Abstract: Two-component solventless polyurethane adhesive compositions are disclosed comprising an isocyanate component comprising an isocyanate blend, and a polyol component comprising an amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines, wherein the amine-initiated polyol comprises a functionality of from 2 to 12, hydroxyl number of from 5 to 1,830, and a viscosity at 40° C. of from 500 to 20,000 mPa-s, and a silicone-based additive (e.g., an anti-foaming agent and/or a wetting agent). The adhesive compositions are formulated such that the isocyanate and polyol components can be applied to separate substrates prior to mixing. Laminate structures comprising the disclosed adhesive compositions and further comprising a polymeric barrier substrate are also disclosed.

Abstract: A composition includes polyethylene; a multifunctional co-agent having a functionality of 3 or greater, where the multifunctional co-agent is from 100 to 2000 ppm based upon the polyethylene; and a free radical generator, where the free radical generator is from 5 to 100 ppm based upon the polyethylene. Such composition may be utilized to form modified polyethylenes.

Abstract: An apparatus and process for the delivery of material to rolls of a laminator is disclosed.

Abstract: An insulated wire or cable is made by a process comprising the steps of: (A) extruding onto a covered or uncovered metal conductor or optical fiber a composition having a DF measured at 130° C. (60 Hz, 2 kV) or 120° C. (60 Hz, 8 kV) or 100° C. (60 Hz, 8 kV) of <0.5% and comprising: (1) a high melt strength ethylene-based polymer made in a tubular reactor, and (2) a peroxide, and (B) crosslinking the high melt strength ethylene-based polymer.

Abstract: Laminate film structures including an adhesive layer having gas and moisture barrier properties are disclosed. The disclosed laminate film structures comprise films bonded together with an adhesive composition, the adhesive composition having barrier properties, e.g., controlling oxygen and/or water vapor transmission rates. The disclosed laminate film structures comprise films made from polymers and/or metallized polymers whereby the weight, thickness, and/or number of film layers has been reduced by using a barrier adhesive in place of a standard adhesive while still achieving similar barrier properties.

Abstract: Recyclable, all-polyethylene laminate film structures suitable for use in a flexible packaging are disclosed. The structures comprise a film layer consisting essentially of an ethylene-based polymer and a barrier adhesive layer disposed on a surface of the film layer, wherein the structure has an oxygen transmission rate not greater than 100 O2/m2/day, measured according to ASTM Method D3985. Recyclable, all-polyethylene laminate film structures suitable for use in a flexible packaging are disclosed comprising (A) a sealant film layer consisting essentially of an ethylene-based polymer, (B) an intermediate film layer consisting essentially of an ethylene-based polymer, (C) a structural film layer consisting essentially of an ethylene-based polymer, and (D) a barrier adhesive layer, wherein the recyclable, all-polyethylene laminate film structure has an oxygen transmission rate not greater than 100 O2/m2/day, measured according to ASTM Method D3985.

Abstract: Articles made from a moisture-crosslinkable, polymeric composition comprising in weight percent based on the weight of the composition: (A) 10 to 99.99 wt % of a nonpolar ethylenic polymer grafted with silane functionality (Si-g-npPE), the npPE having the following properties before grafting: (1) a vinyl content of 0.2 to 0.7 per 1,000 carbon atoms, (2) a melt index of 1.5 to 7.0 dg/min, (3) a density of 0.913 to 0.965 g/cc, and (4) a molecular weight distribution (Mw/Mn) of equal to or less than 8; (B) 0.01 to 20 wt % of a silanol condensation catalyst; and (C) 0 to 70 wt % of a flame retardant additive; exhibit one or more of desirable (a) silane grafting efficiency; (b) hot creep performance as a cable jacket/insulation after moisture crosslinking; (c) retained dielectric strength after glancing impact as a moisture crosslinked cable construction; and (d) crush resistance as a moisture crosslinked cable construction.

