Abstract: A catalyst containing a washcoat including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms physically mixed with platinum and rhodium on a refractory metal oxide support including alumina, silica, zirconia, titania, and a physical mixture or a chemical combination or an atomically doped combination thereof is described. A catalyst containing a first washcoat zone substantially free of platinum group metal and including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms; and a second washcoat zone including copper or iron on a small pore molecular sieve material having a maximum ring size of eight tetrahedral atoms physically mixed with platinum or platinum and rhodium on a refractory metal oxide support including alumina, silica, zirconia, titania, and a physical mixture or a chemical combination or an atomically doped combination thereof is provided.

Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, described is an oxidation catalyst composite including a first oxidation material comprising a first refractory metal oxide support, a rare earth oxide, and palladium (Pd); a second oxidation material comprising a second refractory metal oxide, and platinum (Pt) and palladium (Pd); and a protective overlayer comprising a third refractory metal oxide, platinum (Pt) and, optionally, palladium (Pd), and a molecular sieve promoted with a metal selected from one or more of Cu, Fe, Co, Ni, Mn, V, and, Ag. The oxidation catalyst composite is sulfur tolerant.

Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat comprising a zeolite, Pt, and first refractory metal oxide support containing manganese, a second washcoat comprising a second refractory metal oxide support, a Pt component and a Pd component, and a third washcoat comprising palladium and a rare earth oxide component is described.