Abstract: The present invention provides a polymer fiber containing a flame retardant. In particular, the invention provides a fiber containing poly(trimethylene terephthalate) and a flame retardant that melts at a temperature of equal to or below 280° C. The present invention also provides a process for producing such a fiber, and a material incorporating such fibers.

Abstract: A flame retardant polymer composition and a process for making the composition are provided. The flame retardant polymer composition is a poly(trimethylene terephthalate) co-polymer containing a trimethylene terephthalate monomer and a phosphorous containing flame retardant monomer. The flame retardant polymer composition is produced by a process in which the trimethylene terephthalate monomer or its precursors and the phosphorous containing flame retardant monomer or its precursors are combined to form the poly(trimethylene terephthalate) co-polymer in one or more pre-polymerization and polymerization steps.

Abstract: The present invention provides a polymer composition containing a flame retardant. In particular, the invention provides a polymer composition containing poly(trimethylene terephthalate) and a flame retardant having a flame retardant component that melts at a temperature of equal to or below 280° C. The present invention also provides a process for producing such a composition, and materials incorporating such polymer compositions.

Abstract: A process for the production and for the winding of one polyester yarn, preferably multi-filament yarn, which comprises at least about 85 weight %, in relation to the total weight of the polyester yarn, of polytrimethylene terephthalate (PTT) wherein said process is characterized in that filaments of said polyester yarn is heat-treated, before it is wound on a bobbin, at a temperature in the range of about 70° C. to about 180° C. The method of accomplishing this is by heating the godets that are used in the spinning part of the process, preferably the last pair of godets, to relax the yarns so that the yarn package will not shrink significantly during storage and/or transportation. It is thus possible to obtain at least one PTT yarn package with long-term stability during storage and which is insensitive against elevated temperatures during storage and transport.

Abstract: This invention is a spin draw process for making partially oriented yarn from polytrimethylene terephthalate (PTT) which comprises the steps of: (a) extruding and spinning PTT in forming a monofilament or multifilament yarn therefrom, (b) heating the yarn by contacting it with a first pair of godets moving at a speed in and at a temperature set to give a yarn temperature above the glass transition temperature and less than the cold crystallization temperature of PTT, (c) drawing the yarn between the first godet pair and a second pair of godets moving at a speed and a temperature of from 45 to 120° C. and having a draw ratio of 0.7 to 3.0, and (d) winding the yarns at the speed of 1 to 15% less than that of the second godet pair at a yarn temperature less than the glass transition temperature of PTT yarn.

Abstract: This invention relates to a process of making high stretch elastic knitted fabrics from (PTT) which comprises: (a) making a drawn textured yarn with an elongation to break of 30 to 60 percent by: (i) spinning a polytrimethylene terephthalate polymer into a partially oriented yarn, and (ii) draw texturing the yarn in a false-twisting texturing machine at a draw ratio of 1.05 to 2.0, and a yarn temperature of 50 to 200° C. using a either a contact heater or a non-contact heater, and (b) knitting the yarn into a fabric composed of intermeshing loops of the yarn wherein the stitch length is from 22 cm/100 stitches to 26 cm/100 stitches, and (c) scouring the knitted fabric, and (d) drying the fabric on a belt, and (e) dyeing the knitted fabric at atmospheric pressure by dispersing a dye and the fabric in water and increasing the temperature, and (f) finishing the dyed knitted fabric according to the specific procedure and (g) drying the fabric on a belt.

Abstract: A process for the production and for the winding of one polyester yarn, preferably multi-filament yarn, which comprises at least about 85 weight %, in relation to the total weight of the polyester yarn, of polytrimethylene terephthalate (PTT) wherein said process is characterized in that filaments of said polyester yarn is heat-treated, before it is wound on a bobbin, at a temperature in the range of about 70° C. to about 180° C. The method of accomplishing this is by heating the godets that are used in the spinning part of the process, preferably the last pair of godets, to relax the yarns so that the yarn package will not shrink significantly during storage and/or transportation. It is thus possible to obtain at least one PTT yarn package with long-term stability during storage and which is insensitive against elevated temperatures during storage and transport.

Abstract: A process for making textile staple fibre from polytrimethylene terephthalate (PTT) which comprises: (a) melt extruding PTT polymer at 245 to 253° C., (b) spinning the extruded PTT into yarn using at least one spinneret, (c) moving the spun yarn to a first takeup roll wherein the distance from the spinneret to the roll is from 16 to 20 feet, (d) cooling the spun yarn to less than 31° C. before it reaches the roll, (e) prior to the draw process, preconditioning the yarn under tension at a temperature of at least 60° C., (f) drawing the yarn at a temperature of at least 60° C., (g) allowing the drawn yarn to relax at a temperature of up to 190° C., and (h) crimping the drawn yarn at a temperature of 70 to 120° C., and decreasing the drawn yarn feed denier into the crimper by 10 to 60 percent by denier.

