Abstract: The present invention provides a hydrogenated block copolymer that is a hydrogenated product of a copolymer containing a vinyl aromatic compound monomer unit and a conjugated diene monomer unit, and that satisfies the following conditions (1) to (3): (1) at least one of specific polymer blocks (b) and (c) is contained; (2) elongation at break measured in accordance with JIS K 6251 is 1000% or more; and (3) the hydrogenated block copolymer has at least one peak of tan ? in a viscoelasticity measurement chart at ?25° C. or more and 80° C. or less.

Abstract: A hydrogenated block copolymer satisfying the following conditions (1) to (7): (1) the hydrogenated block copolymer comprises (b) at least one hydrogenated copolymer block containing a vinyl aromatic monomer unit and a conjugated diene monomer unit; (2) a content of the (a) polymer block principally containing a vinyl aromatic monomer unit is 40% by mass or less; (3) Mw is 200,000 or less; (4) a hydrogenation rate is 20% or more; (5) a ratio, in a molecular weight curve of the hydrogenated block copolymer, of an area corresponding to a molecular weight of 10,000 to 150,000 to an area corresponding to a molecular weight of 10,000 to 1,000,000 is over 50%; (6) a vinyl bond content is 20% by mass or more (7) a content, in the (b) hydrogenated copolymer block, of the vinyl aromatic monomer unit is 30% by mass or more and 79% by mass or less.

Abstract: A hydrogenated block copolymer satisfying the following conditions (1) to (7): (1) the hydrogenated block copolymer comprises (b) at least one hydrogenated copolymer block containing a vinyl aromatic monomer unit and a conjugated diene monomer unit; (2) a content of the (a) polymer block principally containing a vinyl aromatic monomer unit is 40% by mass or less; (3) Mw is 200,000 or less; (4) a hydrogenation rate is 20% or more; (5) a ratio, in a molecular weight curve of the hydrogenated block copolymer, of an area corresponding to a molecular weight of 10,000 to 150,000 to an area corresponding to a molecular weight of 10,000 to 1,000,000 is over 50%; (6) a vinyl bond content is 20% by mass or more (7) a content, in the (b) hydrogenated copolymer block, of the vinyl aromatic monomer unit is 30% by mass or more and 79% by mass or less.

Abstract: The present invention, with the purpose of providing a catalyst composition for hydrogenation having high hydrogenation activity, provides a catalyst composition for hydrogenation, comprising: a titanocene dichloride; an organometal compound comprising one or two or more elements selected from the group consisting of Li, Na, K, Mg, Zn, Al and Ca; an unsaturated compound; and a polar compound, wherein a content ratio of the unsaturated compound to the titanocene dichloride is 0.1 or more and 8.0 or less, and a content ratio of the polar compound to the titanocene dichloride is 0.01 or more and 2.0 or less.

Abstract: A method for producing a catalyst composition for hydrogenation, wherein: (A): a titanocene compound represented by following general formula (1): wherein R5 and R6 represent a group selected from the group consisting of hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group and a carbonyl group, and may be the same or different, and R1 and R2 represent a group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and may be the same or different, provided that R1 and R2 represent are not all hydrogens or all hydrocarbon groups having 1 to 12 carbon atoms; (B): a compound containing at least one element selected from the group consisting of elements Li, Na, K, Mg, Zn, Al, and Ca; and (C): an unsaturated compound are used, and the method has: a force application step of applying a shearing force at a shearing rate of 1000 (1/s) or more to at least component (A); and a step of mixing components (A

Abstract: A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio ((C)/(A)) is 0.1 to 4.0 and a mass ratio ((D)/(A)) is 0.01 to 1.00, (A): a titanocene compound represented by formula (1), (wherein R5 and R6 are any group selected from hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group. R1 and R2 are any group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and R1 and R2 are not all hydrogen atoms or all a hydrocarbon group having 1 to 12 carbon atoms), (B): a reductant formed from a compound containing an element selected from the elements Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated compound having a molecular weight of 400 or less, and (D): a polar compound.

Abstract: A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio (D)/(A) is 0.01 to 2.00. (A): a titanocene compound represented by following formula (1), (wherein R5 and R6 are selected from the group consisting of hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group, and R1 and R2 are selected from hydrogen and a hydrocarbon group having 1 to 12 carbon atoms) (B): a compound containing an element selected from Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated polymer having a fraction of an olefinic unsaturated double bond content of side chains based on a total olefinic unsaturated double bond content of 0.25 to 1.0, and (D): a polar compound.

Abstract: A method for producing a catalyst composition for hydrogenation, wherein: (A): a titanocene compound represented by following general formula (1): wherein R5 and R6 represent a group selected from the group consisting of hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group and a carbonyl group, and may be the same or different, and R1 and R2 represent a group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and may be the same or different, provided that R1 and R2 represent are not all hydrogens or all hydrocarbon groups having 1 to 12 carbon atoms; (B): a compound containing at least one element selected from the group consisting of elements Li, Na, K, Mg, Zn, Al, and Ca; and (C): an unsaturated compound are used, and the method has: a force application step of applying a shearing force at a shearing rate of 1000 (1/s) or more to at least component (A); and a step of mixing components (A

Abstract: A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio (D)/(A) is 0.01 to 2.00. (A): a titanocene compound represented by following formula (1), (wherein R5 and R6 are selected from the group consisting of hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group, and R1 and R2 are selected from hydrogen and a hydrocarbon group having 1 to 12 carbon atoms) (B): a compound containing an element selected from Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated polymer having a fraction of an olefinic unsaturated double bond content of side chains based on a total olefinic unsaturated double bond content of 0.25 to 1.0, and (D): a polar compound.

