Patents by Inventor Katsumi Shinohara

Katsumi Shinohara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 12187845
    Abstract: A polyester resin containing: a diol constituent unit containing a unit a1 derived from spiroglycol represented by formula (1) and a unit a2 derived from ethylene glycol; and a dicarboxylic acid constituent unit containing a unit b derived from terephthalic acid and/or an ester thereof. A content of the unit a1 is from 5 to 60 mol % and a content of the unit a2 is from 30 to 95 mol %, based on a total amount of the unit a1 and the unit a2. A content of the unit b is from 80 to 100 mol % based on a total amount of the dicarboxylic acid constituent unit.
    Type: Grant
    Filed: November 2, 2023
    Date of Patent: January 7, 2025
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Katsumi Shinohara, Kazua Sato, Hiroki Ikarashi
  • Publication number: 20240076446
    Abstract: A polyester resin containing: a diol constituent unit containing a unit a1 derived from spiroglycol represented by formula (1) and a unit a2 derived from ethylene glycol; and a dicarboxylic acid constituent unit containing a unit b derived from terephthalic acid and/or an ester thereof. A content of the unit a1 is from 5 to 60 mol % and a content of the unit a2 is from 30 to 95 mol %, based on a total amount of the unit a1 and the unit a2. A content of the unit b is from 80 to 100 mol % based on a total amount of the dicarboxylic acid constituent unit.
    Type: Application
    Filed: November 2, 2023
    Publication date: March 7, 2024
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Katsumi SHINOHARA, Kazua SATO, Hiroki IKARASHI
  • Patent number: 11840603
    Abstract: A polyester resin containing: a diol constituent unit containing a unit a1 derived from spiroglycol represented by formula (1) and a unit a2 derived from ethylene glycol; and a dicarboxylic acid constituent unit containing a unit b derived from terephthalic acid and/or an ester thereof. A content of the unit a1 is from 5 to 60 mol % and a content of the unit a2 is from 30 to 95 mol %, based on a total amount of the unit a1 and the unit a2. A content of the unit b is from 80 to 100 mol % based on a total amount of the dicarboxylic acid constituent unit.
    Type: Grant
    Filed: November 8, 2021
    Date of Patent: December 12, 2023
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Katsumi Shinohara, Kazua Sato, Hiroki Ikarashi
  • Publication number: 20230312817
    Abstract: A polyester resin containing: a diol constituent unit containing a unit a1 derived from spiroglycol represented by formula (1) and a unit a2 derived from ethylene glycol; and a dicarboxylic acid constituent unit containing a unit b derived from terephthalic acid and/or an ester thereof. A content of the unit a1 is from 5 to 60 mol % and a content of the unit a2 is from 30 to 95 mol %, based on a total amount of the unit a1 and the unit a2. A content of the unit b is from 80 to 100 mol % based on a total amount of the dicarboxylic acid constituent unit.
    Type: Application
    Filed: November 8, 2021
    Publication date: October 5, 2023
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Katsumi SHINOHARA, Kazua SATO, Hiroki IKARASHI
  • Patent number: 11110629
    Abstract: An object of the present invention is to provide a method for producing resin pellets, in which occurrence of defective pellets is suppressed. The method for producing resin pellets of the present invention includes the following steps, and a strand-shaped resin has a diameter of 1.5 to 4.5 mm, is discharged at a take-off speed of 1.5 m/s to 10 m/s, a die has 10 or more die holes, and a strand interval X defined by Formula 2 satisfies the following Formula 1; step 1: discharging a molten thermoplastic resin through a die in the form of a strand; step 2: cooling the discharged strand-shaped resin using a refrigerant; and step 3: cutting the cooled strand-shaped resin to obtain resin pellets; 1.73×a?Xb?2.81×a??Formula 1 a=0.524, b=0.
    Type: Grant
    Filed: May 15, 2018
    Date of Patent: September 7, 2021
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Katsumi Shinohara, Tsutomu Nitanda
  • Publication number: 20200406504
    Abstract: An object of the present invention is to provide a method for producing resin pellets, in which occurrence of defective pellets is suppressed. The method for producing resin pellets of the present invention includes the following steps, and a strand-shaped resin has a diameter of 1.5 to 4.5 mm, is discharged at a take-off speed of 1.5 m/s to 10 m/s, a die has 10 or more die holes, and a strand interval X defined by Formula 2 satisfies the following Formula 1; step 1: discharging a molten thermoplastic resin through a die in the form of a strand; step 2: cooling the discharged strand-shaped resin using a refrigerant; and step 3: cutting the cooled strand-shaped resin to obtain resin pellets; 1.73×a?Xb?2.81×a??Formula 1 a=0.524, b=0.
    Type: Application
    Filed: May 15, 2018
    Publication date: December 31, 2020
    Inventors: Katsumi SHINOHARA, Tsutomu NITANDA
  • Patent number: 10786928
    Abstract: The polyamide pellet of the present invention includes a polyamide including diamine units and dicarboxylic acid units, 50% by mole or more of the diamine units being derived from m-xylylenediamine, wherein a spherulite density of a skin portion of the pellet is 40,000 to 250,000/mm2.
