Patents by Inventor Karl-Heinz Dulle
Karl-Heinz Dulle has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11162178Abstract: An electrode of an electrolysis cell for gas-producing electrochemical processes, which includes a plurality of horizontal lamella elements which in the manner of a flat C-profile consist of a flat central part and one or more flank parts, where one or more transition regions of any shape are arranged between the flat central part and the one or more flank parts, where the lamella elements have a plurality of through-openings, where the lamella elements have a flat surface without structural raised regions and depressions and the flat central part has a plurality of through-openings which are arranged in rows and arranged diagonally to one another.Type: GrantFiled: November 28, 2012Date of Patent: November 2, 2021Assignee: UHDENORA S.P.A.Inventors: Karl-Heinz Dulle, Frank Funck, Dirk Hoormann, Stefan Oelmann, Peter Woltering, Carsten Schmitt, Philipp Hofmann
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Patent number: 10030300Abstract: A method for coating a substrate on one or more sides having catalytically active material producible by material deposition under vacuum in a vacuum chamber, using the following steps: loading a substrate in the chamber evacuating the chamber, cleaning the substrate by introducing a gaseous reducing agent, removing the gaseous reducing agent, applying an intermediate layer by means of vacuum arc evaporation, wherein a substrate comprising the same or similar material is introduced into the vacuum chamber, controlling the chamber temperature, coating by vacuum arc evaporation, a metal taken from the group ruthenium, iridium, titanium and mixtures thereof while oxygen is supplied, in a last step the coated substrate is removed from the chamber, wherein at least 99% of the substrate coating is free of constituents originally contained in the substrate itself, and at least 99% of the coating applied on the intermediate layer is kept free of non-oxidized metals.Type: GrantFiled: May 23, 2011Date of Patent: July 24, 2018Assignee: THYSSENKRUPP INDUSTRIAL SOLUTIONS AGInventors: Karl-Heinz Dulle, Frank Funck, Dirk Hoormann, Stefan Oelmann, Peter Woltering, Carsten Schmitt, Philipp Hofmann, Ulf-Steffen Baeumer
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Patent number: 9243336Abstract: In the case of a process for the manufacture of contact strips, in particular for electrolyzers (membrane cells), the objective is to provide a solution that allows to create a cheap but also extremely efficient method for the manufacture of such contact strips at a high electrical efficiency. This objective is achieved by applying the roll bonding method to attach a copper strip to a titanium strip.Type: GrantFiled: January 30, 2008Date of Patent: January 26, 2016Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS (ITALIA) S.R.LInventors: Steffen Köhler, Hans-Jürgen Kunz, Karl Heinz Dulle, Peter Woltering, Heinz Sibum
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Patent number: 8945358Abstract: The invention relates to an electrolysis cell of the single-element type design for chlor-alkali electrolysis plants, comprising an anode compartment and a cathode compartment, each of the two compartments containing an electrode connected to the rear wall of the respective compartment by means of parallel bars. The electrodes are thus subdivided into several sections. In accordance with the invention, at least one of two electrodes is provided with a curved shape in each section, this curved section protruding towards the opposite electrode and pressing a membrane area against the opposite electrode. According to a preferred embodiment, the curved shape of the various electrode sections is obtained by means of springs.Type: GrantFiled: September 27, 2007Date of Patent: February 3, 2015Assignee: Uhdenora S.p.A.Inventors: Peter Woltering, Karl Heinz Dulle, Randolf Kiefer, Stefan Oelmann, Ulf-Steffen Bäumer
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Publication number: 20130206584Abstract: A method for coating a substrate on one or more sides having catalytically active material producible by material deposition under vacuum in a vacuum chamber, using the following steps: loading a substrate in the chamber evacuating the chamber, cleaning the substrate by introducing a gaseous reducing agent, removing the gaseous reducing agent, applying an intermediate layer by means of vacuum arc evaporation, wherein a substrate comprising the same or similar material is introduced into the vacuum chamber, controlling the chamber temperature, coating by vacuum arc evaporation, a metal taken from the group ruthenium, iridium, titanium and mixtures thereof while oxygen is supplied, in a last step the coated substrate is removed from the chamber, wherein at least 99% of the substrate coating is free of constituents originally contained in the substrate itself, and at least 99% of the coating applied on the intermediate layer is kept free of non-oxidized metals.Type: ApplicationFiled: May 23, 2011Publication date: August 15, 2013Applicant: THYSSENKRUPP UHDE GMBHInventors: Karl-Heinz Dulle, Frank Funck, Dirk Hoormann, Stefan Oelmann, Peter Woltering, Carsten Schmitt, Philipp Hofmann, Ulf-Steffen Baeumer
