Abstract: A process for producing hydrogen and pyrolytic carbon from hydrocarbons may involve converting hydrocarbons into hydrogen and carbon in a reactor at temperatures of 1000° C. or more. The reactor may include two electrodes spaced apart from one another in a flow direction of the hydrocarbons. In a region of the reactor between the electrodes an inert gas component is supplied over an entire reactor cross section. The reactor contains carbon particles in the region between the two electrodes. By introducing an inert gas component over the entire reactor cross section, deposition of carbon in this region of the reactor inner wall is prevented, thus effectively inhibiting the formation of conductivity bridges on the reactor inner wall.

Abstract: A method can be used for operating a descending moving bed reactor with flowable granular material. The method involves: (i) filling an upper lock-hopper with granular material and/or emptying a lower lock-hopper, (ii) purging the lock-hoppers with purging gas, and (iii) filling the reaction chamber containing a descending moving bed from the upper lock-hopper and/or emptying the reaction chamber into the lower lock-hopper. The pressure equalization between the reaction chamber and lock-hopper is achieved with product gas. The method then involves: (iv) optionally, relieving the lock-hoppers and conveying the product gas flow into the product line, and (v) purging the lock-hoppers with purging gas.

Abstract: A process can be used for the treatment of an offgas stream, which is formed in a plant for the production of aluminum by electrolytic reduction of aluminum oxide in a melt, using at least one anode composed of a carbon-containing material. The offgas stream contains carbon oxides due to the reduction of the aluminum oxide by the carbon. At least a substream of the carbon oxides contained in the offgas stream is reacted with hydrogen or mixed with a hydrogen stream and is subsequently passed to a use. After purification and conditioning of the offgas stream in a device, an enrichment, for example with carbon monoxide, can subsequently be carried out in a reactor and the synthesis gas obtained in this way can be fed to a chemical or biotechnological plant for the synthesis of chemicals of value.

Abstract: The invention relates to a reactor comprising a moving bed of solid particles that move in the direction of gravitation, and to a method for heating a reactor that comprises a moving bed, for the purpose of pyrolysis reactions.

Abstract: A process can utilize carbon oxides formed in the production of aluminum, by electrolytic reduction of aluminum oxide in a melt using at least one anode made of a carbon-comprising material. A pyrolysis of hydrocarbons, in particular methane or natural gas, is carried out in which pyrolysis carbon and hydrogen are formed. The pyrolysis carbon is used for the production of the at least one anode. The hydrogen formed in the pyrolysis of methane is mixed with carbon dioxide and/or carbon monoxide from the electrolytic production of aluminum, to produce a gas stream which is parsed to a further use. An integrated plant contains an electrolysis apparatus for producing aluminum by melt-electrolytic reduction of aluminum oxide, and also contains at least one reactor in which pyrolysis carbon and hydrogen are produced by pyrolysis of hydrocarbons.

Abstract: An integrated process contains the following steps of: (i) pyrolysis of hydrocarbons to carbon and hydrogen, (iia) removal of at least a part of the produced carbon in step (i) and at least partly further processing of said carbon into a carbon containing electrode, and (iib) removal of the hydrogen produced in step (i) and at least partly using said hydrogen for providing energy, preferably electric energy or heat, for the electrode production in step (iia). A joint plant is also useful, which contains (a) at least one reactor for a pyrolysis process, (b) at least one reactor for the production of electrodes for an aluminum process, (c) a power plant and/or at least one gas-fired burner, and optionally, (d) at least one reactor for the electrolysis for producing aluminum.

Abstract: A reactor for carrying out an endothermic reaction, in particular a high-temperature reaction, in which a product gas is obtained from a feed gas, wherein: the reactor surrounds a reactor interior; the reactor is configured to provide a reactor bed in a reaction zone of the reactor interior, which reactor bed comprises a large number of solid material particles; the reactor is also configured to guide the feed gas into the reaction zone; in order to heat the feed gas, the reactor is designed to heat the solid material particles in the reaction zone such that, by transferring heat from the solid material particles to the feed gas, the feed gas in the reaction zone can be heated to a reaction temperature in order to participate as a starting product in the endothermic reaction for producing the product gas.

Abstract: The invention relates to a process for producing hydrogen, carbon monoxide and a carbon-containing product in at least one reaction apparatus, wherein the at least one reaction apparatus comprises a bed of carbon-containing material and is characterized in that the bed of carbon-containing material in the at least one reaction apparatus is alternately heated to a temperature of >800° C. and, no later than upon reaching a temperature of 1800° C., cooled to a maximum of 800° C., wherein hydrogen and carbon monoxide are produced during the heating phase and carbon and hydrogen are produced during the cooling phase.