Abstract: A catalyst composition for hydrogenation including (A) to (D), in which a mass ratio ((C)/(A)) is 0.1 to 4.0 and a mass ratio ((D)/(A)) is 0.01 to 1.00, (A): a titanocene compound represented by formula (1), (wherein R5 and R6 are any group selected from hydrogen, a hydrocarbon group having 1 to 12 carbon atoms, an aryloxy group, an alkoxy group, a halogen group, and a carbonyl group. R1 and R2 are any group selected from the group consisting of hydrogen and a hydrocarbon group having 1 to 12 carbon atoms, and R1 and R2 are not all hydrogen atoms or all a hydrocarbon group having 1 to 12 carbon atoms), (B): a reductant formed from a compound containing an element selected from the elements Li, Na, K, Mg, Zn, Al, and Ca, (C): an unsaturated compound having a molecular weight of 400 or less, and (D): a polar compound.

Abstract: There are provided a polypropylene-based resin composition having excellent impact resistance, tensile elongation at break and rigidity, a molded article thereof, and an automobile interior or exterior material using the same. The polypropylene-based resin composition contains 50 to 90% by mass of a polypropylene-based polymer (A), 5 to 50% by mass of an ethylene-?-olefin copolymer rubber (B), and 0.1 to 5% by mass of a copolymer (C) primarily comprising a vinyl aromatic monomer unit and an alkylene monomer unit, wherein a content of an ?-olefin monomer unit in all alkylene monomers is 45 mol % or more.

Abstract: The present invention provides a process for producing a block copolymer in high productivity, by anionic polymerization by use of a lithium initiator, and also to provide the block copolymer and a hydrogenated product thereof, the block copolymer having a conjugated diene block portion with a high vinyl bond content and a vinyl aromatic block portion with a narrow molecular weight distribution and exhibiting a narrow molecular weight distribution and high strength. A conjugated diene monomer and a vinyl aromatic monomer by use of a lithium initiator, are block copolymerized by making a tertiary amine compound and (2) sodium alkoxide coexist, wherein (2)/(1) (a molar ratio)=from 0.01 or more to less than 0.1.

Abstract: There are provided a polypropylene-based resin composition having excellent impact resistance, tensile elongation at break and rigidity, a molded article thereof, and an automobile interior or exterior material using the same. The polypropylene-based resin composition contains 50 to 90% by mass of a polypropylene-based polymer (A), 5 to 50% by mass of an ethylene-?-olefin copolymer rubber (B), and 0.1 to 5% by mass of a copolymer (C) primarily comprising a vinyl aromatic monomer unit and an alkylene monomer unit, wherein a content of an ?-olefin monomer unit in all alkylene monomers is 45 mol % or more.

Abstract: The present invention discloses a thermoplastic resin composition comprising: (A) 95 to 5 parts by weight of a styrenic resin and/or a polyphenylene ether resin; (B) 5 to 95 weight parts of an olefinic resin; and (C) 1 to 28 parts by weight of a partially hydrogenated block copolymer based on 100 parts by weight of the total amount of the components (A) and (B), wherein the component (C) comprises at least one polymer block X containing a vinyl aromatic compound as a main component and at least one polymer block Y containing a conjugated diene compound as a main component, a content of the vinyl aromatic compound in the component (C) is at least 10 wt % and at most 80 wt %, the vinyl bond content before hydrogenation in the component (C) is 3 wt % or more and less than 50 wt %, and 1 mol % or more and less than 40 mol % of double bonds derived from the conjugated diene compound in the block copolymer which constitutes the component (C) are hydrogenated.

Abstract: The present invention provides a process for producing a block copolymer in high productivity, by anionic polymerization by use of a lithium initiator, and also to provide the block copolymer and a hydrogenated product thereof, the block copolymer having a conjugated diene block portion with a high vinyl bond content and a vinyl aromatic block portion with a narrow molecular weight distribution and exhibiting a narrow molecular weight distribution and high strength. A conjugated diene monomer and a vinyl aromatic monomer by use of a lithium initiator, are block copolymerized by making a tertiary amine compound and (2) sodium alkoxide coexist, wherein (2)/(1) (a molar ratio)=from 0.01 or more to less than 0.1.

Abstract: Provided is a hydrogenated block copolymer for preparing a foam excellent in tear strength, compression set resistance, low impact resilience, and abrasion resistance. More specifically, provided is a hydrogenated block copolymer comprising a vinyl aromatic compound and a conjugated diene, wherein: (a) the vinyl aromatic unit content is greater than 35 wt. % and not greater than 90 wt. %, (b) the vinyl aromatic polymer block content is not greater than 40 wt. %, (c) the weight average molecular weight is from 5×104 to 100×104, and (d) the hydrogenation ratio of double bonds derived from the conjugated diene is less than 70%.