Patents by Inventor Karla S. Colle

Karla S. Colle has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6107531
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents involves treating the fluid with an inhibitor comprising a substantially water soluble polymer having a polymer backbone .with a pendant C.sub.1 --C.sub.3 alkyl group; the polymer having an average molecular weight between about 1,000 and about 6,000,000. Preferably, the pendant alkyl group is a methyl group. The rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream Is reduced using the alkylated polymer backbone inhibitor, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. Test results are disclosed which unexpectedly show that alkylating the polymer backbone with a methyl group will produce a subcooling for the alkylated polymer that is at least about 2.degree. F. (about 1.1.degree. C.) greater than its nonalkylated counterpart.
    Type: Grant
    Filed: January 6, 1998
    Date of Patent: August 22, 2000
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Karla S. Colle, Christine A. Costello, Larry D. Talley, Russell H. Oelfke, Enock Berluche
  • Patent number: 5600044
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a N-substituted acrylamide having two nitrogen substituent groups, R.sub.1 and R.sub.2, where R.sub.1 is a hydrocarbon group having from one to ten carbon atoms and zero to four heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and combinations thereof, and R.sub.2 is a hydrogen atom or a hydrocarbon group having from one to ten carbon atoms selected from the group consisting of carbon, nitrogen, oxygen, and sulfur; alternatively, R.sub.1 and R.sub.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: February 4, 1997
    Assignee: Exxon Production Research Company
    Inventors: Karla S. Colle, Christine A. Costello, Russell H. Oelfke, Larry D. Talley, John M. Longo, Enoch Berluche
  • Patent number: 5583273
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a cyclic imino ether. Such polymers may be ring closed cyclic imino ether ("CIE") polymers, ring opened CIE polymers, or combinations thereof. Some examples of ring opened CIE polymers include various N-acyl polyalkyleneimines produced by cationic polymerization, such as N-acyl substituted polyethyleneimine, N-acyl substituted polypropyleneimine, N-acyl substituted polybutyleneimine, N-acyl substituted polypentyleneimine and copolymers thereof.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: December 10, 1996
    Assignee: Exxon Production Research Company
    Inventors: Karla S. Colle, Russell H. Oelfke
  • Patent number: 5491269
    Abstract: A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a cyclic imino ether. Some examples of such inhibitors include various N-acyl polyalkyleneimines, such as N-acyl substituted polyethyleneimine, N-acyl substituted polypropyleneimine, N-acyl substituted polybutyleneimine, N-acyl substituted polypentyleneimine and copolymers thereof. Also, such N-acyl substituted polyalkyleneimines can be used in various ratios with other substantially water soluble polymers and copolymers. Preferably, a solvent such as water, brine, alcohol, or mixtures thereof is used to produce an inhibitor solution or mixture to facilitate treatment of the petroleum fluid stream.
    Type: Grant
    Filed: September 15, 1994
    Date of Patent: February 13, 1996
    Assignee: Exxon Production Research Company
    Inventors: Karla S. Colle, Russell H. Oelfke
  • Patent number: 5254275
    Abstract: The addition of an O-alkyl-N-alkoxycarbonylthionocarbamate to a lubricating oil imparts antiwear, antioxidant and/or friction reducing performance to the oil.
    Type: Grant
    Filed: July 13, 1992
    Date of Patent: October 19, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Morton Beltzer, Jacob J. Habeeb, Karla S. Colle
  • Patent number: 5034141
    Abstract: The addition of a thiodixanthogen and a metal thiophosphate to a lubricating oil results in an unexpected synergistic improvement in the antiwear performance of the oil. Octylthiodixanthogen and zinc dialkyldithiophosphate are most preferred additives.
    Type: Grant
    Filed: September 7, 1989
    Date of Patent: July 23, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Morton Beltzer, Karla S. Colle, Jacob J. Habeeb
  • Patent number: 5019283
    Abstract: It now has been discovered that lubricating compositions containing an additive formed by reacting Mo(CO).sub.6 with dixanthogen can be enhanced by the inclusion in the composition ligands selected from polydentate ligands and mixtures thereof. Thus, the present invention comprises a major amount of an aoil of lubricating viscosity and a minor but effective amount of an additive formed by reacting Mo(CO).sub.6 with dixanthogen of the formula (ROCS.sub.2).sub.2 wherein R is an organo group having a sufficient number of carbon atoms to render the additive soluble in the oil; and a polydentate ligand or mixtures thereof, the mole ratio of additive to ligand being in the range of from about 1:1 to about 1:4.
    Type: Grant
    Filed: September 7, 1989
    Date of Patent: May 28, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Morton Beltzer, Jacob J. Habeeb, James N. Francis, Karla S. Colle
  • Patent number: 4561964
    Abstract: An improved hydroconversion process for carbonaceous materials wherein a monohydrocarbyl substituted dithiocarbamate of a metal selected from Group VIII-A of the Periodic Table of Elements or a mixture thereof is used as a catalyst precursor. The improved process is effective for both normally solid and normally liquid carbonaceous materials and for carbonaceous materials which are either solid or liquid at the conversion conditions. The hydroconversion will be accomplished at a temperature within the range from about 500.degree. to about 900.degree. F., at a total pressure within the range from about 500 to 7000 psig and at a hydrogen partial pressure within the range from about 400 to about 5000 psig.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: December 31, 1985
    Assignee: Exxon Research and Engineering Co.
    Inventors: Gopal H. Singhal, Karla S. Colle, Edward H. Edelson, Bobby L. Wilson, Loan H. Dao