    Type: Grant
    Filed: July 23, 2015
    Date of Patent: September 29, 2020
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tatsuya Tochihara, Katsumi Shinohara, Kaname Sato, Tomonori Kato, Jun Mitadera
  • Patent number: 10696789
    Abstract: Provided is a method for producing a polyamide resin including reacting a dicarboxylic acid component containing sebacic acid in an amount of 50 mol % or more and a diamine component containing xylylenediamine in an amount of 70 mol % or more, wherein the total content of the specific compounds in the sebacic acid is 100 ppm by mass or less.
    Type: Grant
    Filed: September 8, 2015
    Date of Patent: June 30, 2020
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tatsuya Tochihara, Katsumi Shinohara, Jun Mitadera
  • Patent number: 10227451
    Abstract: A method for producing a polyamide, comprising performing melt polycondensation of a diamine component comprising xylylenediamine in an amount of 70 mol % or more and a dicarboxylic acid component comprising a linear aliphatic dicarboxylic acid having 6 to 18 carbon atoms in an amount of 70 mol % or more in the presence of a phosphorus atom-containing compound (A), wherein the decomposition temperature of the phosphorus atom-containing compound (A) is not lower than the melting point of the polyamide, and an aqueous solution of the phosphorus atom-containing compound (A) and the diamine component are added to the dicarboxylic acid component being in a molten state to perform the melt polycondensation.
    Type: Grant
    Filed: May 8, 2015
    Date of Patent: March 12, 2019
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tatsuya Tochihara, Katsumi Shinohara, Kuniaki Muneyasu
  • Patent number: 9951182
    Abstract: Provided are [1] a xylylenediamine composition containing xylylenediamine and a 5-membered or 6-membered heterocyclic compound (A) having at least one nitrogen-containing substituent and having two nitrogen atoms as atoms constituting a ring, wherein the content of the heterocyclic compound (A) is 0.001 to 0.02 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a 5-membered or 6-membered heterocyclic compound (A) having at least one nitrogen-containing substituent and having two nitrogen atoms as atoms constituting a ring, a diamine including xylylenediamine (but excluding a diamine corresponding to the above-mentioned heterocyclic compound (A)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the heterocyclic compound (A) to be introduced is 0.001 to 0.02 parts by mass based on 100 parts by mass of xylylenediamine.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: April 24, 2018
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takashi Nakamura, Hajime Yamada, Tatsuya Tochihara, Katsumi Shinohara, Jun Mitadera, Takashi Yamamoto
  • Publication number: 20170306091
    Abstract: Provided is a method for producing a polyamide resin including reacting a dicarboxylic acid component containing sebacic acid in an amount of 50 mol % or more and a diamine component containing xylylenediamine in an amount of 70 mol % or more, wherein the total content of the specific compounds in the sebacic acid is 100 ppm by mass or less.
    Type: Application
    Filed: September 8, 2015
    Publication date: October 26, 2017
    Applicant: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tatsuya TOCHIHARA, Katsumi SHINOHARA, Jun MITADERA
  • Patent number: 9783638
    Abstract: Provided are [1] a xylylenediamine composition containing xylylenediamine and 1,2-ditolylethane wherein the content of 1,2-ditolylethane is 0.001 to 0.02 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a diamine containing xylylenediamine, a dicarboxylic acid, and 1,2-ditolylethane into a reaction system and performing polycondensation reaction, wherein the amount of the 1,2-ditolylethane to be introduced is 0.001 to 0.02 parts by mass based on 100 parts by mass of the xylylenediamine.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: October 10, 2017
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tatsuya Tochihara, Katsumi Shinohara, Takashi Nakamura, Hajime Yamada, Jun Mitadera, Takashi Yamamoto
  • Patent number: 9777115
    Abstract: Provided are [1] a xylylenediamine composition containing xylylenediamine and a pyridine compound (A) having at least one substituent including an amino group, wherein the content of the pyridine compound (A) is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a pyridine compound (A) having at least one substituent including an amino group, a diamine including xylylenediamine (but excluding a diamine corresponding to the above-mentioned pyridine compound (A)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the pyridine compound (A) to be introduced is 0.001 to 0.1 parts by mass based on 100 parts by mass of xylylenediamine.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: October 3, 2017
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takashi Nakamura, Hajime Yamada, Tatsuya Tochihara, Katsumi Shinohara, Jun Mitadera, Takashi Yamamoto
  • Publication number: 20170210031
    Abstract: The polyamide pellet of the present invention includes a polyamide including diamine units and dicarboxylic acid units, 50% by mole or more of the diamine units being derived from m-xylylenediamine, wherein a spherulite density of a skin portion of the pellet is 40,000 to 250,000/mm2.
