Patents by Inventor Karl Schermanz

Karl Schermanz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11135569
    Abstract: The subject matter of the invention is a method for producing composites, comprising mixed oxides of aluminum oxide and cerium/zirconium, hereinafter referred to briefly as Al/Ce/Zr oxide composite(s), using boehmite and soluble cerium/zirconium salts. Al/Ce/Zr oxide composites produced in this way have an increased thermal stability.
    Type: Grant
    Filed: January 29, 2018
    Date of Patent: October 5, 2021
    Assignees: TREIBACHER INDUSTRIE AG, SASOL GERMANY GMBH
    Inventors: Karl Schermanz, Amod Sagar, Marcos Schöneborn, Reiner Glöckler, Kai Dallman, Frank Alber, Sonke Rolfs
  • Patent number: 10780426
    Abstract: Use of a ternary vanadate of formula (I): Fex MeIy MeIIz VO4 wherein MeI and MeII are different from each other and each stand for an element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Er, Gd, Tb, Dy, Ho, Tm, Yb, Lu, Al, Bi and Sb and wherein x=0.05-0.9; y=0.05-0.9; z=0.05-0.9; x+y+z=1, as a catalyst for the oxidation of carbonaceous compounds in combustion engines.
    Type: Grant
    Filed: September 12, 2017
    Date of Patent: September 22, 2020
    Assignee: TREIBACHER INDUSTRIE AG
    Inventors: Karl Schermanz, Lars Hensgen, Amod Sagar, Alessandro Trovarelli, Marzia Casanova
  • Patent number: 10512899
    Abstract: A composition of formula Ce1-a-b-cNaMbDcOx??I wherein M stands for one or more elements from the group of alkaline metals, except sodium, N is Bi and/or Sb, D is present, or is not present, and if present is selected from one or more of Mg, Ca, Sr, Ba; Y, La, Pr, Nd, Sm, Gd, Er; Fe, Zr, Nb, Al; a is a number within the range of 0<a?0.9, b is a number within the range of 0<b?0.3, c is a number within the range of 0<c?0.2, a plus b plus c is <1, and x is a number within the range of 1.2?x?2, and its use for exhaust gas aftertreatment systems of Diesel engines, gasoline combustion engines, lean burn engines and power plants.
    Type: Grant
    Filed: July 24, 2015
    Date of Patent: December 24, 2019
    Assignee: TREIBACHER INDUSTRIE AG
    Inventors: Lars Hensgen, Karl Schermanz, Klaus Stöwe, Viktor Wolf
  • Publication number: 20190193058
    Abstract: Use of a ternary vanadate of formula (I): Fex MeIy MeIIz VO4 wherein MeI and MeII are different from each other and each stand for an element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Er, Gd, Tb, Dy, Ho, Tm, Yb, Lu, Al, Bi and Sb and wherein x=0.05-0.9; y=0.05-0.9; z=0.05-0.9; x+y+z=1, as a catalyst for the oxidation of carbonaceous compounds in combustion engines.
    Type: Application
    Filed: September 12, 2017
    Publication date: June 27, 2019
    Inventors: Karl SCHERMANZ, Lars HENSGEN, Amod SAGAR, Alessandro TROVARELLI, Marzia CASANOVA
  • Publication number: 20180147559
    Abstract: A process for the preparation of a calcined mixed oxide comprising Al-, Ce- and Zr-oxides, comprising the steps of providing an aqueous slurry comprising hydroxides of cerium and zirconium, contacting the hydroxides of cerium and zirconium with an alumina precursor to obtain an aqueous suspension of solids, isolating the solids from the aqueous suspension and drying to obtain a solid composition, calcining the solid composition of step (c) at a temperature from 450° C. to 1200° C. for at least 1 hour to obtain a calcined mixed oxide.