Abstract: According to the invention, a polytrimethylene terephthalate is provided having 0.6 to less than 2 mole percent dipropylene glycol. Such compositions have a reduced tendency to generate acrolein when heated in air. These PTT polymer compositions exhibit improved and enhanced dyeability as compared to conventional PTT made by the DMT process and the TPA polycondensation/solid state polymerization processes.

Abstract: This invention is a spin draw process for making partially oriented yarn from polytrimethylene terephthalate (PTT) which comprises the steps of:

Abstract: This invention relates to a process of making high stretch elastic knitted fabrics from polytrimethylene terephthalate (PTT) which comprises:

Abstract: An aqueous system comprises at least one epoxy resin and a reaction product with an amine equivalent weight of at least 50 prepared by the reaction of an (A) epoxy-functional amidoamine derived from at least one epoxy resin and an amidoamine obtained via the reaction of an acid-terminated polyalkylene glycol and a diamine in an active hydrogen:epoxy groups ratio of from 1:15 to 1:350, with (B) at least one polyamine in an active amine hydrogen:epoxy groups equivalent ratio of from 2:1 to 30:1, and, optionally (C) a monoepoxide in a remaining active amine hydrogen:epoxy groups equivalent ratio of from 5:1 to 20:1.

Abstract: According to the invention, a polytrimethylene terephthalate is provided having 0.6 to less than 2 mole percent dipropylene glycol. Such compositions have a reduced tendency to generate acrolein when heated in air. These PTT polymer compositions exhibit improved and enhanced dyeability as compared to conventional PTT made by the DMT process and the TPA polycondensation/solid state polymerization processes.

Abstract: A water-dispersible curing agent for epoxy resins is prepared by the reaction of (a) an epoxy-functional compound obtained from the reaction of at least one epoxy resin and an amidoamine derived from the reaction of an acid-terminated polyalkylene glycol and a diamine in an active amine hydrogen:epoxy groups ratio of from 1:15 to 1:350, (b) at least one polyamine in an active amine hydrogen:epoxy groups ratio of from 2:1 to 30:1 which yields an amine-terminated product having an amine equivalent weight of at least 50, and, optionally, (c) a monoepoxy in a remaining active amine hydrogen:epoxy groups ratio of from 5:1 to 20:1.

Abstract: An aqueous epoxy resin system suitable for coatings comprises (a) water, (b) at least one epoxy resin and (c) a curing agent prepared by (i) reacting at least one polyamine having at least 3 active amine hydrogen atoms per molecule and at least one epoxy resin in an epoxy equivalent to to polyamine mole ratio of from 0.9:1 to 1:10 to obtain an amine-terminated intermediate; (ii) reacting the amine-terminated intermediate with from 0.5 to 25 weight percent, based on the amine-terminated intermediate, of an acid-terminated polyalkylene glycol to yield an amine-terminated curing agent. The amine-terminated intermediate can be capped with a monoepoxide in an amine hydrogen to epoxy groups ratio of from about 1.5:1 to 30:1 prior to reaction with the acid-terminated polyalkylene glycol, or the amine-terminated curing agent following step (ii) can be capped with a monoepoxide in an amine hydrogen atoms to epoxy groups ratio of from about 2:1 to 30:1.

Abstract: A water-compatible curing agent for epoxy resins is prepared by (a) reacting at least one polyamine having at least 3 active amine hydrogen atoms per molecule and at least one epoxy resin in an epoxy equivalent to polyamine mole ratio of from 0.9:1 to 1:10 to obtain an amine-terminated intermediate; (b) reacting the amine-terminated intermediate with from 0.5 to 25 weight percent, based on the amine-terminated intermediate, of an acid-terminated polyalkylene glycol to yield an amine-terminated curing agent. The amine-terminated intermediate can be capped with a monoepoxide in an amine hydrogen atoms to epoxy groups ratio of from about 1.5:1 to 30:1 prior to reaction with the acid-terminated polyalkylene glycol, or the amine-terminated curing agent produced following step (b) can be capped with a monoepoxide.

Abstract: A polytrimethylene terephthalate composition containing about 0.1 to about 5 wt % of a polyketone can be injection molded at a low temperature and rapid molding time.

Abstract: A process for incorporation of epoxidized polydienes into aromatic epoxy resins which comprises (a) blending the epoxidized polydiene into a curing agent in a ratio of 1:20 to 1:4, (b) reacting the epoxidized polydiene and a curing agent at a temperature of from 100.degree. to 150.degree. C. over a time from 10 to 100 minutes, (c) mixing the pre-reacted epoxidized polydiene and curing agent with the aromatic epoxy resin and accelerator, and (d) curing the aromatic epoxy resin by heating the full mixture of paragraph (c) to a temperature of from 110.degree. to 170.degree. C. for from 2 to 6 hours.

Abstract: The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 1.0 to 7.0 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.