Patents by Inventor Junko Kurazumi
Junko Kurazumi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8557915Abstract: A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.Type: GrantFiled: February 13, 2012Date of Patent: October 15, 2013Assignees: JSR Corporation, Bridgestone CorporationInventors: Takahiro Nakamura, Kouichirou Tani, Ryouji Tanaka, Takuo Sone, Toshihiro Tadaki, Junko Kurazumi, Koji Masaki, Yoichi Ozawa
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Patent number: 8299184Abstract: A rubber composition for tire sidewall which comprises a rubber component, which comprises polybutadiene rubber having a content of the cis-1,4-bond of 92% or greater and a content of the vinyl bond of 1.5% or smaller and natural rubber and/or at least one other diene-based synthetic rubber, and 10 to 70 parts by mass of carbon black having a specific surface area by nitrogen adsorption of 20 to 100 m2/g per 100 parts by mass of the rubber component and does not comprise a softener having an aniline point of 50° C. or lower and a tire using the rubber composition for sidewall. Excellent resistance to cut growth is obtained while sufficient workability is surely exhibited.Type: GrantFiled: February 14, 2007Date of Patent: October 30, 2012Assignee: Bridgestone CorporationInventors: Junko Kurazumi, Kouji Masaki
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Publication number: 20120142851Abstract: A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.Type: ApplicationFiled: February 13, 2012Publication date: June 7, 2012Applicants: BRIDGESTONE CORPORATION, JSR CORPORATIONInventors: Takahiro NAKAMURA, Kouichirou Tani, Ryouji Tanaka, Takuo Sone, Toshihiro Tadaki, Junko Kurazumi, Koji Masaki, Yoichi Ozawa
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Patent number: 8153723Abstract: A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.Type: GrantFiled: December 5, 2006Date of Patent: April 10, 2012Assignees: JSR Corporation, Bridgestone CorporationInventors: Takahiro Nakamura, Kouichirou Tani, Ryouji Tanaka, Takuo Sone, Toshihiro Tadaki, Junko Kurazumi, Koji Masaki, Yoichi Ozawa
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Patent number: 8017695Abstract: This invention relates to a method for producing functionalized cis-1,4-polydienes having a combination of a high cis-1,4-linkage content and a high functionality, the resulting polymers and the vulcanized products containing the polymers. The functionalized cis-1,4-polydienes of the present invention are produced by a method comprising the steps of: (1) preparing a reactive polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst is the combination of or reaction product of (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a halogen-containing compound; and (2) contacting the reactive polymer with a functionalizing agent.Type: GrantFiled: December 27, 2007Date of Patent: September 13, 2011Inventors: Steven Luo, Junko Kurazumi, Yoichi Ozawa, Timothy L. Tartamella, Mark Smale, Kevin McCauley
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Patent number: 7968652Abstract: The present invention provides a modified conjugated diene polymer that is prepared by polymerization of a conjugated diene compound using a catalyst containing a lanthanoid rare earth element compound in an organic solvent and then modifying the resulting polymer having an active organic metal site with a modifier, wherein the modification efficiency is not less than 15% and the cis-1,4 bond content in the conjugated diene moiety measured by Fourier transform infrared spectroscopy satisfies the relationship (I): cis-1,4 bond content?98.00(%)??(I), or the modification efficiency is not less than 75% and the cis-1,4 bond content in the conjugated diene moiety measured by Fourier transform infrared spectroscopy satisfies the relationship (II): 94.00(%)?cis-1,4 bond content<98.00(%)??(II).Type: GrantFiled: April 17, 2006Date of Patent: June 28, 2011Assignee: Bridgestone CorporationInventors: Junko Kurazumi, Eiju Suzuki, Yoichi Ozawa
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Patent number: 7893153Abstract: A process for producing a modified conjugated diene polymer includes subjecting an active terminal of a conjugated diene polymer having a vinyl content of less than 10% and a cis-1,4 bond content of 75% or more to a modification reaction with an alkoxysilane compound, and subjecting the alkoxysilane compound (residue) to a condensation reaction in an aqueous solution at a pH of 9 to 14 and a temperature of 85 to 180° C. in the presence of a condensation accelerator including a compound containing titanium. The modified conjugated diene polymer exhibits low heat build-up and increased reinforcing properties when used for a rubber composition, and exhibits excellent wear resistance, mechanical characteristics, and processability.Type: GrantFiled: October 4, 2006Date of Patent: February 22, 2011Assignees: JSR Corporation, Bridgestone CorporationInventors: Ryouji Tanaka, Kouichirou Tani, Takuo Sone, Toshihiro Tadaki, Junko Kurazumi, Koji Masaki, Yoichi Ozawa
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Publication number: 20100222502Abstract: A process for producing a modified conjugated diene polymer includes subjecting an active terminal of a conjugated diene polymer having a vinyl content of less than 10% and a cis-1,4 bond content of 75% or more to a modification reaction with an alkoxysilane compound, and subjecting the alkoxysilane compound (residue) to a condensation reaction in an aqueous solution at a pH of 9 to 14 and a temperature of 85 to 180° C. in the presence of a condensation accelerator including a compound containing titanium. The modified conjugated diene polymer exhibits low heat build-up and increased reinforcing properties when used for a rubber composition, and exhibits excellent wear resistance, mechanical characteristics, and processability.Type: ApplicationFiled: October 4, 2006Publication date: September 2, 2010Applicants: JSR CORPORATION, BRIDGESTONE CORPORATIONInventors: Ryouji Tanaka, Kouichirou Tani, Takuo Sone, Toshihiro Tadaki, Junko Kurazumi, Koji Masaki, Yoichi Ozawa