    Type: Application
    Filed: January 29, 2018
    Publication date: May 31, 2018
    Inventors: Karl Schermanz, Amod Sagar, Marcos Schöneborn, Reiner Glöckler, Kai Dallman, Frank Alber, Sonke Rolfs
  • Patent number: 9889428
    Abstract: A process for the preparation of a calcined mixed oxide comprising Al-, Ce- and Zr-oxides, comprising the steps of providing an aqueous slurry comprising hydroxides of cerium and zirconium, contacting the hydroxides of cerium and zirconium with an alumina precursor to obtain an aqueous suspension of solids, isolating the solids from the aqueous suspension and drying to obtain a solid composition, calcining the solid composition of step (c) at a temperature from 450° C. to 1200° C. for at least 1 hour to obtain a calcined mixed oxide.
    Type: Grant
    Filed: July 13, 2012
    Date of Patent: February 13, 2018
    Assignees: TREIBACHER INDUSTRIE AG, SASOL GERMANY GMBH
    Inventors: Karl Schermanz, Amod Sagar, Marcos Schöneborn, Reiner Glöckler, Kai Dallmann, Frank Alber, Sönke Rolfs
  • Publication number: 20170291140
    Abstract: A catalyst composition comprising a mixture of (a) a zeolite compound in an amount of from 10% to 60% by weight, wherein the zeolite compound comprises cations selected from Fe2+, Fe3+, Cu+, Cu2+ or mixtures thereof, and (b) a ceria/zirconia/alumina composite oxide, wherein the alumina content in said composite oxide is in the range of 20 to 80% by weight, in particular of 40 to 60% by weight, a catalyst comprising such catalyst composition and its use for exhaust gas after-treatment of diesel and lean burn engines.
    Type: Application
    Filed: September 21, 2015
    Publication date: October 12, 2017
    Inventors: Karl Schermanz, Amod Sagar
  • Publication number: 20170203282
    Abstract: A composition of formula Ce1-a-b-cNaMbDcOx??I wherein M stands for one or more elements from the group of alkaline metals, except sodium, N is Bi and/or Sb, D is present, or is not present, and if present is selected from one or more of Mg, Ca, Sr, Ba; Y, La, Pr, Nd, Sm, Gd, Er; Fe, Zr, Nb, Al; a is a number within the range of 0<a?0.9, b is a number within the range of 0<b?0.3, c is a number within the range of 0<c?0.2, a plus b plus c is <1, and x is a number within the range of 1.2?x?2, and its use for exhaust gas aftertreatment systems of Diesel engines, gasoline combustion engines, lean burn engines and power plants.
    Type: Application
    Filed: July 24, 2015
    Publication date: July 20, 2017
    Applicant: TREIBACHER INDUSTRIE AG
    Inventors: Lars Hensgen, Karl Schermanz, Klaus Stöwe, Viktor Wolf
  • Patent number: 9475035
    Abstract: A process for the preparation of a composition comprising Al—, Ce— and Zr-oxides, which process comprises the steps of (a) preparing an aqueous solution of a mixture of metal salts of cerium, zirconium and aluminium, which aqueous solution optionally comprises one or more salts of the Rare Earth Metals other than cerium, (b) adding to the solution obtained a base at temperatures from 0° C. to 95° C. and precipitating the mixed metal salts in the form of hydroxides or oxy-hydroxides, (d) treating the aqueous suspension obtained in step (b) with a surfactant, and (e) isolating the precipitate obtained in step (d) and treating said precipitate at a temperature from 450° C. to 1200° C., which process is characterized in that the alumina content is in the range from 35 to 80% by weight, and the surface area (BET) of the composition obtained, measured according to DIN (Deutsche Industrie Norm) 66131 after calcining for 2 hours at 1100° C.
    Type: Grant
    Filed: June 12, 2012
    Date of Patent: October 25, 2016
    Assignee: Treibacher Industrie AG
    Inventors: Karl Schermanz, Amod Sagar
  • Patent number: 8975206
    Abstract: A catalyst composition comprising a vanadate represented by the formula XVO4/S, wherein XVO4 stands for a Bi-, Sb-, Ga- and/or Al-vanadate optionally in mixture with one or more rare earth metal-vanadates, or in mixture with one or more transition metal-vanadates, or in mixture with one or more transition metal-vanadates and one or more rare earth metal-vanadates, and S is a support comprising TiO2, optionally in combination with a dopant and a process for the preparation of such catalyst compositions.