    Type: Application
    Filed: July 23, 2015
    Publication date: July 27, 2017
    Inventors: Tatsuya TOCHIHARA, Katsumi SHINOHARA, Kaname SATO, Tomonori KATO, Jun MITADERA
  • Patent number: 9637594
    Abstract: Provided are [1] a xylylenediamine composition containing xylylenediamine and a compound represented by the following general formula (1), wherein the content of the compound represented by the general formula (1) is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine; and a method for producing a polyamide resin including the steps of introducing a compound represented by the following general formula (1), a diamine including xylylenediamine (but excluding the compound represented by the general formula (1)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the compound represented by the general formula (1) to be introduced is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine, where, in the general formula (1), n and m each independently represent an integer of 0 to 6, excluding the case where n and m are both 1.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: May 2, 2017
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tatsuya Tochihara, Katsumi Shinohara, Takashi Nakamura, Hajime Yamada, Jun Mitadera, Takashi Yamamoto
  • Publication number: 20170073469
    Abstract: A method for producing a polyamide, comprising performing melt polycondensation of a diamine component comprising xylylenediamine in an amount of 70 mol % or more and a dicarboxylic acid component comprising a linear aliphatic dicarboxylic acid having 6 to 18 carbon atoms in an amount of 70 mol % or more in the presence of a phosphorus atom-containing compound (A), wherein the decomposition temperature of the phosphorus atom-containing compound (A) is not lower than the melting point of the polyamide, and an aqueous solution of the phosphorus atom-containing compound (A) and the diamine component are added to the dicarboxylic acid component being in a molten state to perform the melt polycondensation.
    Type: Application
    Filed: May 8, 2015
    Publication date: March 16, 2017
    Inventors: Tatsuya TOCHIHARA, Katsumi SHINOHARA, Kuniaki MUNEYASU
  • Patent number: 9562144
    Abstract: Provided are a xylylenediamine composition containing xylylenediamine and bis(methylbenzyl)amine, a content of the bis(methylbenzyl)amine being 0.0005 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine; and a method for producing a polyamide resin including the steps of introducing a diamine containing xylylenediamine, a dicarboxylic acid, and bis(methylbenzyl)amine in an amount of 0.0005 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine into a reaction system and performing a polycondensation reaction.
    Type: Grant
    Filed: April 9, 2014
    Date of Patent: February 7, 2017
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Tatsuya Tochihara, Katsumi Shinohara, Takashi Nakamura, Hajime Yamada, Jun Mitadera
  • Publication number: 20160304671
    Abstract: Provided are [1] a xylylenediamine composition containing xylylenediamine and a compound represented by the following general formula (1), wherein the content of the compound represented by the general formula (1) is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine; and a method for producing a polyamide resin including the steps of introducing a compound represented by the following general formula (1), a diamine including xylylenediamine (but excluding the compound represented by the general formula (1)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the compound represented by the general formula (1) to be introduced is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine, where, in the general formula (1), n and m each independently represent an integer of 0 to 6, excluding the case where n and m are both 1.
    Type: Application
    Filed: October 29, 2014
    Publication date: October 20, 2016
    Inventors: Tatsuya Tochihara, Katsumi Shinohara, Takashi Nakamura, Hajime Yamada, Jun Mitadera, Takashi Yamamoto
  • Publication number: 20160304672
    Abstract: Provided are [1] a xylylenediamine composition containing xylylenediamine and a 5-membered or 6-membered heterocyclic compound (A) having at least one nitrogen-containing substituent and having two nitrogen atoms as atoms constituting a ring, wherein the content of the heterocyclic compound (A) is 0.001 to 0.02 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a 5-membered or 6-membered heterocyclic compound (A) having at least one nitrogen-containing substituent and having two nitrogen atoms as atoms constituting a ring, a diamine including xylylenediamine (but excluding a diamine corresponding to the above-mentioned heterocyclic compound (A)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the heterocyclic compound (A) to be introduced is 0.001 to 0.02 parts by mass based on 100 parts by mass of xylylenediamine.
    Type: Application
    Filed: October 29, 2014
    Publication date: October 20, 2016
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Takashi NAKAMURA, Hajime YAMADA, Tatsuya TOCHIHARA, Katsumi SHINOHARA, Jun MITADERA, Takashi Yamamoto
  • Publication number: 20160304670
    Abstract: Provided are [1] a xylylenediamine composition containing xylylenediamine and a pyridine compound (A) having at least one substituent including an amino group, wherein the content of the pyridine compound (A) is 0.001 to 0.1 parts by mass based on 100 parts by mass of the xylylenediamine; and [2] a method for producing a polyamide resin including the steps of introducing a pyridine compound (A) having at least one substituent including an amino group, a diamine including xylylenediamine (but excluding a diamine corresponding to the above-mentioned pyridine compound (A)), and a dicarboxylic acid into a reaction system and performing a polycondensation reaction, wherein the amount of the pyridine compound (A) to be introduced is 0.001 to 0.1 parts by mass based on 100 parts by mass of xylylenediamine.
    Type: Application
    Filed: October 29, 2014
    Publication date: October 20, 2016
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Takashi Nakamura, Hajime Yamada, Tatsuya Tochihara, Katsumi Shinohara, Jun Mitadera, Takashi Yamamoto