Patents by Inventor Junling Zhou

Junling Zhou has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20200325315
    Abstract: The invention provides an olefin-olefinic alcohol copolymer and a preparation method thereof, said copolymer comprising a spherical and/or spherical-like polymer. The copolymer provided by the invention exhibits a good morphology and has good prospects in industrial use.
    Type: Application
    Filed: October 24, 2018
    Publication date: October 15, 2020
    Inventors: Rong GAO, Zifang GUO, Junling ZHOU, Dongbing LIU, Jie FU, Jingjing LAI, Tingjie HUANG, Shiyuan XU, Xinyang LI
  • Publication number: 20200325262
    Abstract: The present invention provides a copolymer of an olefin and an unsaturated carboxylic acid or an unsaturated carboxylic acid derivative, said copolymer being a spherical and/or spherical-like polymer. The copolymer provided by the invention exhibits a good morphology and has good prospects in industrial use.
    Type: Application
    Filed: October 24, 2018
    Publication date: October 15, 2020
    Inventors: Rong GAO, Zifang GUO, Junling ZHOU, Dongbing LIU, Jie FU, Jingjing LAI, Tingjie HUANG, Shiyuan XU, Xinyang LI
  • Publication number: 20200181296
    Abstract: The present invention discloses a Ziegler-Natta catalyst system for olefin polymerization, comprising at least one compound represented by formula (I) as (i) an internal electron donor, (ii) an external electron donor, or (iii) the both, wherein M1, M2, M3, M4, M5, M6, M1?, M2?, M3?, M4?, M5? and M6? are each independently selected from the group consisting of hydrogen, hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, —R1 and —OR2, wherein R1 and R2 are each independently a C1-C10 hydrocarbyl, which is unsubstituted or substituted by a substituent selected from the group consisting of hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, C1-C10 alkoxy and heteroatoms; and wherein, when among M1-M6 and M1?-M6?, any two adjacent groups on the same phenyl ring are each independently selected from the group consisting of R1 and —OR2, the two adjacent groups may optionally be linked to form a ring, with a proviso that M1, M2, M3, M4, M5, M6, M1?, M2?, M3?, M4?, M5? and M6? are not simultaneous
    Type: Application
    Filed: July 19, 2018
    Publication date: June 11, 2020
    Inventors: Ting HUANG, Zifang GUO, Zhufang SUN, Junling ZHOU, Lunjia XIE, Hongxu YANG, Bingyi LI, Qingqiang GOU, Tingjie HUANG, Peng KOU, Xiaofan ZHANG, Meiyan FU, Jie LIN, Yonghua MA
  • Patent number: 10174141
    Abstract: The present invention provides a preparation method of a catalyst component for olefin polymerization, comprising firstly dissolving an anhydrous magnesium halide into a mixed solvent which comprises an oxygen-containing organic titanium compound, an organic epoxy compound, a hydroxy-containing compound, and an inert solvent, and does not comprise a phosphate compound, so as to form a magnesium halide solution; then mixing the magnesium halide solution with a halogen-containing compound to precipitate a solid, so as to obtain the catalyst component, wherein the halogen-containing compound comprises at least one selected from a group consisting of halogen and titanium-containing compounds, halogenated organic hydrocarbon compounds, acyl halide compounds, halogen and phosphorus-containing compounds, halogen and boron-containing compounds, halogenated organic aluminum compounds, and halogen and silicon-containing compounds.
    Type: Grant
    Filed: April 29, 2015
    Date of Patent: January 8, 2019
    Assignee: China Petroleum & Chemical Corporation Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo Wang, Junling Zhou, Dongbing Liu, Lei Zhang, Xinping Lv, Bingquan Mao, Zhenjie Liu, Xin Zhou, Changli Zhang, Baoquan Xing
  • Patent number: 10087264
    Abstract: A magnesium halide solution is disclosed. The magnesium halide solution comprises a magnesium halide, an oxygen-containing organic titanium compound, a hydroxyl-containing compound, and an organic solvent. The magnesium halide solution further comprises an organic heterocyclic compound. The organic solvent is a hydrocarbon and/or a halogenated hydrocarbon. The organic heterocyclic compound is at least one selected from a group consisting of a sulphur-containing organic heterocyclic compound, a nitrogen-containing organic heterocyclic compound, and an organic epoxy compound. The magnesium halide solution has a good stability, and can be used for preparing a catalyst for olefin polymerization and copolymerization reactions. The raw material of the magnesium halide solution is cheap and easy to be obtained. The preparing method is easy to be performed and is environment-friendly.