    Type: Grant
    Filed: April 12, 2011
    Date of Patent: March 10, 2015
    Assignee: Treibacher Industrie AG
    Inventors: Karl Schermanz, Amod Sagar, Alessandro Trovarelli, Marzia Casanova
  • Publication number: 20140141967
    Abstract: A process for the preparation of a composition comprising Al-, Ce- and Zr-oxides, which process comprises the steps of (a) preparing an aqueous solution of a mixture of metal salts of cerium, zirconium and aluminium, which aqueous solution optionally comprises one or more salts of the Rare Earth Metals other than cerium, (b) adding to the solution obtained a base at temperatures from 0° C. to 95° C. and precipitating the mixed metal salts in the form of hydroxides or oxy-hydroxides, (d) treating the aqueous suspension obtained in step (b) with a surfactant, and (e) isolating the precipitate obtained in step (d) and treating said precipitate at a temperature from 450° C. to 1200° C., which process is characterized in that the alumina content is in the range from 35 to 80% by weight, and the surface area (BET) of the composition obtained, measured according to DIN (Deutsche Industrie Norm) 66131 after calcining for 2 hours at 1100° C.
    Type: Application
    Filed: June 12, 2012
    Publication date: May 22, 2014
    Applicant: TREIBACHER INDUSTRIE AG
    Inventors: Karl Schermanz, Amod Sagar
  • Patent number: 8716172
    Abstract: Catalyst composition represented by the general formula REVO/S wherein RE is at least one of the group of rare earth metals Y, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Er and Yb in an amount of up to 6.0 wt.-%; V is vanadium in an amount of 0.2-2.5 wt.-%; O is oxygen in an amount of up to 3.5 wt.-%; and S is a support containing TiO2 in an amount of at least 70 wt.-%, with the rest being WO3 and optionally SiO2. This catalyst composition shows high removal efficiencies for NOx even after aging at 750° C.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: May 6, 2014
    Assignee: Treibacher Industrie AG
    Inventors: Karl Schermanz, Irene Begsteiger, Alessandro Trovarelli, Eliana Rocchini, Marzia Casanova
  • Patent number: 8465713
    Abstract: A catalyst composition represented by the general formula XVO4/S wherein XVO4 stands for TransitionMetal-Vanadate, or a mixed TransitionMetal-/RareEarth-Vanadate, and S is a support comprising TiO2.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: June 18, 2013
    Assignee: Treibacher Industrie AG
    Inventors: Karl Schermanz, Amod Sagar, Alessandro Trovarelli, Marzia Casanova
  • Publication number: 20130040808
    Abstract: A catalyst composition comprising a vanadate represented by the formula XVO4/S, wherein XVO4 stands for a Bi-, Sb-, Ga- and/or Al-vanadate optionally in mixture with one or more rare earth metal-vanadates, or in mixture with one or more transition metal-vanadates, or in mixture with one or more transition metal-vanadates and one or more rare earth met-al-vanadates, and S is a support comprising TiO2, optionally in combination with a dopant and a process for the preparation of such catalyst composi-tions.
    Type: Application
    Filed: April 12, 2011
    Publication date: February 14, 2013
    Inventors: Karl Schermanz, Amod Sagar, Alessandro Trovarelli, Marzia Casanova
  • Publication number: 20130017947
    Abstract: A process for the preparation of a calcined mixed oxide comprising Al-, Ce- and Zr-oxides, comprising the steps of providing an aqueous slurry comprising hydroxides of cerium and zirconium, contacting the hydroxides of cerium and zirconium with an alumina precursor to obtain an aqueous suspension of solids, isolating the solids from the aqueous suspension and drying to obtain a solid composition, calcining the solid composition of step (c) at a temperature from 450° C. to 1200° C. for at least 1 hour to obtain a calcined mixed oxide.