Abstract: An aqueous polyurethane dispersion compositions are disclosed. The compositions include a polyurethane prepolymer dispersed in an aqueous medium, the polyurethane prepolymer comprising an isocyanate and a crystalline polyester polyol having a hydroxyl content of 20 to 150 mg KOH/g and a melt temperature of less than or equal to 90° C. Methods of forming a laminate are also disclosed. The methods include providing an aqueous polyurethane dispersion, applying the polyurethane dispersion to a surface of the first substrate, bringing the side of the first substrate into contract with a surface of the second substrate, and curing the aqueous dispersion, thereby laminating the first substrate to the second substrate. Laminates formed by the methods and including the compositions are also disclosed.

Abstract: Water-based pressure sensitive adhesive compositions are disclosed comprising (a) an acrylic emulsion having a glass transition temperature of less than or equal to 20° C., (b) optionally, a dispersant or a silane-containing compound, and (c) an ethylene or propylene copolymer emulsion. In some embodiments, (a) comprises from 75 to 99 wt % of the compositions, (b), when present, comprises from 0.1 to 5 wt % of the compositions, and (c) comprises from 0.1 to 25 wt % of the composition, each based on the dry weight of the compositions. Methods for preparing water-based pressure sensitive adhesive compositions are also disclosed comprising emulsion polymerizing at least one unsaturated monomer, thereby forming an emulsion polymer having a glass transition temperature of less than or equal to ?10° C. and blending the emulsion polymer together with a dispersant or silane-containing compound and an ethylene or propylene copolymer emulsion.

Abstract: Articles made from a moisture-curable, polymeric composition comprising in weight percent based on the weight of the composition: (A) 2 to less than 80 weight percent (wt %) of an ethylenic polymer with (1) a crystallinity at room temperature of 34% to 55%, or 65% to 80%, and (2) a melt index (I2) of 0.1 to 50 decigrams per minute (dg/min); (B) 3 to 30 wt % of a halogenated flame retardant; (C) 3 to 30 wt % an inorganic antimony flame retardant; and (D) 0 to 10 wt % of at least one of an inorganic flame retardant other than the inorganic antimony flame retardant, e.g., zinc oxide exhibit enhanced ACBD properties in comparison to articles alike in all respects except made from a composition comprising an ethylenic polymer without the requisite crystallinity at room temperature.

Abstract: Two-component solventless polyurethane adhesive compositions are disclosed. In some embodiments, the solventless adhesive composition includes an isocyanate component including an isocyanate. The solventless adhesive composition further includes a isocyanate-reactive component including a highly-reactive amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines. The isocyanate-reactive component further includes a phosphate ester polyol. The iso-cyanate-reactive component can further include one or more non-amine-initiated polyols.

Abstract: Aqueous matte coating compositions and methods for applying aqueous matte coating compositions to substrates are disclosed. The compositions comprise (a) from 10 to 65 wt % of a first acrylic bead having a calculated glass transition temperature (“Tg”) of from ?30 to 10° C. and an average diameter particle of from 0.1 to 2 ?m, (b) from 20 to 80 wt % of a second acrylic bead having a calculated Tg of from ?60 to 0° C. and an average particle diameter of from 0.5 to 30 optionally (c) from 10 to 30 wt % of a polymer binder having an average particle diameter of 0.03 to 0.5 and (d) a slip additive. In some embodiments, the slip additive comprises a silicone emulsion and a wax dispersion. In some embodiments, the slip additive comprises a polyurethane dispersion. Methods for applying aqueous matte coating compositions are also disclosed.

Abstract: A composition includes polyethylene; a multifunctional co-agent having a functionality of 3 or greater, where the multifunctional co-agent is from 100 to 2000 ppm based upon the polyethylene; and a free radical generator, where the free radical generator is from 5 to 100 ppm based upon the polyethylene. Such composition may be utilized to form modified polyethylenes.