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Patent number: 8444833Abstract: The invention relates to an electrolysis device for cleaning acidic waters which comprises a cathode, an anode, and an ion exchange membrane, wherein the membrane is arranged between the cathode and the anode and is attached at least along the entire circumference of its rim, wherein many inlets and outlets are arranged along the upper and lower rim of the electrolysis device which are linked to the cathode space or to the anode space, in such a way that a plug flow, ideally with a laminar profile, is created in the cathode space and in the anode space.Type: GrantFiled: May 16, 2007Date of Patent: May 21, 2013Assignee: Uhde GmbHInventors: Randolf Kiefer, Karl-Heinz Dulle, Peter Woltering, Stefan Oelmann, Ulf-Steffen Baeumer, Wolfram Stolp
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Patent number: 8057713Abstract: The invention relates to a method for producing electrically conducting nickel oxide surfaces made of nickel-containing material. According to the method, the nickel surface is first degreased and is then roughened for approximately ten minutes in a solution containing about one percent of hydrochloric acid, the process being accelerated by adding hydrogen peroxide solution, resulting in the electrolyte turning green. The nickel surface is briefly wetted, the nickel material is introduced into a solution of 3.5 molar lye to which about ten percent of hydrogen peroxide is added and is kept therein for ten minutes, and the resulting nickel hydroxide surface is dehydrated in a subsequent thermal process and is then further oxidized to obtain nickel oxide. The invention further relates to a conductive boundary layer that is produced according to the method, the electrodes therefrom, and the use thereof in chlorine-alkali electrolysis processes, in fuel cells and storage batteries.Type: GrantFiled: July 9, 2005Date of Patent: November 15, 2011Assignees: UHDE GmbH, Gaskatel Gessellschaft Fuer Gassysteme Durch Katalyse und Elektrochemie mbHInventors: Roland Beckmann, Karl-Heinz Dulle, Peter Woltering, Randolf Kiefer, Frank Holthuis, Frank Funck, Wolfram Stolp, Hans-Joachim Kohnke, Joachim Helmke
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Patent number: 7938938Abstract: Electrolysis cell in the constructive form of single elements, intended for instance for the production of chlorine, hydrogen and/or caustic soda and designed in such a way that the portion of inactive membrane surface is minimised thanks to an optimised flange type so that the ratio between the flange surface of a semi-shell and the active membrane surface can be set to less than 0.045, neither the semi-shells nor the membrane being provided with bores or recesses for accommodating the clamping members.Type: GrantFiled: June 16, 2005Date of Patent: May 10, 2011Assignee: Uhdenora S.p.A.Inventors: Roland Beckmann, Karl Heinz Dulle, Frank Funck, Randolf Kiefer, Peter Woltering
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Patent number: 7918974Abstract: The invention relates to an insulating frame of an electrolysis cell having a microstructured internal section allowing the penetration of the electrolyte even if the structured section is partly or completely overlapped by the membrane, and to an electrolysis cell equipped with the same.Type: GrantFiled: April 27, 2007Date of Patent: April 5, 2011Assignee: Uhdenora S.p.A.Inventors: Ulf Bäumer, Randolf Kiefer, Karl Heinz Dulle, Stefan Oelmann, Peter Woltering, Wolfram Stolp
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Patent number: 7901548Abstract: The invention relates to an electrolytic cell for the production of chlorine from an aqueous alkali halide solution, which mainly consists of two semi-shells, an anode, a cathode and an ion exchange membrane arranged between the electrodes. Spacer elements are arranged between the ion-exchange membrane and the electrodes for fixing the membrane in position and distributing the compressive forces, made of electrically conductive and corrosion-resistant material on at least one side of the membrane.Type: GrantFiled: January 25, 2006Date of Patent: March 8, 2011Assignee: Uhdenora S.p.A.Inventors: Roland Beckmann, Karl Heinz Dulle, Randolf Kiefer, Peter Woltering
