Patent number: 7186670
Abstract: A process for the vapor phase ammoxidation of alkanes and olefins with a catalyst of the general empirical formula: VSbaMbQcOx wherein M is at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, Q is at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, a is 0.5 to 20, b is 2 to 50, c is 0 to 10 and x is determined by the valence requirements of the elements present. The process has a co-feed of gaseous carbon dioxide with an alkane (paraffin) and/or alkene, ammonia and an oxygen-containing gas which react in the presence of the catalyst to form a nitrile and by-products.
Type:
Grant
Filed:
September 30, 2004
Date of Patent:
March 6, 2007
Assignee:
Saudi Basic Industries Corporation
Inventors:
Edouard A. Mamedov, Kathleen A. Bethke, Shahid N. Shaikh, Armando Araujo, Neeta K. Kulkarni
Publication number: 20060069279
Abstract: A process for the vapor phase ammoxidation of alkanes and olefins with a catalyst of the general empirical formula: VSbaMbQcOx wherein M is at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, Q is at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, a is 0.5 to 20, b is 2 to 50, c is 0 to 10 and x is determined by the valence requirements of the elements present. The process has a co-feed of gaseous carbon dioxide with an alkane (paraffin) and/or alkene, ammonia and an oxygen-containing gas which react in the presence of the catalyst to form a nitrile and by-products.
Type:
Application
Filed:
September 30, 2004
Publication date:
March 30, 2006
Inventors:
Edouard Mamedov, Kathleen Bethke, Shahid Shaikh, Armando Araujo, Neeta Kulkarni
Patent number: 6710011
Abstract: A catalyst composition for the vapor phase ammoxidation of alkanes and olefins of the general empirical formulae:
VSbaMbOx
VSbaMbM′b′Ox
VSbaMbQcOx
VSbaMbQcQ′c′Ox
wherein M and M′ are at least one element selected from magnesium, aluminum, zirconium, silicon, hafnium, titanium and niobium, M and M′ being different, Q and Q′ are at least one element selected from rhenium, tungsten, molybdenum, tantalum, manganese, phosphorus, cerium, tin, boron, scandium, bismuth, gallium, indium, iron, chromium, lanthanum, yttrium, zinc, cobalt, nickel, cadmium, copper, strontium, barium, calcium, silver, potassium, sodium and cesium, Q and Q′ being different, a is 0.5 to 20, b is 2 to 50, b′ is 0 to 50, c is 0 to 10, c′ is 0 to 10 and x is determined by the valence requirements of the elements present.
Type:
Grant
Filed:
December 21, 2001
Date of Patent:
March 23, 2004
Assignee:
Saudi Basic Industries Corporatioin
Inventors:
Edouard A. Mamedov, Kathleen A. Bethke, Shahid N. Shaikh, Armando Araujo, Neeta K. Kulkarni, Andrei Khodakov