Abstract: A radically polymerizable composition including at least one urethane group-containing (meth) acrylate monomer, at least one fracture toughness modifier and at least one transfer reagent of the general formula I The composition is particularly suitable as dental materials, for example for the production of dental moldings by generative processes, and is characterised by a high fracture toughness.

Abstract: A free radical polymerization initiator system having at least one monoacylphosphine oxide of formula (I) in which R1, R2, R3 independently of one another are each H, or a linear or branched C1-C10 alkyl radical or OR6, R4 is a linear or branched C1-C10 alkyl radical, C1-C10 alkoxy radical, cyclohexyl radical or a phenyl, methylphenyl or mesityl radical, R5 is a linear or branched C1-C10 alkyl radical, R6 is a linear or branched C1-C6 alkyl radical, and n is 0, 1, 2 or 3, and at least one phenolic inhibitor, wherein the molar ratio of inhibitor to photoinitiator is in a range from 0.002 to 0.9. The initiator system is particularly suitable for the photopolymerization of radically polymerizable compositions containing urethane group-containing monomers and for the production of dental moldings with low discoloration.

Abstract: A polymerizable composition, which includes (a) at least one radically polymerizable oligomer, (b) at least one radically polymerizable monomer and (c) at least one initiator for the radical polymerization, characterized in that the radically polymerizable oligomer (a) is selected from the group consisting of aliphatic urethane (meth)acrylate oligomers, epoxy (meth)acrylate oligomers and polyether urethane (meth)acrylate oligomers, and the radically polymerizable monomer (b) is polyfunctional.

Abstract: Radically polymerizable dental material, which contains at least one ABA or AB block copolymer, preferably at least one monofunctional, radically polymerizable monomer (a) and preferably at least one radically polymerizable urethane di(meth)acrylate telechel (b).

Abstract: A circuit housing (100) for a wearable intraoral application, including an inner layer (105-1) of a first material (101-1) for waterproof enclosure of an electronic circuit (103); and an outer layer (105-2) of a second material (101-2) for spatially fitting the circuit housing to a set of teeth (111), at least partially covering the first material (101-1).

Abstract: A polymerizable composition, which includes (a) at least one radically polymerizable oligomer, (b) at least one radically polymerizable monomer and (c) at least one initiator for the radical polymerization, characterized in that the radically polymerizable oligomer (a) is selected from the group consisting of aliphatic urethane (meth)acrylate oligomers, epoxy (meth)acrylate oligomers and polyether urethane (meth)acrylate oligomers, and the radically polymerizable monomer (b) is polyfunctional.

Abstract: The present invention relates to a polymerizable composition, which comprises (a) at least one radically polymerizable oligomer, (b) at least one radically polymerizable monomer and (c) at least one initiator for the radical polymerization, characterized in that the radically polymerizable oligomer (a) is selected from the group consisting of aliphatic urethane (meth)acrylate oligomers, epoxy (meth)acrylate oligomers and polyether urethane (meth)acrylate oligomers, and the radically polymerizable monomer (b) is polyfunctional.

Abstract: The present invention relates to a polymerizable composition, which comprises (a) at least one radically polymerizable compound and (b) at least one initiator for the radical polymerization, wherein the composition furthermore comprises (c) at least one UV absorber and (d) at least one optical brightener and comprises at least one radically polymerizable oligomer and at least one radically polymerizable, polyfunctional monomer as the at least one radically polymerizable compound (a).

Abstract: The present invention relates to particles comprising a core, in particular a magnetic core, and a first coating of a first shell material, wherein a second coating of a second shell material is applied to the surface of the first coating facing away from the core, the second shell material is different from the first shell material and has a higher refractive index than the first shell material.

Abstract: Radically polymerizable dental material, which contains at least one ABA or AB block copolymer, preferably at least one monofunctional, radically polymerizable monomer (a) and preferably at least one radically polymerizable urethane di(meth)acrylate telechel (b).

Abstract: The present invention relates to a method for building a shaped body by layer-wise solidification of photopolymerizable building material by means of stereolithography characterized in that the positioning of a blade with respect to a vat bottom is adjusted in such a manner that the resulting predetermined, uniform layer thickness is higher than the predefined layer thickness to be set by lowering a building platform, but does not exceed the predefined layer thickness by more than 50%.