    Type: Grant
    Filed: April 29, 2015
    Date of Patent: October 2, 2018
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo Wang, Junling Zhou, Dongbing Liu, Lei Zhang, Xinping Lv, Bingquan Mao, Zhenjie Liu, Xin Zhou, Changli Zhang, Baoquan Xing
  • Publication number: 20170058060
    Abstract: A magnesium halide solution is disclosed. The magnesium halide solution comprises a magnesium halide, an oxygen-containing organic titanium compound, a hydroxyl-containing compound, and an organic solvent. The magnesium halide solution further comprises an organic heterocyclic compound. The organic solvent is a hydrocarbon and/or a halogenated hydrocarbon. The organic heterocyclic compound is at least one selected from a group consisting of a sulphur-containing organic heterocyclic compound, a nitrogen-containing organic heterocyclic compound, and an organic epoxy compound. The magnesium halide solution has a good stability, and can be used for preparing a catalyst for olefin polymerization and copolymerization reactions. The raw material of the magnesium halide solution is cheap and easy to be obtained. The preparing method is easy to be performed and is environment-friendly.
    Type: Application
    Filed: April 29, 2015
    Publication date: March 2, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo WANG, Junling ZHOU, Dongbing LIU, Lei ZHANG, Xinping LV, Bingquan MAO, Zhenjie LIU, Xin ZHOU, Changli ZHANG, Baoquan XING
  • Publication number: 20170051086
    Abstract: The present invention provides a preparation method of a catalyst component for olefin polymerization, comprising firstly dissolving an anhydrous magnesium halide into a mixed solvent which comprises an oxygen-containing organic titanium compound, an organic epoxy compound, a hydroxy-containing compound, and an inert solvent, and does not comprise a phosphate compound, so as to form a magnesium halide solution; then mixing the magnesium halide solution with a halogen-containing compound to precipitate a solid, so as to obtain the catalyst component, wherein the halogen-containing compound comprises at least one selected from a group consisting of halogen and titanium-containing compounds, halogenated organic hydrocarbon compounds, acyl halide compounds, halogen and phosphorus-containing compounds, halogen and boron-containing compounds, halogenated organic aluminium compounds, and halogen and silicon-containing compounds.
    Type: Application
    Filed: April 29, 2015
    Publication date: February 23, 2017
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo WANG, Junling ZHOU, Dongbing LIU, Lei ZHANG, Xinping LV, Bingquan MAO, Zhenjie LIU, Xin ZHOU, Changli ZHANG, Baoquan Xing
  • Publication number: 20150239998
    Abstract: The present invention relates to a catalyst component for ethylene polymerization, which comprises a reaction product of a magnesium complex, at least one titanium compound, at least one alcohol compound, at least one silicon compound, and optionally an organic aluminum compound. The silicon compound is an organic silicon compound having a general formula R1xR2ySi(OR3)2, in which R1 and R2 are independently a hydrocarbyl or a halogen, R3 is a hydrocarbyl, 0?x?2, 0?y?2, 0?z?4, and x+y+z=4. The present invention further relates to a method for the preparation of the catalyst component and to a catalyst comprising the same. The catalysts according to the invention have virtues such as high catalytic activity, good hydrogen response, and narrow particle size distribution of polymer, and are especially suitable for a slurry process of ethylene polymerization and a combined process of ethylene polymerization, which requires a high activity of catalyst.