Abstract: A two-component solventless adhesive composition is disclosed, the adhesive composition comprising an isocyanate component comprising at least one isocyanate, and a polyol component comprising at least one amine-initiated polyol having a functionality of from 3 to 8 and a hydroxyl number of from 20 to 1,000, wherein the first and second components are formulated to be applied to separate substrates before being brought together. Further, a method for forming a laminate is disclosed, the method comprising uniformly applying the isocyanate component to a first substrate, uniformly applying the polyol component to a second substrate, bringing the first and second substrates together, thereby mixing and reacting the isocyanate component and the polyol component to form an adhesive between the first and second substrates, and curing the adhesive to bond the first and second substrates. Still further, a laminate formed by the method is disclosed.

Abstract: Disclosed herein is a multilayered article comprising a core layer comprising a thermoplastic polymer; where the thermoplastic polymer comprises a polyolefin, thermoplastic starch, and a compatibilizer; where the compatibilizer does not contain ethylene acrylic acid; where the polyolefin is not polypropylene and where the polyolefin present in an amount of greater than 40 wt %, based on a total weight of the core layer; a first layer comprising a thermoplastic resin; and a second layer comprising a thermoplastic resin; where the first layer and the second layer are devoid of fillers; where the first layer is disposed on a side of the core layer that is opposed to the side that contacts the second layer; where the multilayered article has an optical clarity of greater than 80% when measured as per ASTM D 1746 and a total haze less than 8% when measured as per ASTM D 1003.

Abstract: Disclosed herein is a multilayered article comprising a first layer comprising a thermoplastic polymer; where the thermoplastic polymer comprises polyolefin, a compatibilizer and thermoplastic starch; where the first layer does not contain any filler; and a second layer comprising a polyolefin and a filler; where the second layer does not contain any thermoplastic starch. Disclosed herein too is a method of manufacturing a multilayered article comprising coextruding a first layer and a second layer; where the first layer comprises a polyolefin, a compatibilizer and thermoplastic starch and does not contain any filler; where the second layer comprises a polyolefin and a filler and does not contain any thermoplastic starch; and where the first layer contacts the second layer.

Abstract: An insulated wire or cable is made by a process comprising the steps of: (A) extruding onto a covered or uncovered metal conductor or optical fiber a composition having a DF measured at 130° C. (60 Hz, 2 kV) or 120° C. (60 Hz, 8 kV) or 100° C. (60 Hz, 8 kV) of <0.5% and comprising: (1) a high melt strength ethylene-based polymer made in a tubular reactor, and (2) a peroxide, and (B) crosslinking the high melt strength ethylene-based polymer.

Abstract: An apparatus and process for the delivery of material to rolls of a laminator is disclosed.

Abstract: A multilayer film comprising (a) a biaxially-oriented polyethylene furanoate (BO-PEF) polymer layer, (b) an optional ink layer, (c) a bonding layer, and (d) a sealant layer, wherein the BO-PEF polymer has an O2 gas permeability of less than 0.25 cc-mil/100 in.2 24 hrs atm at 80% relative humidity, or a moisture permeability of less than 0.5 g-mil/100 in.2 24 hrs atm at 38° C., or both. The film may be formed from microlayers of BO-PEF-based polymer and polymer with a melting point of at least 5° C. greater than the melting point of the BO-PEF-based polymer.

Abstract: Disclosed herein is a multilayered article comprising a core layer comprising a thermoplastic polymer; where the thermoplastic polymer comprises a polyolefin, thermoplastic starch, and a compatibilizer; where the compatibilizer does not contain ethylene acrylic acid; where the polyolefin is not polypropylene and where the polyolefin present in an amount of greater than 40 wt %, based on a total weight of the core layer; a first layer comprising a thermoplastic resin; and a second layer comprising a thermoplastic resin; where the first layer and the second layer are devoid of fillers; where the first layer is disposed on a side of the core layer that is opposed to the side that contacts the second layer; where the multilayered article has an optical clarity of greater than 80% when measured as per ASTM D 1746 and a total haze less than 8% when measured as per ASTM D 1003.