Abstract: Provided is a surface-protective coating composition capable of forming a surface-protective coating film in which the occurrence of cracks is suppressed during the formation of the coating film, while using a polymer having marine biodegradability. Also provided are: a surface-protective coating film formed from the surface-protective coating composition; a substrate with a surface-protective coating film, which is coated with the surface-protective coating film, and a method of producing the same; and a surface protection method using the surface-protective coating film. The surface-protective coating composition according to the present invention contains a polycaprolactone-based polymer (A) and a zinc oxide (B), wherein the polycaprolactone-based polymer (A) has an acid value of 5 mgKOH/g or more and 200 mgKOH/g or less, and a structural unit derived from caprolactone in the polycaprolactone-based polymer (A) has a content of 50% by mass or more and 99.5% by mass or less.

Abstract: An antifouling coating composition contains a silyl ester polymer, at least one rosin compound selected from rosin and rosin derivatives, a poly(vinyl alcohol) resin, and water. A method for producing an antifouling substrate, includes subjecting a substrate to application of or impregnation with the antifouling coating composition to provide an applied body or an impregnated body, and drying the applied body or the impregnated body.

Abstract: Provided is a silyl polymer-based antifouling coating composition that is capable of forming a coating film in which cracking is inhibited from occurring for a long period from the early stage of immersion in seawater and fresh water and enables to maintain excellent coating film consumption for a long term. The antifouling coating composition includes: a copolymer (A) containing a structural unit (a-1) derived from styrene or the like, a structural unit (a-2) derived from glycidyl (meth)acrylate, and optionally a structural unit (a-3) derived from another ethylenically unsaturated monomer; a polymer (B) containing a structural unit (b-1) derived from a monomer represented by the following Formula (b1): wherein X is a hydrogen atom or a carboxyl group; R1 is a hydrogen atom or a methyl group; R2 to R6, which may be the same as or different from each other, are C1-C6 straight or branched chain alkyl; and n is an integer of 0 or 1 or more; and an antifoulant.

Abstract: Provided is a silyl polymer-based antifouling coating composition that is capable of forming a coating film in which cracking is inhibited from occurring for a long period from the early stage of immersion in seawater and fresh water and enables to maintain excellent coating film consumption for a long term. The antifouling coating composition includes: a copolymer (A) containing a structural unit (a-1) derived from styrene or the like, a structural unit (a-2) derived from glycidyl (meth)acrylate, and optionally a structural unit (a-3) derived from another ethylenically unsaturated monomer; a polymer (B) containing a structural unit (b-1) derived from a monomer represented by the following Formula (b1): wherein X is a hydrogen atom or a carboxyl group; R1 is a hydrogen atom or a methyl group; R2 to R6, which may be the same as or different from each other, are C1-C6 straight or branched chain alkyl; and n is an integer of 0 or 1 or more; and an antifoulant.

Abstract: The antifouling coating composition according to the present invention includes a silylacrylic copolymer including a structural unit (1) derived from triisopropylsilyl methacrylate (i), a structural unit (2) derived from triisopropylsilyl acrylate (ii) and a structural unit (3) derived from a polymerizable monomer having a polymerizable double bond (iii), which excludes the above (i) and (ii), the silylacrylic copolymer satisfies specific requirements. Thus, an antifouling coating composition that is excellent in long-term storage stability and gives a coating film excellent in long-term antifouling properties and long-term water resistance can be provided.

Abstract: The antifouling coating composition according to the present invention includes a silylacrylic copolymer including a structural unit (1) derived from triisopropylsilyl methacrylate (i), a structural unit (2) derived from triisopropylsilyl acrylate (ii) and a structural unit (3) derived from a polymerizable monomer having a polymerizable double bond (iii), which excludes the above (i) and (ii), the silylacrylic copolymer satisfies specific requirements. Thus, an antifouling coating composition that is excellent in long-term storage stability and gives a coating film excellent in long-term antifouling properties and long-term water resistance can be provided.