    Type: Application
    Filed: February 2, 2015
    Publication date: August 27, 2015
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry
    Inventors: Wei CHEN, Zifang Guo, Junling Zhou, Hongtao Wang, Hongxu Yang, Ruixia Li, Ruiping Wang
  • Patent number: 9068025
    Abstract: The present invention relates to a catalyst component for olefin polymerization, which comprises the reaction product of at least one organo-magnesium compound, at least one titanium-containing compound, at least one hydroxyl group-containing compound, at least one chlorine-containing organo-aluminum, boron, phosphorus or silicon compound, and at least one polybutadiene block copolymer. The catalyst component of the present invention has well-shaped particles, and a narrow particle size distribution; a polymerization reaction of olefins with the catalyst component produces well-shaped polymer particles with a high bulk density (BD) and an excellent comprehensive catalytic performance. The present invention also relates to a preparation method for said catalyst component and the application thereof, particularly in the homopolymerization and copolymerization of olefins such as ethylene, propylene, butene, hexene and octene.
    Type: Grant
    Filed: August 19, 2011
    Date of Patent: June 30, 2015
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Shibo Wang, Dongbing Liu, Junling Zhou, Xinping Lü, Lei Zhang, Bingquan Mao, Baoquan Xing, Xin Zhou, Changli Zhang
  • Publication number: 20130150540
    Abstract: The present invention relates to a catalyst component for olefin polymerization, which comprises the reaction product of at least one organo-magnesium compound, at least one titanium-containing compound, at least one hydroxyl group-containing compound, at least one chlorine-containing organo-aluminum, boron, phosphorus or silicon compound, and at least one polybutadiene block copolymer. The catalyst component of the present invention has well-shaped particles, and a narrow particle size distribution; a polymerization reaction of olefins with the catalyst component produces well-shaped polymer particles with a high bulk density (BD) and an excellent comprehensive catalytic performance. The present invention also relates to a preparation method for said catalyst component and the application thereof, particularly in the homopolymerization and copolymerization of olefins such as ethylene, propylene, butene, hexene and octene.
    Type: Application
    Filed: August 19, 2011
    Publication date: June 13, 2013
    Inventors: Shibo Wang, Dongbing Liu, Junling Zhou, Xinping Lü, Lei Zhang, Bingquan Mao, Baoquan Xing, Xin Zhou, Changli Zhang
  • Patent number: 8268945
    Abstract: A catalyst component for ethylene polymerization, comprising an organic silicon compound of the formula (I), below wherein R1 is chosen from C3-C20 aliphatic hydrocarbyl groups, and is substituted with at least one substituent chosen from halogens, C1-C6 acyloxy groups, epoxy, amino, C1-C6 alkylamino groups, di(C1-C6 alkyl)amino groups, C1-C6 alkoxy groups, and oxo group; R2, R3 and R4, which may be the same or different, are each chosen from C1-C10 aliphatic hydrocarbyl, C3-C10 alicyclic hydrocarbyl, C6-C10 aryl, C7-C10 aralkyl, and C7-C10 alkaryl groups. A process for preparing the catalyst component and an active catalyst comprising the catalyst component and useful in polymerization, such as ethylene polymerization.
    Type: Grant
    Filed: August 20, 2010
    Date of Patent: September 18, 2012
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Taoyi Zhang, Junling Zhou, Hongtao Wang, Zifang Guo, Qingqiang Gou, Hongxu Yang, Ruixia Li, Shiyuan Xu
  • Publication number: 20110046325
    Abstract: A catalyst component for ethylene polymerization, comprising an organic silicon compound of the formula (I), below wherein R1 is chosen from C3-C20 aliphatic hydrocarbyl groups, and is substituted with at least one substituent chosen from halogens, C1-C6 acyloxy groups, epoxy, amino, C1-C6 alkylamino groups, di(C1-C6 alkyl)amino groups, C1-C6 alkoxy groups, and oxo group; R2, R3 and R4, which may be the same or different, are each chosen from C1-C10 aliphatic hydrocarbyl, C3-C10 alicyclic hydrocarbyl, C6-C10 aryl, C7-C10 aralkyl, and C7-C10 alkaryl groups. A process for preparing the catalyst component and an active catalyst comprising the catalyst component and useful in polymerization, such as ethylene polymerization.
