Abstract: Provided is a toner having good endurance stability and good low-temperature fixability in high-speed printing, and having good resistance to the adhesion of printed paper. The toner is a magnetic toner having, on the surface of toner particle containing a binder resin and an ester compound as a releasing agent, inorganic fine particle “a” and organic-inorganic composite fine particle having a volumetric specific heat of from 2,900 kJ/(m3·° C.) to 4,200 kJ/(m3·° C.), in which a coverage A of the surface of the toner particle with the inorganic fine particle “a” is 45.0% or more and 70.0% or less.

Abstract: The present invention provides a magnetic toner that is excellent in low temperature fixability and that is also excellent in developability, suppression of fogging and transfer efficiency even in a long period of use. The magnetic toner of the present invention is a magnetic toner including a magnetic toner particle containing a binder resin and a magnetic member, and an inorganic fine particle “a” and an organic-inorganic composite fine particle, wherein the magnetic toner has (i) a true specific gravity of 1.40 g/cm3 or more and 1.70 g/cm3 or less, and (ii) a saturation magnetization at a magnetic field of 796 kA/m of 10 Am2/kg or more and 20 Am2/kg or less, and the inorganic fine particle “a” is a metal oxide having a volume resistivity of 1.0×103 ?·cm or more and 1.0×108 ?·cm or less.

Abstract: The toner comprises: toner particles each containing a binder resin and a releasing agent; and an organic-inorganic composite fine particle, wherein: the organic-inorganic composite fine particle comprises: a vinyl resin particle containing a vinyl resin, the vinyl resin containing THF-insoluble matter in an amount of 95% by mass or more; and inorganic fine particles which are exposed at surfaces of the respective organic-inorganic composite fine particles, the organic-inorganic composite fine particle 1) has a plurality of convexes derived from the inorganic fine particles on the surfaces thereof, 2) has a number average particle size of 70-500 nm, and 3) has a shape factor SF-2 as measured at a magnification of 200,000 times of 103-120, and an absolute value of difference between an SP value of the releasing agent and an SP value of the vinyl resin is 0.50 (cal/cm3)1/2 or less.

Abstract: A toner excellent in end-portion hot offset properties is provided. A toner including toner particles and an external additive, wherein the toner particles contain a binder resin, and organic-inorganic composite fine particles dispersed in the binder resin, and the organic-inorganic composite fine particles (1) have a number-average particle diameter of 70 nm or more and 500 nm or less, (2) have a structure in which inorganic fine particles are embedded in a resin particle, convexes derived from the inorganic fine particles being present on surfaces of the organic-inorganic composite fine particles, (3) have a shape factor SF-2 of 103 or more and 120 or less, and (4) contain a resin component in which a proportion of THF-insoluble matter based on a mass of the resin component is 95% by mass or more.

Abstract: To provide a toner that can keep its melt-sticking to sleeve from occurring and, even in double-sided printing, can keep high-temperature offset from occurring and obtain high-quality images on both the surface and the back. The toner comprises toner particles each of which contains a binder resin containing a resin formed by the reaction of i) a resin (A) having a softening point TA (° C.) of 70° C. to 105° C. and having a peak top of endothermic peaks at 55° C. to 120° C. with ii) a resin (B) having a softening point TB (° C.) of 120° C. to 160° C. and having a peak top of endothermic peaks at 55° C. to 120° C., and, in its viscoelasticity characteristics, has a storage elastic modulus at temperature 180° C. (G?180) of 3.0×103 Pa to 3.0×104 Pa, where the loss tangent tan ? has at least one peak having a peak top within the range of 50° C. to 70° C. and, when peak top temperature of the peak is represented by T(° C.), the loss tangent at T+10(° C.) [tan ?(T+10)] is 1.0 to 1.

Abstract: A toner is provided which is superior in the long-term storage stability and has high low-temperature fixing properties. In a DSC curve as measured with a differential scanning calorimeter, the toner has a glass transition temperature of not less than 50° C. and not more than 60° C.; and the toner has, in regard to a resin composition contained therein, a difference of not less than 0.060 W/g in heat flow between a point on the curve at a temperature of 40° C. and a baseline in the range exceeding the glass transition temperature; and in viscoelastic characteristics measured at a frequency of 6.28 rad/sec, the toner has a storage elastic modulus (G?40) at a temperature of 40° C. of not less than 7.0×108 Pa and not more than 2.0×109 Pa, and a storage elastic modulus (G?70) at a temperature of 70° C. of not less than 1.0×105 Pa and not more than 1.0×107 Pa.

