Patents by Inventor Karl-Hermann Friese
Karl-Hermann Friese has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20080269043Abstract: A ceramic insulating material, in particular for sensor elements for determining the concentration of gas components in gas mixtures, is based on an alkaline earth-containing ceramic. The insulating material contains a hexaaluminate of the alkaline earth metal and at least one mixed compound of the alkaline earth metal with an acid oxide, the molar ratio of hexaaluminate to the sum of mixed compounds in the insulating material being 1.3 to 4.0.Type: ApplicationFiled: November 9, 2005Publication date: October 30, 2008Inventors: Thomas Wahl, Ulrich Eisele, Thomas Koehler, Bernd Schumann, Karl-Hermann Friese, Juergen Sindel, Stefan Nufer, Frank Buse
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Patent number: 7361620Abstract: A catalytically active layer that is used, for example, as an electrode for a solid electrolyte-based sensor element of a gas sensor for determining a gas component in a gas mixture. The catalytically active layer includes a metallic component, that includes a noble metal in the form of platinum, rhodium, and/or palladium, and additionally a base metal. At least a portion of the originally present base metal is replaced by cavities in the metallic component.Type: GrantFiled: October 31, 2002Date of Patent: April 22, 2008Assignee: Robert Bosch GmbHInventors: Hans-Martin Wiedenmann, Frank Stanglmeier, Karl-Hermann Friese
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Publication number: 20070020156Abstract: A device for cleaning gas mixtures that contain particles, in particular for cleaning soot-laden exhaust gases of internal combustion engines, is described in which the device is embodied as a filter that has a porous surface of a sintered-metal-containing filter-supporting material that is exposed to the gas mixture to be cleaned. The sintered-metal-containing filter-supporting material has a catalytically active material component.Type: ApplicationFiled: July 19, 2006Publication date: January 25, 2007Inventors: Wolfgang Kraft, Karl-Hermann Friese
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Patent number: 6582669Abstract: A method is described for producing a ceramic powder, in which at least one ceramic base powder or ceramic slurry is subject to a heat treatment for generating an intermediate product from which the ceramic powder is produced. The ceramic base powder, the ceramic slurry, or an optionally added additive is transformed in the heat treatment such that gas components are essentially avoided in the ceramic powder or such that gases released from the ceramic base powder or from the ceramic slurry adjust a partial pressure in the ceramic powder.Type: GrantFiled: July 5, 2000Date of Patent: June 24, 2003Inventor: Karl-Hermann Friese
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Publication number: 20030111341Abstract: A catalytically active layer that is used, for example, as an electrode for a solid electrolyte-based sensor element of a gas sensor for determining a gas component in a gas mixture. The catalytically active layer includes a metallic component, that includes a noble metal in the form of platinum, rhodium, and/or palladium, and additionally a base metal. At least a portion of the originally present base metal is replaced by cavities in the metallic component.Type: ApplicationFiled: October 31, 2002Publication date: June 19, 2003Inventors: Hans-Martin Wiedenmann, Frank Stanglmeier, Karl-Hermann Friese
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Patent number: 6408680Abstract: A sensor for determining an oxygen content in an exhaust gas of an internal combustion engine includes a receptacle, arranged in a longitudinal bore of a metal housing, for a sensing element. The sensing element is received in the receptacle in a gas-tight fashion via a sensing element seal, which includes a glass seal. The receptacle has a measured-gas-side ceramic shaped element and a connector-side ceramic shaped element, which are arranged axially one behind the other. A cavity into which the glass seal is pressed while hot is configured between the two ceramic shaped elements.Type: GrantFiled: April 8, 1999Date of Patent: June 25, 2002Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Heinz Geier, Helmut Weyl, Hans-Martin Wiedenmann
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Patent number: 6367309Abstract: An insulation layer of a heating device for a sensor for determination of oxygen concentration in gas mixtures, in particular exhaust gasses of an internal combustion engine, is produced by applying a silicate-free insulation base material consisting only of barium oxide and/or strontium oxide with aluminum oxide to coat the heating device (50) and then heating the heating device with the insulation base material applied to it to temperatures of about 1350° to 1600° C. to form the insulation layer (60) by sintering. The sensor includes a Nernst measuring cell provided with a first electrode (16) and a second electrode (18) arranged in a solid electrolyte (20). The insulation layer (60) is arranged between the solid electrolyte (20) and the heating device (50).Type: GrantFiled: November 17, 1999Date of Patent: April 9, 2002Assignee: Robert Bosch GmbHInventors: Lothar Diehl, Karl-Hermann Friese
