Patents by Inventor Junichiro Washiyama
Junichiro Washiyama has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9605116Abstract: A method for secondary-molding a polymer nano oriented crystal material in accordance with an embodiment of the present invention includes the steps of: heating the polymer nano oriented crystal material so that the polymer nano oriented crystal material changes into a mobile phase or a melt having a dense entanglement network structure; molding the polymer nano oriented crystal material which changed into the mobile phase or the melt including the dense entanglement network in the step; and cooling the polymer nano oriented crystal material, which has undergone the step, until the polymer nano oriented crystal material changes into an ordered phase.Type: GrantFiled: October 7, 2011Date of Patent: March 28, 2017Assignees: SUNALLOMER LTD., HIROSHIMA UNIVERSITYInventors: Masamichi Hikosaka, Kiyoka Okada, Junichiro Washiyama, Takeshi Nakajima, Yuka Akiyama, Shingo Ueno
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Patent number: 9138933Abstract: A process and apparatus for manufacturing a crystalline resin film or sheet. This manufacturing apparatus includes: an extruder that melts crystalline resin while supplying it; a gear pump that is provided on the downstream side of the extruder; a die which is provided on the downstream side of the gear pump, and which has a slit-shaped aperture; a cooling apparatus which cools film-shaped or sheet-shaped crystalline resin (A) discharged in a melted state from the die to a temperature which is not less than the crystallization temperature but not more than the melting point; and a pair of pinch rolls that press-roll between them the film-shaped or sheet-shaped crystalline resin (B) which has passed through the cooling apparatus (40), wherein the pair of guide rolls are positioned such that the thickness of the film-shaped or sheet-shaped crystalline resin (B) which has passed through the cooling apparatus is between 1.3 and 8.0 times the thickness of the film or sheet (C, D) after it has been press-rolled.Type: GrantFiled: January 22, 2010Date of Patent: September 22, 2015Assignee: SunAllomer Ltd.Inventors: Junichiro Washiyama, Hideharu Kimura, Koji Yamada, Takeshi Nakajima, Akihiro Otsubo, Masamichi Hikosaka, Kiyoka Okada, Kaori Watanabe
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Patent number: 8728616Abstract: A polymer sheet according to at least one embodiment of the present invention is a polymer sheet whose main component is oriented nanocrystals of a polymer, and which satisfies the following conditions (I), (II), and (III): (I) having a crystallinity of not less than 70%; (II) having a tensile strength at break of not less than 100 MPa and a tensile modulus of not less than 3 GPa; and (III) having an average thickness of not less than 0.15 mm. According to at least one embodiment of the present invention, it is possible to provide a polymer sheet excelling in properties such as mechanical strength, heat tolerance, and transparency, particularly a polymer sheet having excellent properties such as mechanical strength, heat tolerance, and transparency in general-purpose plastics such as polypropylene.Type: GrantFiled: January 21, 2010Date of Patent: May 20, 2014Assignees: Hiroshima University, Sunallomer Ltd.Inventors: Masamichi Hikosaka, Kiyoka Okada, Kaori Watanabe, Junichiro Washiyama, Hideharu Kimura, Koji Yamada, Takeshi Nakajima, Akihiro Otsubo
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Publication number: 20130196168Abstract: A method for secondary-molding a polymer nano oriented crystal material in accordance with an embodiment of the present invention includes the steps of: heating the polymer nano oriented crystal material so that the polymer nano oriented crystal material changes into a mobile phase or a melt having a dense entanglement network structure; molding the polymer nano oriented crystal material which changed into the mobile phase or the melt including the dense entanglement network in the step; and cooling the polymer nano oriented crystal material, which has undergone the step, until the polymer nano oriented crystal material changes into an ordered phase.Type: ApplicationFiled: October 7, 2011Publication date: August 1, 2013Applicants: SUNALLOMER LTD., HIROSHIMA UNIVERSITYInventors: Masamichi Hikosaka, Kiyoka Okada, Junichiro Washiyama, Takeshi Nakajima, Yuka Akiyama, Shingo Ueno
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Publication number: 20120018917Abstract: A process and apparatus for manufacturing a crystalline resin film or sheet. This manufacturing apparatus includes: an extruder that melts crystalline resin while supplying it; a gear pump that is provided on the downstream side of the extruder; a die which is provided on the downstream side of the gear pump, and which has a slit-shaped aperture; a cooling apparatus which cools film-shaped or sheet-shaped crystalline resin (A) discharged in a melted state from the die to a temperature which is not less than the crystallization temperature but not more than the melting point; and a pair of pinch rolls that press-roll between them the film-shaped or sheet-shaped crystalline resin (B) which has passed through the cooling apparatus (40), wherein the pair of guide rolls are positioned such that the thickness of the film-shaped or sheet-shaped crystalline resin (B) which has passed through the cooling apparatus is between 1.3 and 8.0 times the thickness of the film or sheet (C, D) after it has been press-rolled.Type: ApplicationFiled: January 22, 2010Publication date: January 26, 2012Applicant: SunAllomer Ltd.Inventors: Junichiro Washiyama, Hideharu Kimura, Koji Yamada, Takeshi Nakajima, Akihiro Otsubo, Masamichi Hikosaka, Kiyoka Okada, Kaori Watanabe
