Abstract: In a conventional self-healing material, although the resin properties after self-healing are restored to the same level as the initial refractoriness and strength of the resin, no further extension of life can be expected. A resin cured product according to the present invention includes: a first vinyl monomer having an ester bond; a second vinyl monomer having a hydroxyl group; a transesterification reaction catalyst; and a boron compound.

Abstract: In a conventional self-healing material, although the resin properties after self-healing are restored to the same level as the initial refractoriness and strength of the resin, no further extension of life can be expected. A resin cured product according to the present invention includes: a first vinyl monomer having an ester bond; a second vinyl monomer having a hydroxyl group; a transesterification reaction catalyst; and a boron compound.

Abstract: An adsorbent which enables solid phase extraction of water-soluble molecules with high efficiency and excellent selectivity and an analysis system using the adsorbent, the adsorbent containing a structure represented by the formula I wherein R is a carrier component, the moiety other than R is a side-chain functional group, R and the benzene ring in the side-chain functional group are bonded directly or bonded through one or more atoms, R? is selected from the group consisting of hydroxy group, alkoxy group, amino group, alkylamino group, thiol group and alkyl sulfide group, R? is independently selected from the group consisting of hydroxy group, alkoxy group, alkyl group, amino group, alkylamino group, dialkylamino group, trialkylamino group, thiol group, alkyl sulfide group and hydrogen atom, x is an integer of zero or more and three or less, and n is the number of the side-chain functional groups contained in the carrier component.

Abstract: This invention is intended to synthesize a multi-branched polymer, which has an uniform molecular chain lengths and is free from branch defects, without the need for purification. This invention is also intended to synthesize a polyfunctional radical polymerization initiator represented by Formula 1: wherein n is an integer of 1 or larger; Y is a polyfunctional unsaturated compound; R1 is a hydrocarbon group; R2 is a structure in which one molecule of a radically polymerizable unsaturated hydrocarbon compound is bound to R1 and the oxygen atom; X1 of B—X1 (boron-X1) bond is an alkoxy or phenyl group; and X2 of B—X2 (boron-X2) bond is an alkoxy or phenyl group.

Abstract: The present invention provides a method for forming a polymer by using a mixture containing a polymerization initiator which is an adduct of a boron compound and a first unsaturated hydrocarbon compound, and a second unsaturated hydrocarbon compound, generating a radical by oxidization of the polymerization initiator and adding the radical to the second unsaturated hydrocarbon compound, thereby forming the polymer. According to the present invention, excellent controllability of alkylboranes for radical polymerization can be maintained and the structure of a polymerization initiation terminal can be freely selected and controlled. Thus, a terminal-modified polymer having functionality imparted to the terminal group can be prepared. In addition, a polymerization initiator having a plurality of polymerization starting points can be prepared, and polymers with special structures including multibranched polymers, grafted-type (comb-type) polymers and brush-shaped polymers can be prepared.

Abstract: This invention is intended to synthesize a multi-branched polymer, which has an uniform molecular chain lengths and is free from branch defects, without the need for purification. This invention is also intended to synthesize a polyfunctional radical polymerization initiator represented by Formula 1: wherein n is an integer of 1 or larger; Y is a polyfunctional unsaturated compound; R1 is a hydrocarbon group; R2 is a structure in which one molecule of a radically polymerizable unsaturated hydrocarbon compound is bound to R1 and the oxygen atom; X1 of B—X1 (boron-X1) bond is an alkoxy or phenyl group; and X2 of B—X2 (boron-X2) bond is an alkoxy or phenyl group.

Abstract: An adsorbent which enables solid phase extraction of water-soluble molecules with high efficiency and excellent selectivity and an analysis system using the adsorbent, the adsorbent containing a structure represented by the formula I wherein R is a carrier component, the moiety other than R is a side-chain functional group, R and the benzene ring in the side-chain functional group are bonded directly or bonded through one or more atoms, R? is selected from the group consisting of hydroxy group, alkoxy group, amino group, alkylamino group, thiol group and alkyl sulfide group, R? is independently selected from the group consisting of hydroxy group, alkoxy group, alkyl group, amino group, alkylamino group, dialkylamino group, trialkylamino group, thiol group, alkyl sulfide group and hydrogen atom, x is an integer of zero or more and three or less, and n is the number of the side-chain functional groups contained in the carrier component.

Abstract: The present invention provides a method for forming a polymer by using a mixture containing a polymerization initiator which is an adduct of a boron compound and a first unsaturated hydrocarbon compound, and a second unsaturated hydrocarbon compound, generating a radical by oxidization of the polymerization initiator and adding the radical to the second unsaturated hydrocarbon compound, thereby forming the polymer. According to the present invention, excellent controllability of alkylboranes for radical polymerization can be maintained and the structure of a polymerization initiation terminal can be freely selected and controlled. Thus, a terminal-modified polymer having functionality imparted to the terminal group can be prepared. In addition, a polymerization initiator having a plurality of polymerization starting points can be prepared, and polymers with special structures including multibranched polymers, grafted-type (comb-type) polymers and brush-shaped polymers can be prepared.

Abstract: An application to a resin material and a polymerization method of a polymerization agent having a polymerizable surface structure and a mechanism of supplying the polymerization agent, the polymerization agent exhibiting a polymerizing function in contact with the surface of the resin material. The resin material is obtained by living radical polymerization of a radical polymerization initiator exhibiting living property and an unsaturated monomer capable of radical polymerization with the polymerization initiator. The polymerization agent is brought into in contact with the surface of the resin material to induce radical re-polymerization of the polymerization agent. As a result, a damaged portion of the resin material can be repaired or the resin materials can be bonded to each other by way of the polymerization agent, which can suppress formation of the hetero-interface or improve the service life of the resin material.

Abstract: An adsorbent that enables solid phase extraction with high efficiency and good selectivity of solutes having a broad chromatographic polarity range including high-polarity solute molecules while suppressing adsorption of impurities, and a solid phase extraction method therefor are provided. A heterocyclic-ring-containing copolymer adsorbent that is provided herein comprises a copolymer that comprises: a multifunctional heterocyclic-ring-containing monomer having a heterocyclic ring containing at least two heteroatoms in the ring system; and a monomer that is copolymerizable with the multifunctional heterocyclic-ring-containing monomer, wherein the multifunctional heterocyclic ring constitutes the main chain structure.

Abstract: An object of the present invention is to provide a low dielectric loss resin composition with a narrow molecular weight distribution, the resin composition suffering as low a dielectric loss as that of commercially available polyphenylenether, being soluble in a general-purpose solvent with a low boiling point, and being easily processed into a wiring board. The present invention provides a thermosetting low dielectric loss resin which is a random copolymer of polyphenylenether having an unsaturated bond in a side chain and which has a molecular weight distribution of less than 10, more preferably at most 5, particularly preferably at most 3, as well as the hardened resin, a resin composition and an electronic part containing the resin, and a synthesizing method for obtaining the resin.