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Publication number: 20100160530Abstract: A rubber composition comprises 10 to 70 parts by mass of carbon black having 20 to 100 m2/g of the specific surface area by nitrogen adsorption per 100 parts by mass of a rubber component comprising 20 to 80 parts by mass of a modified polybutadiene rubber and 80 to 20 parts by mass of natural rubber and/or at least one other diene-based synthetic rubber, wherein the modified polybutadiene is obtained by polymerizing 1,3-butadiene in an organic solvent using a compound having a rare earth element of the lanthanoid series, followed by modifying the obtained polybutadiene, and has a content of the cis-1,4-bond of 92% or greater, a content of vinyl bond of 1.5% or smaller and a fraction of the modified chain end of 20% or greater; and a tire using the rubber composition for a sidewall. The rubber composition exhibits excellent low heat buildup property and resistance to fracture.Type: ApplicationFiled: January 19, 2007Publication date: June 24, 2010Applicant: BRIDGESTRONE CORPORATIONInventors: Junko Kurazumi, Kouji Masaki
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Patent number: 7691957Abstract: This invention is concerned with a butadiene-based polymer having a high cis-1,4 bond content, a low vinyl bond content and a molecular weight distribution of a specified range, and more particularly a butadiene-based polymer having a 1,3-butadiene monomer unit, characterized in that a cis-1,4 bond content and a vinyl bond content in the 1,3-butadiene monomer unit as measured by a Fourier transform infrared spectroscopy (FT-IR) is not less than 98.0% and not more than 0.3%, respectively, and a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) is 1.6-3.5.Type: GrantFiled: June 23, 2004Date of Patent: April 6, 2010Assignee: Bridgestone CorporationInventors: Eiju Suzuki, Yoichi Ozawa, Tetsuya Ohmura, Junko Kurazumi
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Publication number: 20090292043Abstract: The present invention provides a modified conjugated diene polymer that is prepared by polymerization of a conjugated diene compound using a catalyst containing a lanthanoid rare earth element compound in an organic solvent and then modifying the resulting polymer having an active organic metal site with a modifier, wherein the modification efficiency is not less than 15% and the cis-1,4 bond content in the conjugated diene moiety measured by Fourier transform infrared spectroscopy satisfies the relationship (I): cis-1,4 bond content?98.00(%)??(I), or the modification efficiency is not less than 75% and the cis-1,4 bond content in the conjugated diene moiety measured by Fourier transform infrared spectroscopy satisfies the relationship (II): 94.00(%)?cis-1,4 bond content<98.00(%)??(II).Type: ApplicationFiled: April 17, 2006Publication date: November 26, 2009Applicant: Bridgestone CorporationInventors: Junko Kurazumi, Eiju Suzuki, Yoichi Ozawa
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Publication number: 20090247695Abstract: A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.Type: ApplicationFiled: December 5, 2006Publication date: October 1, 2009Applicants: JSR Corporation, Bridgestone CorporationInventors: Takahiro Nakamura, Kouichirou Tani, Ryouji Tanaka, Takuo Sone, Toshihiro Tadaki, Junko Kurazumi, Koji Masaki, Yoichi Ozawa
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Publication number: 20090203828Abstract: A rubber composition for tire sidewall which comprises a rubber component, which comprises polybutadiene rubber having a content of the cis-1,4-bond of 92% or greater and a content of the vinyl bond of 1.5% or smaller and natural rubber and/or at least one other diene-based synthetic rubber, and 10 to 70 parts by mass of carbon black having a specific surface area by nitrogen adsorption of 20 to 100 m2/g per 100 parts by mass of the rubber component and does not comprise a softener having an aniline point of 50° C. or lower and a tire using the rubber composition for sidewall. Excellent resistance to cut growth is obtained while sufficient workability is surely exhibited.Type: ApplicationFiled: February 14, 2007Publication date: August 13, 2009Applicant: Bridgestone CorporationInventors: Junko Kurazumi, Kouji Masaki
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Publication number: 20080182954Abstract: This invention relates to a method for producing functionalized cis-1,4-polydienes having a combination of a high cis-1,4-linkage content and a high functionality, the resulting polymers and the vulcanized products containing the polymers. The functionalized cis-1,4-polydienes of the present invention are produced by a method comprising the steps of: (1) preparing a reactive polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst in the presence of less than 20% by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst is the combination of or reaction product of (a) a lanthanide compound, (b) an aluminoxane, (c) an organoaluminum compound other than an aluminoxane, and (d) a halogen-containing compound; and (2) contacting the reactive polymer with a functionalizing agent.Type: ApplicationFiled: December 27, 2007Publication date: July 31, 2008Inventors: Steven Luo, Junko Kurazumi, Yoichi Ozawa, Timothy L. Tartamella, Mark Smale
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Publication number: 20070055029Abstract: This invention is concerned with a butadiene-based polymer having a high cis-1,4 bond content, a low vinyl bond content and a molecular weight distribution of a specified range, and more particularly a butadiene-based polymer having a 1,3-butadiene monomer unit, characterized in that a cis-1,4 bond content and a vinyl bond content in the 1,3-butadiene monomer unit as measured by a Fourier transform infrared spectroscopy (FT-IR) is not less than 98.0% and not more than 0.3%, respectively, and a ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) is 1.6-3.5.Type: ApplicationFiled: June 23, 2004Publication date: March 8, 2007Inventors: Eiju Suzuki, Yoichi Ozawa, Tetsuya Ohmura, Junko Kurazumi