    Type: Application
    Filed: August 20, 2010
    Publication date: February 24, 2011
    Inventors: Taoyi ZHANG, Junling Zhou, Hongtao Wang, Zifang Guo, Qingqiang Gou, Hongxu Yang, Ruixia Li, Shiyuan Xu
  • Publication number: 20090318643
    Abstract: The present invention relates to a catalyst component for ethylene polymerization, which comprises a reaction product of a magnesium complex, at least one titanium compound, at least one alcohol compound, at least one silicon compound, and optionally an organic aluminum compound. The silicon compound is an organic silicon compound having a general formula R1xR2ySi(OR3)z, in which R1 and R2 are independently a hydrocarbyl or a halogen, R3 is a hydrocarbyl, 0?x?2, 0?y?2, 0?z?4, and x+y+z=4. The present invention further relates to a method for the preparation of the catalyst component and to a catalyst comprising the same. The catalysts according to the invention have virtues such as high catalytic activity, good hydrogen response, and narrow particle size distribution of polymer, and are especially suitable for a slurry process of ethylene polymerization and a combined process of ethylene polymerization, which requires a high activity of catalyst.
    Type: Application
    Filed: October 31, 2006
    Publication date: December 24, 2009
    Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry
    Inventors: Wei Chen, Zifang Guo, Junling Zhou, Hongtao Wang, Hongxu Yang, Ruixia Li, Ruiping Wang
  • Patent number: 7153804
    Abstract: The present invention provides a catalyst component for ethylene polymerization, a process for preparing the same, a catalyst comprising the same, and a process for polymerizing ethylene using the catalyst. The catalyst component comprises a reaction product, supported on an inorganic oxide support, of a magnesium complex, a titanium compound, an alcohol compound, and an organoaluminum compound, wherein said magnesium complex is formed by dissolving a magnesium halide in a solvent system comprising an organic epoxy compound and an organo phosphorus compound. The catalyst according to the invention is especially suitable for slurry phase polymerization of ethylene. The catalyst according to the present invention has high catalytic activity, and a good hydrogen response, with the resultant polymer having a more uniform particle size diameter and a narrow particle size distribution.
    Type: Grant
    Filed: April 12, 2005
    Date of Patent: December 26, 2006
    Assignees: China Petroleum & Chemical Corporation, Beijing Reasearch Institute of Chemical Industry
    Inventors: Wei Chen, Zifang Guo, Junling Zhou, Hongxu Yang, Ruixia Li, Ruiping Wang, Yuexiang Liu, Hongtao Wang, Jingmei Zhang, Xiaojing Cheng
  • Publication number: 20050227858
    Abstract: The present invention provides a catalyst component for ethylene polymerization, a process for preparing the same, a catalyst comprising the same, and a process for polymerizing ethylene using the catalyst. The catalyst component comprises a reaction product, supported on an inorganic oxide support, of a magnesium complex, a titanium compound, an alcohol compound, and an organoaluminum compound, wherein said magnesium complex is formed by dissolving a magnesium halide in a solvent system comprising an organic epoxy compound and an organo phosphorus compound. The catalyst according to the invention is especially suitable for slurry phase polymerization of ethylene. The catalyst according to the present invention has high catalytic activity, and a good hydrogen response, with the resultant polymer having a more uniform particle size diameter and a narrow particle size distribution.
    Type: Application
    Filed: April 12, 2005
    Publication date: October 13, 2005
    Inventors: Wei Chen, Zifang Guo, Junling Zhou, Hongxu Yang, Ruixia Li, Ruiping Wang, Yuexiang Liu, Hongtao Wang, Jingmei Zhang, Xiaojing Cheng
  • Patent number: D930646
    Type: Grant
    Filed: February 28, 2020
    Date of Patent: September 14, 2021
    Inventors: Qingsen Zhang, Junling Chen, Chengjian Zhou