Abstract: The present invention provides a method for selectively removing metal ions of interest from a solution (12), such as the wastewater from a chemical mechanical polishing process. The method comprises contacting a solution (12) containing solid particles, an oxidizing agent and a first concentration of the metal ions with an ion-exchange resin (20), such as a crosslinked poly-4-vinylpyridine resin, that is resistant to damage by the oxidizing agent and that is operative when in contact with the solution (12) to exchange selected ones of the metal ions in the solution for selected preferred ions in the ion-exchange resin thereby to produce a treated solution (22) having a second concentration of the metal ions that is lower than the first concentration. The present invention also relates to an apparatus (100) and system (500) for use with the method of the present invention.

Abstract: The present invention provides a method and apparatus for purifying effluent wastewater utilizing electrophoretic cross-flow filtration and electrode ionization. The method first comprises filtering the water in a cross-flow direction with a filter membrane in the presence of an electric field that is operative to drive suspended particles away from a surface of the filter membrane. The permeate containing dissolved solids is next passed through a mixture of at least one cation-exchange resin and at least one anion-exchange resin disposed between a cation-selective membrane and an anion-selective membrane in the presence of an electric field. The electric field drives cations in the permeate through the cation-selective membrane, and drives anions in the permeate through the anion-selective membrane, thereby to form deionized water. The apparatus includes cell modules adapted to be used in plate-and-frame or radial flow configurations.

Abstract: The present invention provides a method for selectively removing metal ions of interest from a solution (12), such as the wastewater from a chemical mechanical polishing process. The method comprises contacting a solution (12) containing solid particles, an oxidizing agent and a first concentration of the metal ions with an ion-exchange resin (20), such as a crosslinked poly-4-vinylpyridine resin, that is resistant to damage by the oxidizing agent and that is operative when in contact with the solution (12) to exchange selected ones of the metal ions in the solution for selected preferred ions in the ion-exchange resin thereby to produce a treated solution (22) having a second concentration of the metal ions that is lower than the first concentration. The present invention also relates to an apparatus (100) and system (500) for use with the method of the present invention.

Abstract: The present invention provides a method for selectively removing metal ions of interest from a solution (12), such as the wastewater from a chemical mechanical polishing process. The method comprises contacting a solution (12) containing solid particles, an oxidizing agent and a first concentration of the metal ions with an ion-exchange resin (20), such as a crosslinked poly-4-v resin, that is resistant to damage by the oxidizing agent and that is operative when in contact with the solution (12) to exchange selected ones of the metal ions in the solution for selected preferred ions in the ion-exchange resin thereby to produce a treated solution (22) having a second concentration of the metal ions that is lower than the first concentration. The present invention also relates to an apparatus (100) and system (500) for use with the method of the present invention.

Abstract: A process for fluoride removal from wastewater streams produced during industrial operation for further industrial use or to comply with environmental regulations. The process segregates the removal of fluoride and fluorosilicate ions, from the totality of ions in the waste water stream, thus improving treatment efficiency and reducing costs. Ion-exchange chromatography is used to remove the fluoride and fluorosilicate ions by passing the wastewater stream through one or more columns that contain a charged resin which selectively binds cations/anions in the stream. The fluoride ions are washed from the column and then collected for removal or use in other processes.

Abstract: The present invention provides a method and apparatus for purifying effluent wastewater utilizing electrophoretic cross-flow filtration and electrodeionization. The method first comprises filtering the water in a cross-flow direction with a filter membrane (120) in the presence of an electric field that is operative to drive suspended particles away from a surface of the filter membrane (120). The permeate (134) containing dissolved solids is next passed through a mixture (188) of at least one cation-exchange resin and at least one anion-exchange resin disposed between a cation-selective membrane (184) and an anion-selective membrane (181) in the presence of an electric field. The electric field drives cations in the permeate through the cation-selective membrane (184), and drives anions in the permeate through the anion-selective membrane (181), thereby to form deionized water (192). The apparatus includes cell modules adapted to be used in plate-and-frame or radial flow configurations.

