Abstract: A column 1 for removing an interfering substance to an analysis of polychlorinated biphenyls contained in an oily liquid such as an electric insulating oil from the oily liquid, includes a first column 10 packed with a multilayer silica gel 13 in which an upper layer 14 of a sulfuric acid silica gel is stacked on a lower layer 15 of a nitrate silica gel and a second column 20 connected to the lower layer 15 side of the column 10 and packed with an alumina layer 23. The nitrate silica gel of the lower layer 15 is produced by treating an activated silica gel with a mixed aqueous solution of copper nitrate and silver nitrate, wherein the ratio by mole of the copper element to the silver element (the copper element:the silver element) is preferably from 1:0.5 to 2.0.

Abstract: An optical shaping apparatus includes: an exposing unit for turning on/off irradiation of light to a hardening resin surface for each predetermined unit area to irradiate light collectively on multiple the unit areas with irradiation of light being on; and a scanning unit for irradiating an optical beam with a predetermined diameter to scan the optical beam on the hardening resin surface; with the exposing unit irradiating the light in an area offset by a predetermined number of unit areas toward the inner side than the unit areas overlapped with the profile line of the cross-sectional-shaped data on the hardening resin surface; and with the scanning unit scanning an optical beam having a first diameter along a center line offset from the profile line of the cross-sectional-shaped data, and scanning an optical beam having a second diameter shorter than the first diameter along the inner side of the profile line.

Abstract: An optical molding apparatus molds an optically molded product by stacking cured layers. Each cured layer is formed by emitting light according to cross-sectional-shape data of the optically molded product onto a surface of photo-curable resin. The optical molding apparatus includes an exposing unit and an exposure control unit. The exposing unit performs exposure on the photo-curable resin for each of small work areas that are defined by dividing an overall work area, which is where an optical molding operation is performed, into a plurality of areas. The exposure control unit controls an exposure condition of the exposing unit for each of the small work areas and allows the exposure to be performed collectively on multiple layers' worth of the photo-curable resin in a predetermined one of the small work areas.

Abstract: Column which includes a first column with an upper layer of H2SO4 silica gel and a lower layer AgNO3 silica gel and a second column packed with alumina, connected detachably to a lower end of the first column. An oily liquid containing polychlorinated biphenyls, is added to the upper layer and heated. An aliphatic hydrocarbon solvent is supplied to the upper layer, whereby polychlorinated biphenyls captured by the first column are dissolved in the aliphatic hydrocarbon and then flow to the second column. The polychlorinated biphenyls are captured by the alumina which is located near the inlet of the second column, which is then detached from the first column. A hydrophobic solvent is passed through the second column in a direction opposite to the direction in which the aliphatic hydrocarbon was passed, providing an extract containing the polychlorinated biphenyls dissolved in a small amount of the hydrophobic solvent.

Abstract: An optical molding apparatus that molds a three-dimensional model by stacking cured layers. Each cured layer is formed by emitting light according to cross-sectional-shape data of the three-dimensional model onto a surface of photo-curable resin. The optical molding apparatus includes a container that contains the photo-curable resin, a movable stage that is movable in a direction orthogonal to the surface of the photo-curable resin, an optical system that emits the light onto the surface of the photo-curable resin contained in the container so as to form each cured layer on the movable stage, and a discharging mechanism that performs a discharging operation for discharging new photo-curable resin onto a surface of each cured layer formed on the movable stage before stacking a subsequent cured layer.

Abstract: An optical molding apparatus molds a three-dimensional model by stacking cured layers. Each cured layer is formed by emitting light according to cross-sectional-shape data of the three-dimensional model onto a surface of photo-curable resin. The optical molding apparatus includes a container that contains the photo-curable resin, a movable stage that is movable in a direction orthogonal to the surface of the photo-curable resin, an optical system that emits the light onto the surface of the photo-curable resin contained in the container so as to form each cured layer on the movable stage, and a discharging mechanism that performs a discharging operation for discharging new photo-curable resin onto a surface of each cured layer formed on the movable stage before stacking a subsequent cured layer.

Abstract: A stereolithography apparatus that is configured to fabricate a three-dimensional model by forming a cured layer by irradiating an interface of a photocurable resin with light corresponding to sectional data of the three-dimensional model and stacking the cured layers includes a container holding the photocurable resin and having a constraining window configured to constrain the interface of the photocurable resin; a vertical movement table movable in a vertical direction orthogonal to the interface of the photocurable resin; an optical system configured to form the cured layer between the vertical movement table and the constraining window by irradiating the interface of the photocurable resin with light through the constraining window; and a position constraining mechanism configured to substantially flatten the constraining window by applying a force to the constraining window from the outside of the container when the cured layer is formed by the optical system.

