8 of the periodic table on at least one complex oxide selected from the group consisting of Si—Al complex oxides, Al—P complex oxides and Si—Al—P complex oxides.

Abstract: The present invention provides a metallic copper catalyst for use in an ethylene addition reaction to polyfluoroalkyl iodides, a process for efficiently producing a polyfluoroalkylethyl iodide using such a metal copper catalyst in an ethylene addition reaction to a polyfluoroalkyl iodide, and a process for efficiently producing a polyfluoroalkylethyl iodide from a polyfluoroalkyl iodide using the same metallic copper catalyst in a telomerization reaction and a subsequent ethylene addition reaction.

Abstract: The present invention provides a process for producing a fluoroalkyl iodide represented by the general formula (II): Rf-CH2CH2I??(II) wherein Rf is a perfluoroalkyl or polyfluoroalkyl group comprising 1 to 20 carbons, the process comprising reacting hydrogen iodide gas with a fluoroalkene in the presence of a catalyst. The present invention also provides a process for producing a fluoroester by reacting the fluoroalkyl iodide with a carboxylate.

Abstract: The present invention relates to a process for continuously producing a perfluoroalkyl iodide represented by the general formula Rf(CF2CF2)nI, wherein Rf is a C1-6 perfluoroalkyl and n is an integer from 1 to 4, the method comprising continuously supplying a perfluoroalkyl iodide as a telogen represented by the general formula RfI, wherein Rf is as defined above, and tetrafluoroethylene as a taxogen to a tubular reactor packed with a metal catalyst comprising a powdery spherical metal or a sintered metal; and conducting telomerization at a temperature of 60 to 160° C. under a pressure of 0.1 to 5 MPa (gauge pressure). According to the present invention, medium-chain perfluoroalkyl iodides can be continuously and efficiently produced with little generation of impurities, such as hydrogen-containing organic compounds and the like.

Abstract: A process for preparing a fluorine-containing alcohol compound, the process comprising the step of reacting water with a halogenated fluorine compound in the presence of a catalyst for preparing a fluorine-containing alcohol compound, the catalyst obtained by supporting an ammine complex containing at least one component selected from the group consisting of the elements in Group 1B, Group 2B, Group 6A, Group 7A and Group 8 of the periodic table on at least one complex oxide selected from the group consisting of Si—Al complex oxides, Al—P complex oxides and Si—Al—P complex oxides.