Abstract: A solid glutaraldehyde composition is provided having an increased glass transition temperature. The glutaraldehyde can be used in a method of treating a wellbore or a subterranean formation, by introducing the composition to a wellbore or to an injection line within a wellbore in an amount effective to reduce biodegradation of crude oil, reduce corrosion of metal surfaces from sulfur-reducing bacteria, or to reduce the introduction of bacteria into the formation, reduce microbial contamination of a fluid introduced into the wellbore, or reduce microbial contamination of a pipeline.

Abstract: A method of detecting concentration of dipicolinic acid and terbium chloride in a chemical composition with a fluorometer, wherein the fluorometer comprises an excitation source for emitting electromagnetic radiation at one or more wavelengths, and a detector module for detecting fluorescence emitted by dipicolinic acid, emitting electromagnetic radiation from the excitation source at wavelengths that induce fluorescence in dipicolinic acid-terbium chloride combination present in the chemical composition, detecting the fluorescence emitted by the dipicolinic acid-terbium chloride combination via the detector module, and determining the concentration of dipicolinic acid using predetermined relationship between fluorescence emitted and the concentration of dipicolinic acid-terbium chloride combination.

Abstract: A method of fluorometrically detecting the concentration of chemical components in oxidizing formulations is disclosed. In a particular embodiment the detection is of the stabilizing component of picolinic acid, present in such formulations, although any component which fluoresces may be detected. According to the invention sample preparation of the oxidizing formulation includes adding to said sample an excess of reducing agent to bind peracid, and in the case of picolinic acid, adding to said sample an excess of terbium chloride. The sample then is subjected to radiation to induce fluorescence and the concentration of said chemical component is determined by a linear relationship between fluorescence emitted and the concentration of the target chemical.

Abstract: A solid glutaraldehyde composition is provided having an increased glass transition temperature. The glutaraldehyde can be used in a method of treating a wellbore or a subterranean formation, by introducing the composition to a wellbore or to an injection line within a wellbore in an amount effective to reduce biodegradation of crude oil, reduce corrosion of metal surfaces from sulfur-reducing bacteria, or to reduce the introduction of bacteria into the formation, reduce microbial contamination of a fluid introduced into the wellbore, or reduce microbial contamination of a pipeline.

Abstract: A solid glutaraldehyde composition is provided which incorporates a quaternary ammonium compound. The glutaraldehyde can be used in a method of treating a wellbore or a subterranean formation, by introducing the composition to a wellbore or to an injection line within a wellbore in an amount effective to reduce biodegradation of crude oil, reduce corrosion of metal surfaces from sulfur-reducing bacteria, or to reduce the introduction of bacteria into the formation, reduce microbial contamination of a fluid introduced into the wellbore, or reduce microbial contamination of a pipeline.

Abstract: A method of fluorometrically detecting the concentration of chemical components in oxidizing formulations is disclosed. In a particular embodiment the detection is of the stabilizing component of picolinic acid, present in such formulations, although any component which fluoresces may be detected. According to the invention sample preparation of the oxidizing formulation includes adding to said sample an excess of reducing agent to bind peracid, and in the case of picolinic acid, adding to said sample an excess of terbium chloride. The sample then is subjected to radiation to induce fluorescence and the concentration of said chemical component is determined by a linear relationship between fluorescence emitted and the concentration of the target chemical.

Abstract: A method of detecting concentration of dipicolinic acid and terbium chloride in a chemical composition with a fluorometer, wherein the fluorometer comprises an excitation source for emitting electromagnetic radiation at one or more wavelengths, and a detector module for detecting fluorescence emitted by dipicolinic acid, emitting electromagnetic radiation from the excitation source at wavelengths that induce fluorescence in dipicolinic acid-terbium chloride combination present in the chemical composition, detecting the fluorescence emitted by the dipicolinic acid-terbium chloride combination via the detector module, and determining the concentration of dipicolinic acid using predetermined relationship between fluorescence emitted and the concentration of dipicolinic acid-terbium chloride combination.

Abstract: A fluorometer for measuring fluorescence of a sample includes an excitation source for emitting electromagnetic radiation along a first beam path to induce fluorescence in the sample. An excitation filter transmits electromagnetic radiation from the excitation source toward the sample. An excitation filter holder supports the excitation filter and defines an aperture for passage of electromagnetic radiation from the excitation source. The aperture is positioned asymmetrically relative to the first beam path such that the aperture allows an asymmetrical portion of the electromagnetic radiation in the first beam path to pass toward the sample and the excitation filter holder blocks passage of a corresponding asymmetrical portion of the electromagnetic radiation in the first beam path.

Abstract: A fluorometer for measuring fluorescence of a sample includes an excitation source for emitting electromagnetic radiation along a first beam path to induce fluorescence in the sample. An excitation filter transmits electromagnetic radiation from the excitation source toward the sample. An excitation filter holder supports the excitation filter and defines an aperture for passage of electromagnetic radiation from the excitation source. The aperture is positioned asymmetrically relative to the first beam path such that the aperture allows an asymmetrical portion of the electromagnetic radiation in the first beam path to pass toward the sample and the excitation filter holder blocks passage of a corresponding asymmetrical portion of the electromagnetic radiation in the first beam path.