Abstract: There is provided an improved electrochemical energy storage device. The storage device includes using functionalized boron nitride nanoparticles as electroactive materials in the electrodes.

Abstract: A radical anion based functionalization of two-dimensional (2D) layered materials is proposed. The covalent functionalization of the basal plane of 2D materials with charge neutral radicals is typically unstable to reduction, leading to detachment of the functional groups from the basal plane upon reduction. This instability hinders the use of functionalized 2D materials as rechargeable electroactive species, unless the functional groups are bound to the edges of the 2D material. However, to achieve high capacity without the creation of many edges and defects, a stable functionalization of the basal plane in the reduced state is required. This goal can be achieved by radical anion functionalization, whereby the reduced/discharged state of the basal-plane-functionalized 2D material is produced. The product of the radical anion functionalization can be used as the discharged state of a cathode active material, solid electrolyte or part of a polymer composite.

Abstract: A radical anion based functionalization of two-dimensional (2D) layered materials is proposed. The covalent functionalization of the basal plane of 2D materials with charge neutral radicals is typically unstable to reduction, leading to detachment of the functional groups from the basal plane upon reduction. This instability hinders the use of functionalized 2D materials as rechargeable electroactive species, unless the functional groups are bound to the edges of the 2D material. However, to achieve high capacity without the creation of many edges and defects, a stable functionalization of the basal plane in the reduced state is required. This goal can be achieved by radical anion functionalization, whereby the reduced/discharged state of the basal-plane-functionalized 2D material is produced. The product of the radical anion functionalization can be used as the discharged state of a cathode active material, solid electrolyte or part of a polymer composite.

Abstract: There is provided an improved electrochemical energy storage device. The storage device includes using functionalized boron nitride nanoparticles as electroactive materials in the electrodes.

Abstract: There is provided an improved electrochemical energy storage device. The storage device includes using functionalized boron nitride nanoparticles as electroactive materials in the electrodes.

Abstract: A method that uses a pressurized reactive medium composed of inert solvents such as pressurized liquid or supercritical fluid carbon dioxide (C02), and sulfur hexafluoride (SF6) and reactive dissolved species ozone (03) and/or boron trifluoride (BF3) and general boron trihalogenides (BX3) to react with two-dimensional (2D) layered materials and thereby synthesize covalently oxygen and/or BX3 functionalized exfoliated 2D layered materials. When 2D layered materials are dispersed in these reactive liquids or fluids by ultrasound sonication or high shear mixing, a simultaneous covalent functionalization and exfoliation of the 2D layered materials happens. Following attainment of the required extent of functionalization and exfoliation, the unreacted 03, BX3, SF6 and C02 can be easily removed as gases by decompression leaving behind the solid phase, thereby leading to efficient and economical production of functionalized and exfoliated 2D layered materials.

Abstract: There is provided an improved electrochemical energy storage device. The storage device includes using functionalized boron nitride nanoparticles as electroactive materials in the electrodes.

Abstract: Novel intercalation electrode materials including ternary acetylides of chemical formula: AnMC2 where A is alkali or alkaline-earth element; M is transition metal or metalloid element; C2 is reference to the acetylide ion; n is an integer that is 0, 1, 2, 3 or 4 when A is alkali element and 0, 1, or 2 when A is alkaline-earth element. The alkali elements are Lithium (Li), Sodium (Na), Potassium (K), Rubidium (Rb), Cesium (Cs) and Francium (Fr). The alkaline-earth elements are Berilium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), and Radium (Ra). M is a transition metal that is any element in groups 3 through 12 inclusive on the Periodic Table of Elements (elements 21 (Sc) to element 30 (Zn)). In another exemplary embodiment, M is a metalloid element.

Abstract: A low-workfunction photocathode includes a photoemissive material employed as a coating on the photocathode. The photoemissive material includes AnMC2, where A is a first metal element, the first element is an alkali metal, an alkali-earth element or the element Al; n is an integer that is 0, 1, 2, 3 or 4; M is a second metal element, the second metal element is a transition metal or a metal stand-in; and C2 is the acetylide ion C22?. The photoemissive material includes a crystalline structure or non-crystalline structure of rod-like or curvy 1-dimensional polymeric substructures with MC2 repeating units embedded in a matrix of A.

Abstract: An electrochemical energy storage device comprising a primary positive electrode, a negative electrode, and one or more ionic conductors. The ionic conductors ionically connect the primary positive electrode with the negative electrode. The primary positive electrode comprises carbon dioxide (CO2) and a means for electrochemically reducing the CO2. This means for electrochemically reducing the CO2 comprises a conductive primary current collector, contacting the CO2, whereby the CO2 is reduced upon the primary current collector during discharge. The primary current collector comprises a material to which CO2 and the ionic conductors are essentially non-corrosive. The electrochemical energy storage device uses CO2 as an electroactive species in that the CO2 is electrochemically reduced during discharge to enable the release of electrical energy from the device.

Abstract: An electrochemical energy storage device comprising a primary positive electrode, a negative electrode, and one or more ionic conductors. The ionic conductors ionically connect the primary positive electrode with the negative electrode. The primary positive electrode comprises carbon dioxide (CO2) and a means for electrochemically reducing the CO2. This means for electrochemically reducing the CO2 comprises a conductive primary current collector, contacting the CO2, whereby the CO2 is reduced upon the primary current collector during discharge. The primary current collector comprises a material to which CO2 and the ionic conductors are essentially non-corrosive. The electrochemical energy storage device uses CO2 as an electroactive species in that the CO2 is electrochemically reduced during discharge to enable the release of electrical energy from the device.

Abstract: A method and an apparatus for the differential thermal analysis of materials includes heating a first sample to be investigated and a reference sample by radiation heat transfer from respective separated radiation sources, controlling both sources according to a predetermined temperature program for the samples, interposing an element that partly transmits radiation between each of the samples and their associated sources, sensing the temperature difference between the elements, controlling one of the radiation sources in response to the temperature difference to equalize the temperature of the elements and measuring the temperature difference between the samples during the temperature program.