Patents by Inventor Junpei Kojima
Junpei Kojima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4820775Abstract: A process for the production of .alpha.-olefin block copolymer particles having excellent impact resistance at low temperature and excellent molding and processing characteristics, is disclosed. The process includes a two step gas phase polymerization procedure under specific conditions in the presence of a specific catalyst system.Type: GrantFiled: May 23, 1986Date of Patent: April 11, 1989Assignee: Sumitomo Chemical Company LimitedInventors: Akinobu Shiga, Masahiro Kakugo, Hajime Sadatoshi, Hiroyuki Kora, Toshio Sasaki, Junpei Kojima, Kazuki Wakamatsu, Syozo Kawamata
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Patent number: 4761392Abstract: A process for producing an olefin polymer which comprises the homopolymerizing or copolymerizing an olefin in the presence of a catalyst system composed of an organoaluminum compound and a hydrocarbyloxy group-containing solid catalyst component which is prepared byreducing a titanium compound represented by the general formula Ti(OR.sup.1).sub.n X.sub.4-n, wherein R.sup.1 is a C.sub.1 -C.sub.20 hydrocarbon radical, X is halogen, and n is a number defined as 0<n.ltoreq.4, with an organoaluminum compound represented by the general formula AlR.sup.2.sub.m Y.sub.3-m, wherein R.sup.2 is a C.sub.1 -C.sub.20 hydrocarbon radical, Y is halogen, and m is a number defined as 1.ltoreq.m.ltoreq.3,subjecting the reduction product, which is a hydrocarbyloxy group-containing solid insoluble in hydrocarbon solvents, to a preliminary ethylene polymerization treatment, andtreating the resultant solid in a state of slurry in a hydrocarbon solvent with an ether compound and titanium tetrachloride at a temperature of 30.Type: GrantFiled: November 12, 1986Date of Patent: August 2, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Toshio Sasaki, Junpei Kojima
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Patent number: 4645808Abstract: A process for producing an olefin polymer which comprises the homopolymerizing or copolymerizing an olefin in the presence of a catalyst system composed of an organoaluminum compound and a hydrocarbyloxy group-containing solid catalyst component which is prepared byreducing a titanium compound represented by the general formula Ti(OR.sup.1).sub.n X.sub.4-n, wherein R.sup.1 is a C.sub.1 -C.sub.20 hydrocarbon radical, X is halogen, and n is a number defined as 0<n.ltoreq.4, with an organoaluminum compound represented by the general formula AlR.sup.2.sub.m Y.sub.3-m, wherein R.sup.2 is a C.sub.1 -C.sub.20 hydrocarbon radical, Y is halogen, and m is a number defined as 1.ltoreq.m.ltoreq.3,subjecting the reduction product, which is a hydrocarbyloxy group-containing solid insoluble in hydrocarbon solvents, to a prelimary ethylene polymerization treatment, andtreating the resultant solid in a state of slurry in a hydrocarbon solvent with an ether compound and titanium tetrachloride at a temperature of 30.degree.Type: GrantFiled: April 22, 1985Date of Patent: February 24, 1987Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Toshio Sasaki, Junpei Kojima
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Patent number: 4554264Abstract: A process for producing an .alpha.-olefin polymer which comprises polymerizing an .alpha.-olefin in the presence of a catalyst system comprising(A) a solid catalyst component obtained by steps of(i) reducing titanium tetrachloride with an organoaluminum compound represented by the general formula R.sup.1.sub.n AlY.sub.3-n, wherein R.sup.1 represents a C.sub.1 -C.sub.18 hydrocarbon group, Y represents a halogen, and n represents a number satisfying 1<n<3,(ii) heating the reduction product at a temperature of up to 150.degree. C.,(iii) treating the thus obtained solid product containing .gamma.-titanium trichloride by preliminary polymerization of an .alpha.-olefin in the presence thereof, and(iv) reacting the resulting solid product with a halogen represented by the general formula X.sub.Type: GrantFiled: July 16, 1984Date of Patent: November 19, 1985Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Toshio Sasaki, Junpei Kojima, Akira Nunose
