Abstract: Aspects of the present disclosure are directed methods and systems pertaining to the use of at least one methodology or technique for the purpose of at least one of either: 1) determining that a desired and predetermined level or “degree” of surface treatment of a composite substrate surface has or has not been conducted (e.g., laser treatment of a composite substrate surface); and 2) that a composite substrate surface has been laser treated.

Abstract: Disclosed are methods and coatings for protecting the surface of a non-metallic composite part, comprising applying a protective layer to an exposed surface of the non-metallic composite part, the protective layer comprising: (a) a multilayer having at least a co-cured layer applied to the surface of the non-metallic part and laser-sensitive layer applied to a surface of the co-cured layer, wherein the laser-sensitive layer is selected from a reflective layer, an optical sensor layer or a layer having both reflective and optical sensor properties; or (b) a co-cured coating which comprises a laser-sensitive material incorporated therein to form a laser-sensitive co-cured layer applied to a surface of the non-metallic composite part, wherein the laser-sensitive material is selected from a reflective material, an optical sensor material or a combination thereof, such that the non-metallic composite part will be protected from damage during subsequent laser ablation to remove an outer coating.

Abstract: Aspects of the present disclosure are directed methods and systems pertaining to the use of at least one methodology or technique for the purpose of at least one of either: 1) determining that a desired and predetermined level or “degree” of surface treatment of a composite substrate surface has or has not been conducted (e.g., laser treatment of a composite substrate surface); and 2) that a composite substrate surface has been laser treated.

Abstract: Systems and methods are provided for removing adhesive features. One embodiment is a method for operating a cryogenic-assisted adhesive a removal tool. The method includes dispensing a cryogenic fluid onto an adhesive feature disposed at a surface of a structure, cooling the adhesive feature to cause a physical change making the adhesive feature brittle, and operating the cryogenic-assisted adhesive removal tool to cleave the adhesive feature from the surface while the adhesive feature is physically changed.

Abstract: Systems and methods are provided for removing adhesive features. One embodiment is a method for operating a cryogenic-assisted adhesive a removal tool. The method includes dispensing a cryogenic fluid onto an adhesive feature disposed at a surface of a structure, cooling the adhesive feature to cause a physical change making the adhesive feature brittle, and operating the cryogenic-assisted adhesive removal tool to cleave the adhesive feature from the surface while the adhesive feature is physically changed.

Abstract: A method and apparatus comprising a sol-gel solution. Zirconium n-propoxide is aged in a solvent to form a first part for the sol-gel solution. The first part is combined with deionized water to form a second part for the sol-gel solution. Aminoaryltrialkoxysilane is combined with an alcohol to form a third part for the sol-gel solution. The third part is combined with the second part to form a mixture for the sol-gel solution. The deionized water, or the alcohol, or a combination thereof is combined with the mixture to form a solution. The solution is aged to form the sol-gel solution comprising a mole balance ratio of approximately 1:5 between the zirconium n-propoxide and the aminoaryltrialkoxysilane.

Abstract: A method and apparatus comprising a sol-gel solution. Zirconium n-propoxide is aged in a solvent to form a first part for the sol-gel solution. The first part is combined with deionized water to form a second part for the sol-gel solution. Aminoaryltrialkoxysilane is combined with an alcohol to form a third part for the sol-gel solution. The third part is combined with the second part to form a mixture for the sol-gel solution. The deionized water, or the alcohol, or a combination thereof is combined with the mixture to form a solution. The solution is aged to form the sol-gel solution comprising a mole balance ratio of approximately 1:5 between the zirconium n-propoxide and the aminoaryltrialkoxysilane.

Abstract: Adhesion testing systems, methods of fabrication, and methods of testing are disclosed. Test systems include test coupons with non-metallic test adherends. Test coupons are configured to test bonds to the non-metallic test adherends under peeling stress and/or shearing stress. Test methods are simplified and rapid as compared to standard adhesion tests and include methods of accelerated environmental testing. Test methods also are adapted for qualitative and quantitative measurement of bond performance.

Abstract: A method and apparatus comprising a sol-gel solution. Zirconium n-propoxide is aged in a solvent to form a first part for the sol-gel solution. The first part is combined with deionized water to form a second part for the sol-gel solution. Aminoaryltrialkoxysilane is combined with an alcohol to form a third part for the sol-gel solution. The third part is combined with the second part to form a mixture for the sol-gel solution. The deionized water, or the alcohol, or a combination thereof is combined with the mixture to form a solution. The solution is aged to form the sol-gel solution comprising a mole balance ratio of approximately 1:5 between the zirconium n-propoxide and the aminoaryltrialkoxysilane.

Abstract: A method for manufacturing a test specimen assembly. A first material for the test specimen assembly and a witness coupon are positioned relative to each other. A surface treatment is applied onto a first surface of the first material and onto a surface of the witness coupon. An adhesive is applied onto the first surface of the first material. A second surface of a second material for the test specimen assembly is placed onto the first surface of the first material with the adhesive. The adhesive is cured to form the test specimen assembly.

Abstract: Adhesion testing systems, methods of fabrication, and methods of testing are disclosed. Test systems include test coupons with non-metallic test adherends. Test coupons are configured to test bonds to the non-metallic test adherends under peeling stress and/or shearing stress. Test methods are simplified and rapid as compared to standard adhesion tests and include methods of accelerated environmental testing. Test methods also are adapted for qualitative and quantitative measurement of bond performance.

Abstract: Silicon and aluminum complexes having the following formula I, II or III: ##STR1## wherein x is 0 or 1, T is H or ##STR2## each R is independently selected from the group consisting of H, OH, C.sub.1-6 alkyl, C.sub.1-6 alkoxy, C.sub.2-6 alkene, C.sub.6-12 aryl, C.sub.1-6 hydroxyalkyl, C.sub.1-6 thioalkyl, C.sub.2-12 alkoxyalkyl, C.sub.3-20 heteroaromatic, and combinations thereof, wherein R may further contain one or more atoms of a non-carbon element such as Si, Ge, Sn, P, and the like; Y is a cation, and Z is a multivalent cation, are prepared by reacting silica or alumina with a diol, in the presence of a base, while removing water formed during the reaction. Methods for producing such complexes starting with silica or alumina, and methods for converting such complexes into other silicon or aluminum-containing compounds, are disclosed.

Abstract: Silicon and aluminum complexes having the following formula: ##STR1## wherein x is 0 or 1, T is H or ##STR2## each R is independently selected from the group consisting of H, OH, C.sub.1-6 alkyl, C.sub.1-6 alkoxy, C.sub.2-6 alkene, C.sub.6-12 aryl, C.sub.1-6 hydroxyalkyl, C.sub.1-6 thioalkyl, C.sub.2-12 alkoxyalkyl, C.sub.3-20 heteroaromatic, and combinations thereof, wherein R may further contain one or more atoms of a non-carbon element such as Si, Ge, Sn, P, and the like; and Y is a cation, are prepared by reacting silica or alumina with a diol, in the presence of a base, while removing water formed during the reaction. Methods for producing such complexes starting with silica or alumina, and methods for converting such complexes into other silicon or aluminum-containing compounds, are disclosed.

Abstract: A tractable ceramic precursor and method for producing the same, capable of being formed into useful shapes at low temperatures and thereafter capable of transformation into high-temperature superconducting ceramics is provided. The method consists of preparing one or more organometallic compounds selected from organometallic clusters and organometallic polymers and combining them in the proper stoichiometric ratio to form a tractable ceramic precursor having rheological/viscoelastic properties suitable for forming useful shapes and having metal elements in suitable proportions to form high-temperature superconducting ceramics.