Abstract: A perovskite solar cell and a method of manufacturing the same are provided. The perovskite solar cell includes a first electrode, a second electrode, an active layer, a hole transporting layer, electron transporting layer, and a passivation layer. The second electrode is disposed opposite to the first electrode. The active layer is disposed between the first electrode and the second electrode, and the active layer includes a perovskite layer. The hole transporting layer is disposed between the first electrode and the active layer. The electron transporting layer is disposed between the second electrode and the active layer. The passivation layer is disposed between the active layer and the electron transporting layer, and the passivation layer includes a dipolar ion having a heteroaryl group.