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Patent number: 4551501Abstract: A crystalline propylene polymer composition having excellent transparency and rigidity comprising a blend of a crystalline polypropylene with a polymer of a vinyl cycloalkane having at least 6 carbon atoms. The composition contains 0.05 weight ppm to 10,000 weight ppm of the vinyl cycloalkane unit.Type: GrantFiled: December 27, 1984Date of Patent: November 5, 1985Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Masahiro Kakugo, Junpei Kojima, Kizuku Wakatsuki
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Patent number: 4533706Abstract: A catalyst system for the polymerization of olefins which comprises;(A) a hydrocarbyloxy group-containing solid catalyst component prepared by (i) reducing a titanium compound represented by the general formula Ti(OR.sup.1).sub.n X.sub.4-n wherein, R.sup.1 represents a hydrocarbon radical of 1-20 carbon atoms, X represents a halogen atom, and n represents a number satisfying 0<n.ltoreq.4, with an organoaluminum compound represented by the general formula AlR.sup.2.sub.m Y.sub.3-m wherein, R.sup.2 represents a hydrocarbon radical of 1-20 carbon atoms, Y represents a halogen atom, and m represents a number satisfying 1.ltoreq.m.ltoreq.3, and (ii) treating the resulting, hydrocarbon solvent-insoluble, hydrocarbyloxy group-containing solid product in a slurry state with an ether compound and titanium tetrachloride at a temperature of 30.degree.-120.degree. C., and(B) an organoaluminum compound.Type: GrantFiled: December 13, 1983Date of Patent: August 6, 1985Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Toshio Sasaki, Junpei Kojima
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Patent number: 4514512Abstract: A method for the production of a solid titanium trichloride catalyst by the steps of preparing a titanium trichloride composition comprising a solid reduction product obtained by reducing titanium tetrachloride with an organoaluminum compound represented by the formula, R.sup.1.sub.n AlY.sub.3-n (wherein R.sup.1 is a hydrocarbon group having 1 to 18 carbon atoms; Y is a halogen atom or a hydrogen atom; and n is a number satisfying the equation, 1<n.ltoreq.3), or a solid product obtained by thermally treating said solid reduction product at a temperature of not more than 150.degree. C.; reacting said titanium trichloride composition in an aromatic hydrocarbon solvent with a mixture consisting of a halogen compound represented by the formula, X.sub.2 (wherein X is Cl, Br, or I), or an interhalogen compound represented by the formula, XX'.sub.a (wherein X and X' are each Cl, Br, or I, and a is 1 or 3), and an ether compound represented by the formula, R.sup.2 --O--R.sup.3 (wherein R.sup.2 and R.sup.Type: GrantFiled: March 31, 1983Date of Patent: April 30, 1985Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Yukio Naito, Toshio Sasaki, Junpei Kojima, Hiroshi Yoshioka, Akira Nunose
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Patent number: 4504637Abstract: A catalyst system for the polymerization of olefins comprising:(A) a solid catalyst component containing hydrocarbyloxy groups obtained by reacting a titanium compound represented by the general formula Ti(OR.sup.1).sub.n X.sub.3-n (wherein R.sup.1 is a hydrocarbon group having 1 to 20 carbon atoms, X is a halogen atom, and n is a number defined by 0<n.ltoreq.3) with an ether compound and titanium tetrachloride in a slurry state in the presence of a magnesium halide, and(B) an organoaluminum compound.Type: GrantFiled: December 13, 1983Date of Patent: March 12, 1985Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Toshio Sasaki, Junpei Kojima
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Patent number: 4412049Abstract: A process for producing highly stereoregular .alpha.-olefin polymers which comprises polymerizing .alpha.-olefins in the presence of a catalyst system comprising:(A) a solid catalyst obtained by contact reaction between(a) a solid product prepared by reacting an organo-magnesium compound with at least one of halogenated silicon compound (I) and halogenated aluminum compound (II) in a solvent and(b) a titanium compound having both titanium-aryloxy and titanium-halogen linkages, and(B) an organo-aluminum compound as an activating agent.Type: GrantFiled: January 10, 1983Date of Patent: October 25, 1983Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Yukio Naito, Toshio Sasaki, Junpei Kojima, Hiroshi Yoshioka