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Publication number: 20110300364Abstract: A polymer sheet according to at least one embodiment of the present invention is a polymer sheet whose main component is oriented nanocrystals of a polymer, and which satisfies the following conditions (I), (II), and (III): (I) having a crystallinity of not less than 70%; (II) having a tensile strength at break of not less than 100 MPa and a tensile modulus of not less than 3 GPa; and (III) having an average thickness of not less than 0.15 mm. According to at least one embodiment of the present invention, it is possible to provide a polymer sheet excelling in properties such as mechanical strength, heat tolerance, and transparency, particularly a polymer sheet having excellent properties such as mechanical strength, heat tolerance, and transparency in general-purpose plastics such as polypropylene.Type: ApplicationFiled: January 21, 2010Publication date: December 8, 2011Applicants: SUNALLOMER LTD., HIROSHIMA UNIVERSITYInventors: Masamichi Hikosaka, Kiyoka Okada, Kaori Watanabe, Junichiro Washiyama, Hideharu Kimura, Koji Yamada, Takeshi Nakajima, Akihiro Otsubo
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Patent number: 7288598Abstract: A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.Type: GrantFiled: March 6, 2003Date of Patent: October 30, 2007Assignee: Basell Poliolefine Italia S.p.A.Inventors: Anteo Pelliconi, Enea Garagnani, Yutaka Yokoyama, Junichiro Washiyama, Hiroshi Takenouchi, Takeshi Nakajima
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Publication number: 20050113521Abstract: A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.Type: ApplicationFiled: March 6, 2003Publication date: May 26, 2005Applicant: Basell Poliolefine Italia S.p. A.Inventors: Anteo Pelliconi, Enea Garagnani, Yutaka Yokoyama, Junichiro Washiyama, Hiroshi Takenouchi, Takeshi Nakajima
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Patent number: 6586531Abstract: A masterbatch composition, a polyolefin composition prepared from the masterbatch and articles prepared from the polyolefin composition. The masterbatch contains (percent by weight) from 20% to 90% of A) a crystalline polypropylene containing from 25% to 75% of a fraction AI having a melt flow rate MFRI of from 0.5 to 10 g/10 min., and from 75% to 25% of a fraction AII having a melt flow rate MFRII such that MFRII/MFRI is from 30 to 2000; and from 10% to 80% of B) a copolymer of ethylene and at least one C3-C10 &agr;-olefin, the copolymer containing from 10 to 70% of ethylene, the copolymer being soluble in xylene at room temperature, and having an intrinsic viscosity [&eegr;] of from 4 to 9 dl/g. Articles prepared from the polyolefin composition exhibit a good balance of physical properties and reduced surface defects such as tiger striping.Type: GrantFiled: September 27, 2001Date of Patent: July 1, 2003Assignee: Basell Poliolefine Italia S.p.A.Inventors: Junichiro Washiyama, Kazuhiko Minowa, Hiroshi Takenouchi, Takeshi Nakajima, Masamitsu Yamauchi, Yutaka Yokoyama, Anteo Pelliconi
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Publication number: 20030040583Abstract: A masterbatch composition, a polyolefin composition prepared from the masterbatch and articles prepared from the polyolefin composition. The masterbatch contains (percent by weight) from 20% to 90% of A) a crystalline polypropylene containing from 25% to 75% of a fraction AI having a melt flow rate MFRI of from 0.5 to 10 g/10 min., and from 75% to 25% of a fraction AII having a melt flow rate MFRII such that MFRII/MFRI is from 30 to 2000; and from 10% to 80% of B) a copolymer of ethylene and at least one C3-C10 &agr;-olefin, the copolymer containing from 10 to 70% of ethylene, the copolymer being soluble in xylene at room temperature, and having an intrinsic viscosity [&eegr;] of from 4 to 9 dl/g. Articles prepared from the polyolefin composition exhibit a good balance of physical properties and reduced surface defects such as tiger striping.Type: ApplicationFiled: September 27, 2001Publication date: February 27, 2003Inventors: Junichiro Washiyama, Kazuhiko Minowa, Hiroshi Takenouchi, Takeshi Nakajima, Masamitsu Yamauchi, Yutaka Yokoyama, Anteo Pelliconi
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Patent number: 4994515Abstract: A resin composition comprising (A) at least one heat-resistant resin, (B) at least one thermoplastic resin, (C) an antimony oxide, (D) at least one bromine-containing reaction product selected from the group consisting of (1) a compound having a molecular weight of from 1,200 to 6,000 and a bromine content of from 5.0 to 60% by weight which is obtained by reacting a bromine-containing epoxy compound and 1,3,5-tribromophenol, and (2) a compound obtained by reacting a bromine-containing epoxy compound having an epoxy equivalent of from 450 to 7,000 and a bromine content of from 5.0 to 52% by weight and an acrylonitrile-butadiene copolymer having a carboxyl group at the both terminals thereof and a molecular weight of from 1,000 to 10,000, and (E) at least one silicon-containing compound selected from the group consisting of (1) silicone oil, (2) a ladder silicone resin, and (3) an alkoxysilane having a mercapto group, a vinyl group or a methacryloyl group, is disclosed.Type: GrantFiled: June 27, 1989Date of Patent: February 19, 1991Assignee: Showa Denko Kabushiki KaishaInventors: Junichiro Washiyama, Chikara Aoyama, Tetsuo Yasuda
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Patent number: 4990386Abstract: An optical disk substrate is disclosed, which is molded from a terpolymer composed of (A) an aromatic vinyl monomer, (B) cyclohexylmaleimide, and (C) at least one compound selected from the group consisting of (meth)acrylonitrile, isobornyl (meth)acrylate and cyclohexyl (meth)acrylate, with the cyclohexyl maleimide being copolymerized in an amount of from 5 to 60 wt % of said terpolymer. The optical disk substrate exhibits high heat resistance, low water absorption and low birefringence.Type: GrantFiled: April 7, 1989Date of Patent: February 5, 1991Assignee: Showa Denko Kabushiki KaishiInventors: Junichiro Washiyama, Motoyuki Hirata, Tetsuo Yasuda, Shigenobu Ishihara