Abstract: A process for fluoride removal from wastewater streams produced during industrial operation for further industrial use or to comply with environmental regulations. The process segregates the removal of fluoride and fluorosilicate ions, from the totality of ions in the waste water stream, thus improving treatment efficiency and reducing costs. Ion-exchange chromatography is used to remove the fluoride and fluorosilicate ions by passing the wastewater stream through one or more columns that contain a charged resin which selectively binds cations/anions in the stream. The fluoride ions are washed from the column and then collected for removal or use in other processes.

Abstract: A method for treating an electroless plating liquid or other metal-containing solution that also contains reducing agents. The method includes providing a reaction vessel containing an anode, a cathode, and a hydrogen ion-permeable membrane separating the anode and the cathode, placing the metal-containing liquid in contact with the anode, placing a catholyte solution in contact with the cathode; driving an electrical current through the anode and the cathode to oxidize the reducing agents present, and removing the used catholyte solution and the partially treated liquid from the electrodes, optionally from the reaction vessel to separate reservoirs. The partially treated liquid and an anolyte solution are placed in contact with the cathode and anode, respectively, and a current is again driven through the anode and cathode, plating a majority of the metal ions onto the cathode. The steps of oxidizing the reducing agents and plating the metal ions may also be reversed in order.

Abstract: A method and apparatus for treating an electroless plating solution is provided. The apparatus includes a reaction vessel, a cathode and an anode disposed in the interior of the reaction vessel and in electrical communication with a power source, a drain disposed in the reaction vessel, and a nozzle in fluid communication with the drain, disposed in the reaction vessel such that the nozzle and the drain are separated by the cathode and the anode. The method includes disposing an electroless plating solution in the reaction vessel, recirculating the plating solution through the reaction vessel by draining the plating solution from the reaction vessel and subsequently re-injecting the plating solution into the reaction vessel through the nozzle. A current is driven through the anode and cathode to oxidize reducing agents in the liquid and plate out the metal as the elemental metal.

Abstract: A process for fluoride removal from wastewater streams produced during industrial operation for further industrial use or to comply with environmental regulations. The process segregates the removal of fluoride and fluorosilicate ions, from the totality of ions in the waste water stream, thus improving treatment efficiency and reducing costs. Ion-exchange chromatography is used to remove the fluoride and fluorosilicate ions by passing the wastewater stream through one or more columns that contain a charged resin which selectively binds cations/anions in the stream. The fluoride ions are washed from the column and then collected for removal or use in other processes.

Abstract: A method for treating an electroless plating liquid or other metal-containing solution that also contains reducing agents. The method includes providing a reaction vessel containing an anode, a cathode, and a hydrogen ion-permeable membrane separating the anode and the cathode, placing the metal-containing liquid in contact with the anode, placing a catholyte solution in contact with the cathode; driving an electrical current through the anode and the cathode to oxidize the reducing agents present, and removing the used catholyte solution and the partially treated liquid from the electrodes, optionally from the reaction vessel to separate reservoirs. The partially treated liquid and an anolyte solution are placed in contact with the cathode and anode, respectively, and a current is again driven through the anode and cathode, plating a majority of the metal ions onto the cathode. The steps of oxidizing the reducing agents and plating the metal ions may also be reversed in order.

Abstract: An apparatus and method for electrowinning metal from ionic solutions is provided wherein ionic solution is subject to nanofiltration. An electrowinning cell (10) includes a reservoir (12) adapted to receive an ionic solution (14). During operation, metal ions in solution (14) electroplate onto cathode (18). Nanofilter (20) is in fluid communication with the reservoir and receives solution (14) from a location (22) proximate to the cathode (18). Retentate (52) is formed as a first portion (26) of the solution (14) which passes through the membrane (21) of the filter (20). Permeate (54) is formed as a second portion (28) of the solution (14) which passes through the membrane (21) of the filter (20) to a second region (29) on the opposite side of membrane (21) from the first region (27). Permeate (54) has a second concentration of metal ions lower than the first concentration in first portion (26). Retentate (52) is returned to the reservoir (12) to intermix with solution (14).