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Patent number: 6347543Abstract: A measuring sensor, in particular, for determining the oxygen content in exhaust gases of internal combustion engines, includes a ceramic molding arranged in a metal housing for the accommodation of a sensor element, in particular, planar, the sensor element being sealed by a seal element made of warm-deformable temperature-resistant material. The molded housing is designed in one piece and has a cylindrically shaped longitudinal hole on the connector side, around the sensor element, and the seal element is compressed between a first compressing element on the measuring-gas side and a second compressing element on the connector side, such that it tightly encloses the sensor element and hermetically seals the sensor element with respect to the molded housing.Type: GrantFiled: November 5, 1999Date of Patent: February 19, 2002Assignee: Robert Bosch GmbHInventors: Heinz Geier, Helmut Weyl, Hans-Martin Wiedenmann, Karl-Hermann Friese
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Publication number: 20010045120Abstract: A sensor, in particular for determining the oxygen content in exhaust gases of internal combustion engines, is proposed, as well as a method for its manufacture. The sensor includes a receptacle, arranged in a longitudinal bore (16) of a metal housing (10), for a sensing element (12), in which receptacle the sensing element (12) is received in gas-tight fashion via a sensing element seal, the sensing element seal being a glass seal (57). The receptacle has a measured-gas-side ceramic shaped element (20) and a connector-side ceramic shaped element (27), which are arranged axially one behind the other. A cavity (55) into which the glass seal (57) is pressed while hot is configured between the two ceramic shaped element (20, 27).Type: ApplicationFiled: April 8, 1999Publication date: November 29, 2001Inventors: KARL-HERMANN FRIESE, HEINZ GEIER, HELMUT WEYL, HANS-MARTIN WIEDENMANN
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Patent number: 6299805Abstract: A sealing member is produced from form-pressed boron nitride powder, while adding an inorganic or organic binding agent. Such boron nitride powder is obtained during the machining of boron nitride blocks composed of hexagonal boron nitride. This powder can be fractionated according to particle size and the particle size desired for manufacturing the sealing member can be separated out.Type: GrantFiled: July 9, 1999Date of Patent: October 9, 2001Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Helmut Weyl, Anton Hans
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Patent number: 6223583Abstract: A sensor for determining an oxygen content of an exhaust gas of an internal combustion engine includes a flat-plate sensing element that is inserted in a gas-tight fashion via a hybrid seal in a ceramic shaped element that is arranged in a metal housing. The seal includes a powdered sealing packing, both placed around the sensing element in a recess at one end of the ceramic shaped element and a fusible glass seal located above the powdered sealing packing. The seal achieves gas-tight and gasoline-resistant isolation or immobilization of the sensing element in the ceramic shaped element.Type: GrantFiled: April 19, 1999Date of Patent: May 1, 2001Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Helmut Weyl
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Patent number: 6164120Abstract: A sensor for determining an oxygen level in an exhaust gas of an internal combustion engine includes a receptacle arranged in a longitudinal bore of a metallic enclosure for a sensor element. The sensor element is accommodated in a gas-tight manner using a sensor element seal. The receptacle has a measured gas-side ceramic molded component and a connection-side ceramic molded component, which are arranged one behind the other axially. A hollow space is formed between the measured gas-side ceramic molded component and the connection-side ceramic molded component, in which a metallic sealing element is hot-pressed.Type: GrantFiled: February 22, 1999Date of Patent: December 26, 2000Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Heinz Geier, Helmut Weyl, Hans-Martin Wiedenmann
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Patent number: 6096181Abstract: An electrochemical sensor for determining the oxygen content of gases of internal combustion engines includes a ceramic element that is inserted with a sealing ring into a housing. The sealing ring is built up from different metal layers. The arrangement of the metal layers proceeds from a metal support which is composed of a steel alloy. The sealing ring is covered on both sides with a roll-clad copper layer. A nickel layer can additionally be arranged beneath the copper layer.Type: GrantFiled: June 10, 1998Date of Patent: August 1, 2000Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Helmut Weyl, Hans-Martin Wiedenmann, Anton Hans
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Process of applying material, in particular for the production of electrodes for exhaust gas sensors
Patent number: 6074694Abstract: A process for applying materials to a carrier, for which the material is atomized just prior to applying it by compressed air that is supplied separately. The process is particularly suited for the application of electrically conductive material to carriers of ceramics materials.Type: GrantFiled: April 10, 1997Date of Patent: June 13, 2000Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Siegfried Nees, Frank Stanglmeier, Hans Baumann -
Patent number: 6018982Abstract: A Lambda probe type gas sensor for use in determining the oxygen content of exhaust gases produced by an internal combustion engine includes a sensor element of the electrochemical, solid electrolyte, metallic oxide semiconductor or Lambda air-fuel ratio variety, which sensor element is arranged in a metallic housing and is contacted by connecting cables that are brought out of the metallic housing. These connecting cables are each surrounded by cable insulation that is made of PTFE (Polytetra-fluoroethylene). The surface of the cable insulation has, at least in certain areas, a gas-permeable section that allows a reference atmosphere to arrive inside the cable insulation and, from there, in the metallic housing. The gas-permeable section, on the other hand, prevents ingress of liquids such as fuel, condensed water, etc., This is achieved, for example, by an additionally applied, PTFE film that is placed over the gas-permeable section.Type: GrantFiled: May 26, 1998Date of Patent: February 1, 2000Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Helmut Weyl, Anton Hans