Abstract: A column 1 for removing an interfering substance to an analysis of polychlorinated biphenyls contained in an oily liquid such as an electric insulating oil from the oily liquid, includes a first column 10 packed with a multilayer silica gel 13 in which an upper layer 14 of a sulfuric acid silica gel is stacked on a lower layer 15 of a nitrate silica gel and a second column 20 connected to the lower layer 15 side of the column 10 and packed with an alumina layer 23. The nitrate silica gel of the lower layer 15 is produced by treating an activated silica gel with a mixed aqueous solution of copper nitrate and silver nitrate, wherein the ratio by mole of the copper element to the silver element (the copper element : the silver element) is preferably from 1:0.5 to 2.0.

Abstract: An optical molding apparatus molds a three-dimensional model by stacking cured layers. Each cured layer is formed by emitting light according to cross-sectional-shape data of the three-dimensional model onto a surface of photo-curable resin. The optical molding apparatus includes a container that contains the photo-curable resin, a movable stage that is movable in a direction orthogonal to the surface of the photo-curable resin, an optical system that emits the light onto the surface of the photo-curable resin contained in the container so as to form each cured layer on the movable stage, and a discharging mechanism that performs a discharging operation for discharging new photo-curable resin onto a surface of each cured layer formed on the movable stage before stacking a subsequent cured layer.

Abstract: A column 1 is formed which includes a first column 10 in which an upper layer 14 made of sulfuric acid silica gel and a lower layer 15 made of silver nitrate silica gel are stacked and packed and a second column 20 packed with an alumina layer 23 and connected detachably to the lower end part of the first column 10. An oily liquid containing polychlorinated biphenyls, such as an electric insulating oil, is added to the upper layer 14 and then kept for a predetermined time in a state heated to at least 35° C. An aliphatic hydrocarbon solvent such as n-hexane is supplied to the upper layer 14 having been cooled to ordinary temperature. As a result, polychlorinated biphenyls captured by the first column 10 are dissolved in the aliphatic hydrocarbon solvent and then flows to the second column 20. The polychlorinated biphenyls are captured by that part of the alumina layer 23 which is located near the inlet of the second column 20. The second column 20 is then detached from the first column 10.

Abstract: Device for recovering a material to be measured comprising a reservoir filled with a sample holding material impregnated with a sample liquid in which a material to be measured is dissolved and an adsorbing column for adsorbing the material to be measured, wherein the reservoir and the adsorbing column are communicated by a straight pipe, and further communicated with a recovery vessel via a recovery pipe branched out the straight pipe. Accordingly, operations of opening/closing or switching a first valve provided on the in-flow side of the reservoir, a second valve provided on the out-flow side of the adsorbing column, and a third valve provided to a vent hole to the atmosphere in the recovery vessel, make it possible to recover the material to be measured without depositing the material on the valves.

Abstract: The cross-sectional shape data of a three-dimensional model is divided according to work small areas obtained by dividing a work entire area where optical shaping work is performed into a plurality of areas, and work small area data which is cross-sectional shape data corresponding to said work small areas is generated. Also, the work small area data is enlarged with offset width based on the contracting ratio of a light hardening resin, and areas, which are wider than the work small areas on the surface of the light hardening resin by the offset width, are subjected to one-shot exposure based on the enlarged work small area data to form a hardening layer for each of the work small areas. The present invention can be applied to, for example, an optical shaping apparatus.

Abstract: A stereolithography apparatus that is configured to fabricate a three-dimensional model by forming a cured layer by irradiating an interface of a photocurable resin with light corresponding to sectional data of the three-dimensional model and stacking the cured layers includes a container holding the photocurable resin and having a constraining window configured to constrain the interface of the photocurable resin; a vertical movement table movable in a vertical direction orthogonal to the interface of the photocurable resin; an optical system configured to form the cured layer between the vertical movement table and the constraining window by irradiating the interface of the photocurable resin with light through the constraining window; and a position constraining mechanism configured to substantially flatten the constraining window by applying a force to the constraining window from the outside of the container when the cured layer is formed by the optical system.