Abstract: A magnetic toner having a toner particle containing a binder resin and a magnetic member, a first inorganic fine particle and an organic-inorganic composite particle on the surface of the toner particle, wherein the organic-inorganic composite particle i) has a structure in which a second inorganic fine particle is embedded in a resin particle, and ii) is contained in an amount of 0.5 mass % or more and 3.0 mass % or less based on the mass of the toner; the first inorganic fine particle contains an inorganic oxide fine particle selected from the group consisting of a silica fine particle, a titanium oxide fine particle and an alumina fine particle; has a number average particle diameter (D1) of 5 nm or more and 25 nm or less, and contains the silica fine particle in an amount of 85 mass % or more based on the inorganic oxide fine particle.

Abstract: The toner comprises: toner particles each containing a binder resin and a releasing agent; and an organic-inorganic composite fine particle, wherein: the organic-inorganic composite fine particle comprises: a vinyl resin particle containing a vinyl resin, the vinyl resin containing THF-insoluble matter in an amount of 95% by mass or more; and inorganic fine particles which are exposed at surfaces of the respective organic-inorganic composite fine particles, the organic-inorganic composite fine particle 1) has a plurality of convexes derived from the inorganic fine particles on the surfaces thereof, 2) has a number average particle size of 70-500 nm, and 3) has a shape factor SF-2 as measured at a magnification of 200,000 times of 103-120, and an absolute value of difference between an SP value of the releasing agent and an SP value of the vinyl resin is 0.50 (cal/cm3)1/2 or less.

Abstract: The toner includes a resin component containing a crystalline polyester resin and a polyester-type resin that has a long-chain monomer bonded by condensation at a terminal, the toner having, in a total heat flow measured by a temperature-modulated differential scanning calorimeter, an endothermic peak resulting from the crystalline polyester resin in a specific temperature range, and the percentage of the endothermic quantity of the endothermic peak in a reversing heat flow with respect to the endothermic quantity of the endothermic peak in the total heat flow being at least 20.0%.

Abstract: Provided is a toner that has excellent low-temperature fixability and is capable of obtaining an image having a stable image density, in which the occurrence of image defects is suppressed. The toner includes toner base particles, each of which contains a binder resin and a magnetic material, and organic-inorganic composite fine particles on each of the toner base particles. Each of the organic-inorganic composite fine particles comprises a vinyl resin particle, and inorganic fine particles which are embedded in the vinyl resin particle, and at least a part of which are exposed. The volumetric specific heat of the organic-inorganic composite fine particles and the volumetric specific heat of the toner base particles satisfy a predetermined provision.

Abstract: The present invention provides a toner that exhibits an excellent low-temperature fixability and an excellent ejected paper adhesiveness during high-speed printing, without affecting the long-term storage stability, in which the toner has a toner particle that contains a resin component, wherein the toner has, in a DSC curve measured with a differential scanning calorimeter, a glass transition temperature of at least 50° C. and not more than 65° C. and a cold crystallization peak during cooling of at least 40° C. and not more than 70° C., and has an endothermic peak in a DSC curve measured with a differential scanning calorimeter for the resin component of at least 70° C. and not more than 95° C.

Abstract: A toner excellent in end-portion hot offset properties is provided. A toner including toner particles and an external additive, wherein the toner particles contain a binder resin, and organic-inorganic composite fine particles dispersed in the binder resin, and the organic-inorganic composite fine particles (1) have a number-average particle diameter of 70 nm or more and 500 nm or less, (2) have a structure in which inorganic fine particles are embedded in a resin particle, convexes derived from the inorganic fine particles being present on surfaces of the organic-inorganic composite fine particles, (3) have a shape factor SF-2 of 103 or more and 120 or less, and (4) contain a resin component in which a proportion of THF-insoluble matter based on a mass of the resin component is 95% by mass or more.

Abstract: A toner is provided including large particle-diameter external additives with sweep to the concaves of a toner particle suppressed, so that the large particle-diameter external additives function as spacer particles for a long period. The toner includes toner particles which contain a binder resin and magnetic material, and organic-inorganic composite fine particles having a structure including inorganic fine particles embedded in a vinyl resin particle. The presence state of the magnetic material on the toner particle surface satisfies specific conditions and the presence state of the organic-inorganic composite fine particles on the toner surface satisfies specific conditions.

Abstract: Provided is magnetic toner capable of favorably maintain fluidity of the magnetic toner in a developing unit even after a large number of image formation. The magnetic toner to which an external additive that has 1) a number average particle diameter of 70 or more and 200 or less, 2) a shape factor SF-1 of 100 or more and 250 or less, and 3) a shape factor SF-2 of 105 or more and 250 or less, is added, and a covering rate by silica on the surfaces of toner particles is 40.0% or more and 70.0% or less, and the magnetic toner has specific fluidity.

