Patents by Inventor Karl D. Dreher

Karl D. Dreher has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5358046
    Abstract: A process utilizing an emulsion of a carbon dioxide phase and an aqueous phase is provided to enhance oil recovery from a subterranean formation. The aqueous phase is in a liquid state and is made up of a water-soluble polymer and surfactant dissolved within an aqueous solvent. The emulsion is prepared by condensing the carbon dioxide to a supercritical state under elevated pressure either at the surface or in situ. The carbon dioxide phase is mixed with the aqueous phase either prior to, simultaneous with, or subsequent to the condensation step. Placement of the emulsion in the formation via an injection well enables recovery of oil from the formation via a production well in accordance with one of several embodiments. In one embodiment, the emulsion functions as an oil displacement fluid. In other embodiments, the emulsion functions as a mobility control fluid or a conformance improvement treatment composition in conjunction with an oil displacement flood.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: October 25, 1994
    Assignee: Marathon Oil Company
    Inventors: Robert D. Sydansk, Karl D. Dreher
  • Patent number: 4221229
    Abstract: A fluidic fluid composition containing lamellar micelles and which exhibits retro-viscous properties at noncryogenic temperatures is composed of 7.00-7.35% of a surfactant (preferably petroleum sulfonate having an average equivalent weight of 350-525), 50.00-54.00% of liquid hydrocarbon, 24.80-28.00% of water and optionally up to 13.00-13.95% of a cosurfactant (preferably an alcohol containing 1-20 carbon atoms) and/or electrolyte (preferably inorganic salt). The micelles within the composition must have an axial ratio of at least 3.5. The composition is substantially optically clear, phase stable, birefrigent, and the flow properties are such that substantially large increases in flow rates, e.g. 20-fold, can be realized at very small pressure increases, e.g. 5%. Additional additives to impart desired properties can be included with the composition.
    Type: Grant
    Filed: March 10, 1976
    Date of Patent: September 9, 1980
    Assignee: Marathon Oil Company
    Inventors: Karl D. Dreher, William B. Gogarty
  • Patent number: 4022276
    Abstract: Fluids are injected into porous strata for many purposes. These include, for example, well stimulation, secondary-type oil recovery, mobility control, regulation of formation "wetness" and regulation of the encroachment of fluids. Fluids used for the above purposes are readily selected using nuclear magnetic resonance (NMR) measurements in the laboratory to measure the interaction between the fluids being injected into the reservoir rock and the in situ fluids or between injected fluids and the porous material. NMR measurements are taken for each component of sample fluids proposed to be injected in the reservoir for a desired purpose, or the sample fluid per se and each of the in situ fluids. NMR measurements are then taken of the interaction between the nuclei of sample fluids injected, the reservoir rock, and the nuclei of fluids in situ.
    Type: Grant
    Filed: February 13, 1976
    Date of Patent: May 10, 1977
    Assignee: Marathon Oil Company
    Inventors: Karl D. Dreher, Robert D. Sydansk
  • Patent number: 3954627
    Abstract: Compositions containing lamellar micelles and which exhibit retro-viscous property at noncryogenic temperatures are prepared by mixing 4-15 percent of a surfactant (preferably an alkaryl sulfonate having an average equivalent weight of 350-525), 30-70 percent of a liquid hydrocarbon, 15-66 percent of water and optionally up to 20 percent of a cosurfactant, preferably an alcohol containing 1-20 carbon atoms, and/or electrolyte (preferably inorganic salt). The micelles have an axial ratio of at least 3.5 and preferably the composition has a viscosity of at least 75 cp. at a shear rate of 10 sec.sup.- .sup.1 at 23.degree.C. The composition is substantially optically clear, phase stable, birefringent, and the flow properties are such that substantially large increases in flow rate, e.g. 20-fold, can be realized at very small increases in pressure drop, e.g. 5 percent. Uses for the compositions include stimulation of wells (e.g.
    Type: Grant
    Filed: November 7, 1973
    Date of Patent: May 4, 1976
    Assignee: Marathon Oil Company
    Inventors: Karl D. Dreher, William B. Gogarty
  • Patent number: 3950034
    Abstract: An improved method of pipelining solids is effected by suspending the solids in a liquid containing lamellar micelles and pumping the mixture at flow rates predetermined to produce retro-viscous behavior in the liquid at noncryogenic temperatures. The liquid is a composition containing 4-15% surfactant (preferably petroleum sulfonate having an average equivalent weight of 350-525), and at least two substantially immiscible liquids (e.g. 30-70% liquid hydrocarbon and 15-66% water) and optionally up to 20% cosurfactant (preferably an alcohol containing 1-20 carbon atoms) and/or electrolyte (preferably inorganic salt). The micelles have an axial ratio of at least 3.5. Preferably, the composition has a viscosity of at least 75 cp at a shear rate of 10.sup.-.sup.1 seconds at 23.degree.C. The composition is substantially optically clear, phase stable, birefringent, and the flow properties are such that substantially large increases in flow rates, e.g. 20-fold, can be realized at very small pressure increases, e.g.
    Type: Grant
    Filed: November 23, 1973
    Date of Patent: April 13, 1976
    Assignee: Marathon Oil Company
    Inventors: Karl D. Dreher, William B. Gogarty
  • Patent number: 3948782
    Abstract: An improved method of drilling a well is effected by circulating in the well a drilling fluid containing lamellar micelles at flow rates predetermined to produce retro-viscous behavior in the drilling fluid at noncryogenic temperatures. The composition contains 4-15% surfactant (preferably petroleum sulfonate having an average equivalent weight of 350-525), 30-70% liquid hydrocarbon, 15-66% water and optionally up to 20% cosurfactant (preferably an alcohol containing 1-20 carbon atoms) and/or electrolyte (preferably inorganic salt) and the micelles have an axial ratio of at least 3.5. Preferably, the composition has a viscosity of at least 75 cp at a shear rate of 10.sup.-.sup.1 seconds at 23.degree.C. The composition is substantially optically clear, phase stable, birefrigent, and the flow properties are such that substantially large increases in flow rates, e.g., 20-fold, can be realized at very small pressure increases, e.g., 5%.
    Type: Grant
    Filed: September 10, 1973
    Date of Patent: April 6, 1976
    Assignee: Marathon Oil Company
    Inventors: Karl D. Dreher, William B. Gogarty
  • Patent number: 3938591
    Abstract: Micellar systems which are neither oil-external nor water-external can be formed from petroleum sulfonates, e.g., crude oil sulfonates formulated with water and, optionally, cosurfactants, e.g., hexanol. Because such micellar systems resist uptake of both oil and water, they are suitable for long distance displacement in which injection wells are spaced at least about 300 feet from production wells.
    Type: Grant
    Filed: March 7, 1975
    Date of Patent: February 17, 1976
    Assignee: Marathon Oil Company
    Inventors: Paul S. Ossip, Karl D. Dreher