    Type: Application
    Filed: July 13, 2012
    Publication date: January 17, 2013
    Applicants: Sasol Germany GmbH, Treibacher Industries AG
    Inventors: Karl Schermanz, Amod Sagar, Marcos Schöneborn, Reiner Glöckler, Kai Dallmann, Frank Alber, Sönke Rolfs
  • Publication number: 20120264587
    Abstract: Composition in the form of a solid-solid solution which is phase stable at 1150° C./36 hours and at 1200°/4 hours and which exhibits a thermal stability in surface area of at least 15 m2/g after treatment at 1100° C./4 hours, the composition comprising oxides of zirconium and cerium wherein the oxide of zirconium is enriched, an oxide of erbium, gadolinium, dysprosium, or yttrium as a stabilizer in an amount of 10% to 30% by weight, and optionally one ore more dopant, the use of such composition in a system for exhaust gas after treatment, a process which is appropriate for the preparation of such composition and compositions obtainable by such process.
    Type: Application
    Filed: February 15, 2010
    Publication date: October 18, 2012
    Applicant: TREIBACHER INDUSTRIE AG
    Inventors: Karl Schermanz, Amod Sagar
  • Publication number: 20110150731
    Abstract: A catalyst composition represented by the general formula XVO4/S wherein XVO4 stands for TransitionMetal-Vanadate, or a mixed TransitionMetal-/RareEarth-Vanadate, and S is a support comprising TiO2.
    Type: Application
    Filed: April 16, 2010
    Publication date: June 23, 2011
    Applicant: TREIBACHER INDUSTRIE AG
    Inventors: Karl Schermanz, Amod Sagar, Alessandro Trovarelli, Marzia Casanova
  • Patent number: 7927391
    Abstract: The invention is directed to a process for the manufacture of a ceria based polishing composition, comprising (a) suspending an inorganic cerium salt or cerium hydroxide with a cerium content calculated as cerium oxide in the range of 50%-100% based on Total rare earth oxide (TREO) in an aqueous medium thereby obtaining an aqueous suspension, (b) treating said aqueous suspension with an acid or a salt of an acid selected from the group of HF, H3PO4 and H2SO4, thereby obtaining a solid suspended in said aqueous medium, (c) separating said solid from said aqueous medium, and (d) calcining the separated solid at a temperature between 750° C. and 1,200° C. and grinding the calcined solid to grain sizes in the range of 0.5 ?m to 5.0 ?m.
    Type: Grant
    Filed: July 19, 2006
    Date of Patent: April 19, 2011
    Assignee: Treibacher Industrie AG
    Inventors: Karl Schermanz, Johann Schönfelder
  • Publication number: 20100075174
    Abstract: The invention relates to a method for deposition of chromium layers as hard-chrome plating for protection against wear or corrosion and/or for decorative purposes and also an electroplating bath with which chromium layers of this type can be deposited. The invention also relates to hard-chrome surfaces produced accordingly.
    Type: Application
    Filed: July 31, 2007
    Publication date: March 25, 2010
    Applicant: Fraunhofer-Gesellschaft zur Forderung der angewandten Forschung e.V.
    Inventors: Jens Bohnet, Martin Metzner, Herwig Krassnitzer, Karl Schermanz
  • Publication number: 20080307712
    Abstract: The invention is directed to a process for the manufacture of a ceria based polishing composition, comprising (a) suspending an inorganic cerium salt or cerium hydroxide with a cerium content calculated as cerium oxide in the range of 50%-100% based on Total rare earth oxide (TREO) in an aqueous medium thereby obtaining an aqueous suspension, (b) treating said aqueous suspension with an acid or a salt of an acid selected from the group of HF, H3PO4 and H2SO4, thereby obtaining a solid suspended in said aqueous medium, (c) separating said solid from said aqueous medium, and (d) calcining the separated solid at a temperature between 750° C. and 1,200° C. and grinding the calcined solid to grain sizes in the range of 0.5 ?m to 5.0 ?m.
    Type: Application
    Filed: July 19, 2006
    Publication date: December 18, 2008
    Applicant: TREIBACHER INDUSTRIE AG
    Inventors: Karl Schermanz, Johann Schonfelder