Abstract: Radically polymerizable dental material, which contains at least one sulphonic acid ester of Formula 1: in which A is H, CN, an aromatic, cycloaliphatic, linear or branched aliphatic C1-C30-hydrocarbon radical or a combination thereof; X is COO— or —CON(R1)— or is absent; B is an aromatic, cycloaliphatic, linear or branched aliphatic C1-C30-hydrocarbon radical, or a combination thereof; R1 is hydrogen or an aromatic, cycloaliphatic, linear or branched aliphatic C1-C10-hydrocarbon radical; m is an integer from 1 to 6, n is an integer from 1 to 6 and p is an integer from 1 to 6; wherein m and p cannot simultaneously be greater than 1. The compounds of Formula 1 are active as chain transfer agents in radical polymerization.

Abstract: The present invention relates to a polymerizable composition, which comprises (a) at least one radically polymerizable oligomer, (b) at least one radically polymerizable monomer and (c) at least one initiator for the radical polymerization, characterized in that the radically polymerizable oligomer (a) is selected from the group consisting of aliphatic urethane (meth)acrylate oligomers, epoxy (meth)acrylate oligomers and polyether urethane (meth)acrylate oligomers, and the radically polymerizable monomer (b) is polyfunctional.

Abstract: The present invention relates to a polymerizable composition, which comprises (a) at least one radically polymerizable compound and (b) at least one initiator for the radical polymerization, wherein the composition furthermore comprises (c) at least one UV absorber and (d) at least one optical brightener and comprises at least one radically polymerizable oligomer and at least one radically polymerizable, polyfunctional monomer as the at least one radically polymerizable compound (a).

Abstract: The invention relates to a polymerizable composition which comprises a thermolabile polymerizable compound of Formula I: A-[X-(T-X-Sp-X)p-T-X-Q-(Z)n]m?? Formula I, wherein T represents a thermolabile Diels-Alder or hetero-Diels-Alder group of the Formula The invention also relates to the use of the polymerizable composition according to the present invention and the compounds of Formula I according to the present invention as polymerization resin or for the preparation of polymerization resins and polymerizates such as adhesives, composites, stereolithographic materials, shaped parts, duromers and mounting and fixing elements, and as dental material and for the preparation of dental materials such as adhesives, cements and filling composites.

Abstract: The present invention relates to particles comprising a core, in particular a magnetic core, and a first coating of a first shell material, wherein a second coating of a second shell material is applied to the surface of the first coating facing away from the core, the second shell material is different from the first shell material and has a higher refractive index than the first shell material.

Abstract: Radically polymerizable dental material, which contains at least one compound of Formula I: and at least one thermolabile radically polymerizable compound and/or at least one photolabile radically polymerizable compound. The materials are characterized by debonding-on-demand properties.

Abstract: Radically polymerizable dental material, which contains at least one sulphonic acid ester of Formula 1: in which A is H, CN, an aromatic, cycloaliphatic, linear or branched aliphatic C1-C30-hydrocarbon radical or a combination thereof; X is COO— or —CON(R1)— or is absent; B is an aromatic, cycloaliphatic, linear or branched aliphatic C1-C30-hydrocarbon radical, or a combination thereof; R1 is hydrogen or an aromatic, cycloaliphatic, linear or branched aliphatic C1-C10-hydrocarbon radical; m is an integer from 1 to 6, n is an integer from 1 to 6 and p is an integer from 1 to 6; wherein m and p cannot simultaneously be greater than 1. The compounds of Formula 1 are active as chain transfer agents in radical polymerization.

Abstract: The invention relates to a polymerizable composition which comprises a thermolabile polymerizable compound of Formula I: A-[X-(T-X-Sp-X)p-T-X-Q-(Z)n]m?? Formula I, wherein T represents a thermolabile Diels-Alder or hetero-Diels-Alder group of the Formula The invention also relates to the use of the polymerizable composition according to the present invention and the compounds of Formula I according to the present invention as polymerization resin or for the preparation of polymerization resins and polymerizates such as adhesives, composites, stereolithographic materials, shaped parts, duromers and mounting and fixing elements, and as dental material and for the preparation of dental materials such as adhesives, cements and filling composites.

Abstract: Radically polymerizable dental material, which contains at least one compound of Formula I: and at least one thermolabile radically polymerizable compound and/or at least one photolabile radically polymerizable compound. The materials are characterized by debonding-on-demand properties.