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Publication number: 20100294653Abstract: The invention relates to an electrolysis device for cleaning acidic waters which comprises a cathode, an anode, and an ion exchange membrane, wherein the membrane is arranged between the cathode and the anode and is attached at least along the entire circumference of its rim, wherein many inlets and outlets are arranged along the upper and lower rim of the electrolysis device which are linked to the cathode space or to the anode space, in such a way that a plug flow, ideally with a laminar profile, is created in the cathode space and in the anode space.Type: ApplicationFiled: May 16, 2007Publication date: November 25, 2010Inventors: Randolf Kiefer, Karl-Heinz Dulle, Peter Woltering, Stefan Oelmann, Ulf-Steffen Baeumer, Wolfram Stolp
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Publication number: 20100219165Abstract: A device for the linear butt welding of thin metal sheets without weld filler materials comprising movable welding heads, a clamping device having at least two pressing elements which operate independently of one another at least one of the pressing elements being suitable for applying two or more distinct pressure levels and additional horizontal pressing elements are further provided in order to press the metal sheets to be welded against one other while being deformed, until full-area contact of the metal-sheet edges butting against one another is achieved as well as a welding method making use of the device.Type: ApplicationFiled: June 23, 2007Publication date: September 2, 2010Inventors: Peter Woltering, Karl-Heinz Dulle, Randolf Kieffer, Stefan Oelmann, Ulf-Steffen Bäumer, Joachim Hoedtke, Günther Kobabe
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Patent number: 7785453Abstract: An electrode for electrochemical processes for gas production, which in the installed state is located parallel and opposite to an ion exchange membrane and consists of a multitude of horizontal lamellar elements which are structured and three-dimensionally shaped and are in contact with only one surface with the membrane, wherein the lamellar elements have grooves and holes, the major part of the holes being placed in the grooves and the surfaces of such holes or part thereof are located in the grooves or extend into the grooves whereby the holes are ideally placed in the contact area of the respective lamellar element with the membrane.Type: GrantFiled: February 10, 2006Date of Patent: August 31, 2010Assignee: Uhdenora S.p.A.Inventors: Karl Heinz Dulle, Roland Beckmann, Randolf Kiefer, Peter Woltering
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Patent number: 7780822Abstract: An electrolytic cell consisting of two semi-shells and encompassing mainly the inlet and outlet devices, components for the flow control, a membrane as well as anode and cathode.Type: GrantFiled: January 25, 2006Date of Patent: August 24, 2010Assignee: UHDENORA S.p.A.Inventors: Roland Beckmann, Karl Heinz Dulle, Frank Funck, Randolf Kiefer, Peter Woltering
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Publication number: 20100092692Abstract: The invention relates to a method for coating one or more sides of substrates with catalytically active material, comprising material deposition under vacuum in a vacuum chamber, wherein the following steps are performed: (a) loading the vacuum chamber with at least one substrate, (b) closing and evacuating the vacuum chamber, (c) cleaning the substrate by introducing a gaseous reducing agent into the vacuum chamber, (d) increasing the size of the substrate surface by depositing a vaporous component on the substrate surface, (e) coating by a coating process taken from the group of plasma coating processes, physical gas deposition, sputtering processes or the like, wherein one or more metals and/or alkaline and/or earth alkaline metals or their oxides are applied to the surface of the substrate. This method may be used, for example, for coating electrodes which are used in the chlor-alkali electrolysis.Type: ApplicationFiled: November 15, 2007Publication date: April 15, 2010Applicant: UHDE GMBHInventors: Karl-Heinz Dulle, Ulf-Steffen Baeumer, Randolf Kiefer, Peter Woltering, Dirk Hoormann, Stefan Oelmann, Joachim-H. Hoedtke, Oliver Kayser