Abstract: A method for producing synthesis gas may involve introducing a hydrocarbon-containing coke-oven gas and a carbon dioxide-containing converter gas into a first reaction zone where hydrogen present in the hydrocarbon-containing coke-oven gas reacts at least partly with carbon dioxide to form water, which reacts thermally with hydrocarbon to form synthesis gas containing carbon monoxide and hydrogen. The method may further involve introducing an oxygen-containing gas in a second reaction zone, and using the oxygen-containing gas and some hydrogen from the first reaction zone to produce thermal energy. Still further, the method may involve supplying the thermal energy produced in the second reaction zone to the first reaction zone.

Abstract: The invention relates to a method for producing syngas in combined operation with a metallurgical plant which comprises at least one blast furnace for producing crude iron, a converter steel mill and a coke-oven plant. Part of the blast-furnace top gas that is produced in the production of crude iron and/or part of the converter gas that occurs in the converter steel mill and/or part of the coke-oven gas that is produced in the coke-oven plant are mixed. By choosing the gas streams that are brought together to form a mixed gas and/or by changing the mixing ratios of the gas streams that are brought together, at least two streams of useful gas are produced, differing with regard to their composition and respectively prepared to form streams of syngas.

Abstract: The invention relates to a process for utilizing a hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas, wherein hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas is introduced into a reaction space and the multicomponent mixture comprised in the coproduct gas, accompanying gas and/or biogas is converted in a high-temperature zone at temperatures of more than 1000° C. and in the presence of a carrier into a product gas mixture which comprises more than 95% by volume of CO, CO2, H2, H2O, CH4 and N2 and optionally into a carbon-comprising solid which is deposited to an extent of at least 75% by weight, based on the total mass of the carbon-comprising solid, on the carrier where the flow velocity of the gas mixture of coproduct gas, accompanying gas and/or biogas in the reaction zone is less than 20 m/s.

Abstract: A method for producing synthesis gas may involve introducing a hydrocarbon-containing coke-oven gas and a carbon dioxide-containing converter gas into a first reaction zone where hydrogen present in the hydrocarbon-containing coke-oven gas reacts at least partly with carbon dioxide to form water, which reacts thermally with hydrocarbon to form synthesis gas containing carbon monoxide and hydrogen. The method may further involve introducing an oxygen-containing gas in a second reaction zone, and using the oxygen-containing gas and some hydrogen from the first reaction zone to produce thermal energy. Still further, the method may involve supplying the thermal energy produced in the second reaction zone to the first reaction zone.

Abstract: The invention relates to a method for producing syngas in combined operation with a metallurgical plant which comprises at least one blast furnace for producing crude iron, a converter steel mill and a coke-oven plant. Part of the blast-furnace top gas that is produced in the production of crude iron and/or part of the converter gas that occurs in the converter steel mill and/or part of the coke-oven gas that is produced in the coke-oven plant are mixed. By choosing the gas streams that are brought together to form a mixed gas and/or by changing the mixing ratios of the gas streams that are brought together, at least two streams of useful gas are produced, differing with regard to their composition and respectively prepared to form streams of syngas.

Abstract: The invention relates to a process for utilizing a hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas, wherein hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas is introduced into a reaction space and the multicomponent mixture comprised in the coproduct gas, accompanying gas and/or biogas is converted in a high-temperature zone at temperatures of more than 1000° C. and in the presence of a carrier into a product gas mixture which comprises more than 95% by volume of CO, CO2, H2, H2O, CH4 and N2 and optionally into a carbon-comprising solid which is deposited to an extent of at least 75% by weight, based on the total mass of the carbon-comprising solid, on the carrier where the flow velocity of the gas mixture of coproduct gas, accompanying gas and/or biogas in the reaction zone is less than 20 m/s.

Abstract: Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof. Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.

Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.

Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.

Abstract: The invention relates to a synthesis reactor and to a method for producing vinyl acetate, in which gaseous ethylene and acetic acid, in addition to oxygen or gases containing oxygen, react catalytically. The inventive synthesis reactor is a wall reactor, in which the catalytic synthesis takes place in a plurality of reaction chambers, whose free flow cross sections measure less than 2000 ?m, preferably 1000 ?m and whose indirectly cooled walls are coated with a palladium-gold catalyst.

Abstract: A process for reactions with or to form peroxidic compounds in a wall reactor whose reaction space has a specific material coating is described. Both higher space-time yields and increased selectivities can be achieved by means of the process.

Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.