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Patent number: 5998012Abstract: A ceramic layer system including at least two layers having respective ion conductivities which are substantially different includes a substrate layer composed of a ceramic material and having substantially no ion conductivity; and at least one conducting layer positioned adjacent to the substrate layer, containing coated ceramic particles composed of ceramic particles composed of a ceramic material having no substantial ion conductivity which are coated with a material having a substantial ion conductivity so that each conducting layer of the at least one conducting layer has a continuous phase after sintering composed of the material which has a substantial ion conductivity and so that the at least one conducting layer has an ion conductivity effective to conduct ions.Type: GrantFiled: September 19, 1996Date of Patent: December 7, 1999Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Lothar Weber, Werner Gruenwald, Gert Lindemann, Harald Neumann, Ulrich Eisele
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Patent number: 5885429Abstract: An electrochemical measuring sensor having a solid electrolyte, a first electrode exposed to a gas to be measured and a second electrode exposed to a reference gas, with the electrodes preferably being arranged on opposite sides of the solid electrolyte. At least one of the electrodes (16, 20) is provided with a contouring (24) on its side (22) that is exposed to the gas to be measured or to the reference gas, with the contouring being a trench-shaped groove (26) embossed into the surface of the electrode such that the electrode is pressed into the adjacent solid electrolyte in the region of the groove. According to the method, the embossing is done while the electrode and the solid electrolyte are in the non-sintered state, and the sensor is subsequently sintered.Type: GrantFiled: August 8, 1997Date of Patent: March 23, 1999Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Werner Gruenwald, Kurt Schmid, Claudio De La Prieta, Gerhard Schneider, Hans-Joerg Renz, Harald Neumann, Uwe Glanz, Stefan Kuschel, Ralf Haug, Manfred Moser, Kurt Bayha, Annette Seibold, Carmen Schmiedel, Reiner Schuetz
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Patent number: 5846391Abstract: A seal for a sensor element for a gas sensor for determining the oxygen content in a gas to be measured including exhaust gases of internal combustion engines, the seal including a metallic housing having defined therein a longitudinal bore; a sensor element inserted into the longitudinal bore; and a sealing arrangement provided in the longitudinal bore, surrounding at least a portion of the sensor element, and comprised of at least one seal element comprised of steatite and an additional seal element comprised of boron nitride arranged in contact with one another and in a stack having a side near the gas to be measured so that, when there is one seal element comprised of steatite, the one seal element comprised of steatite is positioned on the side of the stack near the gas to be measured, and so that, when there are two seal elements comprised of steatite, the additional seal element is positioned between the two seal elements comprised of steatite, wherein the at least one seal element comprised of steatitType: GrantFiled: April 29, 1997Date of Patent: December 8, 1998Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Helmut Weyl, Hans-Martin Wiedenmann, Anton Hans
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Patent number: 5795454Abstract: A seal for a sensor element of a gas sensor for determining the oxygen content in gases including exhaust gases of an internal combustion engine, which seal seals the sensor element in a longitudinal bore of a housing, the seal including a sealing stack which is positioned within the longitudinal bore of the housing and around the sensor element in use and which is comprised of two sealing bodies and an additional seal positioned between the two sealing bodies. The two sealing bodies are comprised of a pre-sintered ceramic material. The additional seal is comprised of a pre-pressed powder material and has a porosity which is lower than that of the two sealing bodies. The two sealing bodies and the additional seal are compressed together within the longitudinal bore in use, whereby at least the additional seal is deformed so that the sensor element is sealed in a gap-free manner within the longitudinal bore.Type: GrantFiled: December 4, 1995Date of Patent: August 18, 1998Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Helmut Weyl, Romuald Fries, Hans-Martin Wiedenmann, Anton Hans
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Patent number: 5773894Abstract: An insulation layer system, in particular for gas sensors, is proposed, having at least one electrically conductive solid-electrolyte layer (10), an electrically conductive layer (20) and at least one electrically insulating layer (13) between the solid-electrolyte layer (10) and the electrically conductive layer (20). The material of the insulating layer (13) contains, prior to sintering, pentavalent metal oxides of niobium or tantalum as an additive, it being possible for the additive to diffuse into the adjoining solid-electrolyte layer (10) during sintering.Type: GrantFiled: December 18, 1996Date of Patent: June 30, 1998Assignee: Robert Bosch GmbHInventors: Karl-Hermann Friese, Heinz Geier, Werner Gruenwald, Claudio De La Prieta