Abstract: A toner having toner particles, each of which contains a binder resin and a colorant, wherein in viscoelastic properties of the toner as measured with a rotating flat plate rheometer at a frequency of 6.28 rad/sec: a storage elastic modulus at the temperature of 60° C. (G?60) is in a range from 1.0×107 to 1.0×109 (Pa), and a maximal value (G?p) exists for the storage elastic modulus in a temperature range from 110° C. to 140° C., with this G?p being in a range from 5.0×104 to 5.0×106 (Pa).

Abstract: To provide a toner that can keep its melt-sticking to sleeve from occurring and, even in double-sided printing, can keep high-temperature offset from occurring and obtain high-quality images on both the surface and the back. The toner comprises toner particles each of which contains a binder resin containing a resin formed by the reaction of i) a resin (A) having a softening point TA (° C.) of 70° C. to 105° C. and having a peak top of endothermic peaks at 55° C. to 120° C. with ii) a resin (B) having a softening point TB (° C.) of 120° C. to 160° C. and having a peak top of endothermic peaks at 55° C. to 120° C., and, in its viscoelasticity characteristics, has a storage elastic modulus at temperature 180° C. (G?180) of 3.0×103 Pa to 3.0×104 Pa, where the loss tangent tan ? has at least one peak having a peak top within the range of 50° C. to 70° C. and, when peak top temperature of the peak is represented by T(° C.), the loss tangent at T+10(° C.) [tan ?(T+10)] is 1.0 to 1.

Abstract: A toner comprising toner particles, each of which contains a binder resin and a colorant, wherein the binder resin includes a resin having an endothermic peak at a temperature of 55° C. to 120° C. in a DSC curve; the toner has a softening point Tm of 90° C. to 140° C.; in the viscoelastic characteristic of the toner measured at a frequency of 6.28 rad/sec, the storage elastic modulus at a temperature of 180° C. is 1.0×102 Pa to 1.0×104 Pa; in a chart with the temperature on the x-axis and tan ? on the y-axis, tan ? has a peak having a peak top in the range of 50° C. to 70° C.; tan ? (P) at the peak top temperature is 2.0 to 10.0; the ratio of the tan ? (P) at the peak top temperature to tan ? (Tm) at a temperature of Tm (tan ? (P)/tan ? (Tm)) is in the range of 2.5 to 8.0.

Abstract: A toner is provided which is superior in the long-term storage stability and has high low-temperature fixing properties. In a DSC curve as measured with a differential scanning calorimeter, the toner has a glass transition temperature of not less than 50° C. and not more than 60° C.; and the toner has, in regard to a resin composition contained therein, a difference of not less than 0.060 W/g in heat flow between a point on the curve at a temperature of 40° C. and a baseline in the range exceeding the glass transition temperature; and in viscoelastic characteristics measured at a frequency of 6.28 rad/sec, the toner has a storage elastic modulus (G?40) at a temperature of 40° C. of not less than 7.0×108 Pa and not more than 2.0×109 Pa, and a storage elastic modulus (G?70) at a temperature of 70° C. of not less than 1.0×105 Pa and not more than 1.0×107 Pa.

Abstract: Provided is a magnetic toner capable of preventing electrostatic offset while attaining a high image quality by a high speed machine. The magnetic toner comprises magnetic toner particles, each of which contains a binder resin and a magnetic material, and a fine inorganic powder, in which the binder resin contains a polyester unit, and the magnetic toner has a dielectric loss factor at 40° C. and 100 kHz of 0.40 pF/m or more but 1.00 pF/m or less and a dielectric loss factor at 150° C. and 100 kHz of 0.50 pF/m or more but 4.00 pF/m or less.

Abstract: An image-forming method includes forming an electrostatic image on an electrostatic image bearing member which has been charged; developing the electrostatic image to form a toner image; transferring the toner image on the electrostatic image bearing member with or without mediating an intermediate transferring member onto a transfer material; and fixing the toner image on the transfer material. The electrostatic image bearing member is a photosensitive member obtained by sequentially laminating a photoconductive layer and a surface layer formed of hydrogenated amorphous silicon carbide, and a sum of an atomic density of silicon atoms and an atomic density of carbon atoms in the surface layer of the photosensitive member is 6.60×1022 atoms/cm3 or more. The toner has a binder resin and magnetic iron oxide particles, and the magnetic iron oxide particles contain Fe(2+) at a content of 20.0 mass % or more and 25.0 mass % or less.