Abstract: A method for removing fluorine gas from a selected environment comprises contacting the fluorine gas with water to generate a solution of hydrofluoric acid and contacting the solution of hydrofluoric acid with an ion exchange resin having an active state operative to exchange selected ions therein for fluoride ions in the solution. The apparatus (200) may include a dual resin setup (222, 223) such that one of the ion-exchange resin can be in the service cycle while the other of the ion-exchange resins undergoes the regeneration and rinse/refill cycles.

Abstract: A process for separation and environmentally benign disposal of amine borane complexes includes adsorbing amine borane complex onto a solid support, treating the adsorbed amine borane complex with an oxidizing agent in situ on the adsorbent thereby forming decomposition products without the formation of hydrogen gas, and collecting the decomposition products for disposal thereof.

Abstract: The present invention generally relates to the removal of certain salts, such as those of calcium or magnesium, from water. More particularly, the present invention is directed to a method for efficiently softening water containing certain ions in a manner which limits the volume amount of undesirable waste that is sent to municipality waste treatment systems. Additionally, the present invention includes a water softening apparatus (100) and system (200) useable in small domestic water softeners and existing water and drainage lines.

Abstract: Disclosed are methods for conducting catalytic reactions where energy is supplied to catalyst molecules locally by using a support having thermal and electrical conductivity wherein catalysts are dispersed therein or disposed thereon and activated through the support.

Abstract: The present invention relates to an electrowinning cell adapted to recover metal ions from a solution as their corresponding elementary metals. The electrowinning cell includes a reservoir and a filter in fluid communication with the reservoir. The filter is operative to receive a solution containing metal ions from a location proximate to the cathode and to retain a first portion of the solution having a first concentration of metal ions and to remove a second portion of the solution having a second concentration of metal ions lower than the first concentration. The electrowinning cell additionally includes return means operative to return the first portion of the solution to the reservoir. The present invention also relates to a method of concentrating metal ions in a solution for use in an electrochemical cell and to a system for reducing metal ions in a solution to their corresponding elementary metals.

Abstract: A process for separation and environmentally benign disposal of amine borane complexes includes adsorbing amine borane complex onto a solid support, treating the adsorbed amine borane complex with an oxidizing agent in situ on the adsorbent thereby forming decomposition products without the formation of hydrogen gas, and collecting the decomposition products for disposal thereof.

Abstract: The present invention provides a method and apparatus for purifying effluent wastewater utilizing electrophoretic cross-flow filtration and electrode ionization. The method first comprises filtering the water in a cross-flow direction with a filter membrane (120) in the presence of an electric field that is operative to drive suspended particles away from a surface of the filter membrane (120). The permeate (134) containing dissolved solids is next passed through a mixture (188) of at least one cation-exchange resin and at least one anion-exchange resin disposed between a cation-selective membrane (184) and an anion-selective membrane (181) in the presence of an electric field. The electric field drives cations in the permeate through the cation-selective membrane (184), and drives anions in the permeate through the anion-selective membrane (181), thereby to form deionized water (192). The apparatus includes cell modules adapted to be used in plate-and-frame or radial flow configurations.

Abstract: A method for removing fluorine gas from a selected environment comprises contacting the fluorine gas with water to generate a solution of hydrofluoric acid and contacting the solution of hydrofluoric acid with an ion exchange resin having an active state operative to exchange selected ions therein for fluoride ions in the solution. The apparatus (200) may include a dual resin setup (222, 223) such that one of the ion-exchange resin can be in the service cycle while the other of the ion-exchange resins undergoes the regeneration and rinse/refill cycles.