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Publication number: 20100012707Abstract: In the case of a process for the manufacture of contact strips, in particular for electrolysers (membrane cells), the objective is to provide a solution that allows to create a cheap but also extremely efficient method for the manufacture of such contact strips at a high electrical efficiency. This objective is achieved by applying the roll bonding method to attach a copper strip to a titanium strip.Type: ApplicationFiled: January 30, 2008Publication date: January 21, 2010Inventors: Steffen Köhler, Hans-Jürgen Kunz, Karl Heinz Dulle, Peter Woltering, Heinz Sibum
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Publication number: 20090236220Abstract: The invention relates to an electrolysis cell of the single-element type design for chlor-alkali electrolysis plants, comprising an anode compartment and a cathode compartment, each of the two compartments containing an electrode connected to the rear wall of the respective compartment by means of parallel bars. The electrodes are thus subdivided into several sections. In accordance with the invention, at least one of two electrodes is provided with a curved shape in each section, this curved section protruding towards the opposite electrode and pressing a membrane area against the opposite electrode. According to a preferred embodiment, the curved shape of the various electrode sections is obtained by means of springs.Type: ApplicationFiled: September 27, 2007Publication date: September 24, 2009Inventors: Peter Woltering, Karl Heinz Dulle, Randolf Kiefer, Stefan Oelmann, Ulf-Steffen Bäumer
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Publication number: 20090159435Abstract: The invention relates to an insulating frame of an electrolysis cell having a microstructured internal section allowing the penetration of the electrolyte even if the structured section is partly or completely overlapped by the membrane, and to an electrolysis cell equipped with the same.Type: ApplicationFiled: April 27, 2007Publication date: June 25, 2009Inventors: Ulf Baumer, Randolf Kiefer, Karl Heinz Dulle, Stefan Oelmann, Peter Woltering, Wolfram Stolp
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Publication number: 20080292944Abstract: The invention relates to a method for the production of a gas diffusion electrode from a silver catalyst on a PTFE-substrate. The pore system of the silver catalyst is filled with a moistening filling agent. A dimensionally stable solid body having a particle size greater than the particle size of the silver catalyst is mixed with the silver catalyst. Said compression-stable mass is formed in a first calendar in order to form a homogenous catalyst band. In a second calendar, an electroconductive discharge material is embossed in the catalyst band, and heating takes places between the first and the second calendar by means of a heating device, wherein at least parts of the moistened filling agent are eliminated. The invention also relates to a gas diffusion electrode which is produced according to said method.Type: ApplicationFiled: July 9, 2005Publication date: November 27, 2008Applicants: UHDE GMBH, GASKATEL GESELLSCHAFT FÜR GASSYSTEME DURCH KATALYSInventors: Roland Beckmann, Karl-Heinz Dulle, Peter Woltering, Randolf Kiefer, Frank Funck, Wolfram Stolp, Hans-Joachim Kohnke, Joachim Helmke
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Publication number: 20080280204Abstract: The invention relates to a method for producing electrically conducting nickel oxide surfaces made of nickel-containing material. According to said method, the nickel surface is first degreased and is then roughened for approximately ten minutes in a solution containing about one percent of hydrochloric acid, said process being accelerated by adding hydrogen peroxide solution, resulting in the electrolyte turning green. The nickel surface is briefly wetted, the nickel material is introduced into a solution of 3.5 molar lye to which about ten percent of hydrogen peroxide is added and is kept therein for ten minutes, and the resulting nickel hydroxide surface is dehydrated in a subsequent thermal process and is then further oxidized to obtain nickel oxide. The invention further relates to a conductive boundary layer that is produced according to said method, the electrodes therefrom, and the use thereof in chlorine-alkali electrolysis processes, in fuel cells and storage batteries.Type: ApplicationFiled: July 9, 2005Publication date: November 13, 2008Applicants: UHDE GMBH, Gaskatel Gessellschaft Fuer Gassysteme Durch Katalyse Und Elektrochemie MBHInventors: Roland Beckmann, Karl-Heinz Dulle, Peter Woltering, Randolf Kiefer, Frank Holthuis, Frank Funck, Wolfram Stolp, Hans-Joachim Kohnke, Joachim Helmke