Abstract: An optical molding apparatus molds a three-dimensional model by stacking cured layers. Each cured layer is formed by emitting light according to cross-sectional-shape data of the three-dimensional model onto a surface of photo-curable resin. The optical molding apparatus includes a container that contains the photo-curable resin, a movable stage that is movable in a direction orthogonal to the surface of the photo-curable resin, an optical system that emits the light onto the surface of the photo-curable resin contained in the container so as to form each cured layer on the movable stage, and a discharging mechanism that performs a discharging operation for discharging new photo-curable resin onto a surface of each cured layer formed on the movable stage before stacking a subsequent cured layer.

Abstract: An optical molding apparatus molds an optically molded product by stacking cured layers. Each cured layer is formed by emitting light according to cross-sectional-shape data of the optically molded product onto a surface of photo-curable resin. The optical molding apparatus includes an exposing unit and an exposure control unit. The exposing unit performs exposure on the photo-curable resin for each of small work areas that are defined by dividing an overall work area, which is where an optical molding operation is performed, into a plurality of areas. The exposure control unit controls an exposure condition of the exposing unit for each of the small work areas and allows the exposure to be performed collectively on multiple layers' worth of the photo-curable resin in a predetermined one of the small work areas.

Abstract: The cross-sectional shape data of a three-dimensional model is divided according to work small areas obtained by dividing a work entire area where optical shaping work is performed into a plurality of areas, and work small area data which is cross-sectional shape data corresponding to said work small areas is generated. Also, the work small area data is enlarged with offset width based on the contracting ratio of a light hardening resin, and areas, which are wider than the work small areas on the surface of the light hardening resin by the offset width, are subjected to one-shot exposure based on the enlarged work small area data to form a hardening layer for each of the work small areas. The present invention can be applied to, for example, an optical shaping apparatus.

Abstract: An optical shaping apparatus includes a light source configured to irradiate light on the surface of a light hardening resin, and a spatial light modulating unit configured to subject light irradiated from the light source to spatial modulation, and irradiate the light on an irradiation area which is an area where a hardening layer is formed. Subsequently, the spatial light modulating unit divides the irradiation area into multiple sections in a zigzag form or tree-ring form, and subjects the light from the light source to spatial modulation to irradiate the light on the irradiation area for each of the sections by multiple number of times. The present invention can be applied to, for example, an optical shaping apparatus.

Abstract: An optical shaping apparatus includes: an exposing unit for turning on/off irradiation of light to a hardening resin surface for each predetermined unit area to irradiate light collectively on multiple the unit areas with irradiation of light being on; and a scanning unit for irradiating an optical beam with a predetermined diameter to scan the optical beam on the hardening resin surface; with the exposing unit irradiating the light in an area offset by a predetermined number of unit areas toward the inner side than the unit areas overlapped with the profile line of the cross-sectional-shaped data on the hardening resin surface; and with the scanning unit scanning an optical beam having a first diameter along a center line offset from the profile line of the cross-sectional-shaped data, and scanning an optical beam having a second diameter shorter than the first diameter along the inner side of the profile line.

Abstract: An aliphatic hydrocarbon solvent solution obtained by extracting dioxins contained in a specimen such as soil with an aliphatic hydrocarbon solvent is supplied to an alumina layer 33 side of a sample-preparation column 30 in which the alumina layer 33 is placed on a carbon material layer 32. Upon flowing and passing of an aliphatic hydrocarbon solvent through the alumina layer 33 and the carbon material layer 32 in this order, the dioxins contained in the aliphatic hydrocarbon solvent solution are trapped in these layers. Then, one extracting solvent among toluene, a mixed solvent of toluene and an aliphatic hydrocarbon solvent, and a hydrophilic solvent capable of dissolving dioxins is supplied to the sample-preparation column 30 in the direction opposed to the passing direction of the aliphatic hydrocarbon solvent, the dioxins trapped in the carbon material layer 32 and the alumina layer 33 are extracted to obtain a sample for analysis of dioxins.

Abstract: To treat an organotin compound in a liquid at low cost. Addition of iron oxide into a liquid containing an organotin compound allows trapping of the organotin compound in the liquid by the iron oxide, and reduction of the organotin compound concentration in the liquid. Various iron oxides such as FeO, Fe2O3(iron sesquioxide), and Fe3O4 (iron oxide black) may be used, but iron oxide black is preferred. Such the method of treating a liquid may be applied to polluted seawater at a harbor to allow reduction of the organotin compound concentration in the seawater and purification of the harbor.